Paper coating for ink jet printing

• US 6,528,119 B1
• Filed: 01/18/2000
• Issued: 03/04/2003
• Est. Priority Date: 01/18/2000
• Status: Expired due to Term

• Current Assignee: Funai Electric Co., Ltd. (Funai Electric Holdings Company Limited)
• Original Assignee: Lexmark International Incorporated (Ninestar Corporation)
• Inventors: MacMillan, David Starling
• Primary Examiner(s): Barr, Michael
• Assistant Examiner(s): JOLLEY, KIRSTEN
• Application Number:
  US09/484,700
• Time in Patent Office: 1,141 Days
• Field of Search: 427/261, 427/265, 427/288, 427/411, 427/419.1
• US Class Current: 427/261
• CPC Class Codes: B41M 5/508 Supports
• CPC Class Codes: B41M 5/52 Macromolecular coatings
• CPC Class Codes: B41M 5/5218 characterised by inorganic additives, e.g. pigments, clays
• CPC Class Codes: B41M 5/5227 characterised by organic non-macromolecular additives, e.g. UV-absorbers, plasticisers, surfactants
• CPC Class Codes: B41M 5/5245 characterised by the use of polymers containing cationic or anionic groups, e.g. mordants
• CPC Class Codes: B41M 5/529 characterised by the use of fluorine- or silicon-containing organic compounds
• CPC Class Codes: Y10T 428/24802 Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
• CPC Class Codes: Y10T 428/24893 including particulate material
• CPC Class Codes: Y10T 428/24909 Free metal or mineral containing
• CPC Class Codes: Y10T 428/31931 Polyene monomer-containing
• CPC Class Codes: Y10T 428/31993 Of paper
• CPC Class Codes: Y10T 428/31996 Next to layer of metal salt [e.g., plasterboard, etc.]

Abstract

The invention provides an improved paper coating composition for ink jet printing applications. The composition contains from about 2 to about 1 parts by weight polyvalent metal salt, from about 0 to about 30 parts by weight deionized water, an effective amount of cationic amine polymer and surfactant and from about 35 to about 60 parts by weight of an ink penetrant promoter selected from the group consisting of 1,2-propanediol, dipropylene glycol and mixtures of 1,2-propanediol and dipropylene glycol. Since the composition is free from ethylene glycol components, the composition is safer to use and less harmful to humans and the environment. The composition has also been found to provide improved ink drying with less bleeding or smearing of image.

Claims

1. A method for improving print resolution comprising applying an aqueous penetrant promoter composition to a cellulosic web to provide an ink receptive coating and printing on the coated web wherein the promoter composition contains from about 2 to about 10 parts by weight polyvalent metal salt, from about 15 to about 40 parts by weight water, an effective amount of cationic amine polymer and surfactant and from about 35 to about 60 parts by weight of an ink penetrant promoter selected from the group consisting of 1,2-propanediol, dipropylene glycol and mixtures of 1,2-propanediol and dipropylene.

2. The method of claim 1 wherein the penetrant promoter composition contains from about 5 to about 30 percent by weight cationic amine polymer.

3. The method of claim 2 wherein the cationic amine polymer is a compound of the formula

wherein x is an integer ranging from about 15 to about 2000.

4. The method of claim 2 wherein the cationic amine polymer is derived from dimethylamine and epichlorohydrin and has a number average molecular weight ranging from about 7,500 to about 10,000 MW_N.

5. The method of claim 2 wherein the surfactant comprises a polysiloxane surfactant.

6. The method of claim 5 wherein the polysiloxane surfactant is a compound having the following general structure:

wherein;

PE comprises —

CH₂CH₂CH₂O(EO)_n(PO)_oZ, Me is a methyl group, EO is an ethyleneoxy group, PO is a 1,2-propyleneoxy group, Z is H or a lower alkyl radical y is an integer ranging from about 1 to about 10, m is an integer ranging from about 1 to about 10, n is an integer ranging from about 0 to about 5 and o is an integer ranging from about 0 to about 5.

7. The method of claim 1 wherein the polyvalent metal salt is selected from the group consisting of calcium chloride, magnesium chloride, calcium acetate hydrate, magnesium acetate tetrahydrate and mixtures thereof.