Multi-component polymeric networks containing poly(ethylene glycol)

• US 6,528,584 B2
• Filed: 04/12/2001
• Issued: 03/04/2003
• Est. Priority Date: 04/12/2001
• Status: Expired due to Fees

• Current Assignee: University of Akron
• Original Assignee: University of Akron
• Inventors: Kurian, Pious V., Kennedy, Joseph P.
• Primary Examiner(s): Dawson, Robert
• Assistant Examiner(s): Robertson, Jeffrey B.
• Application Number:
  US09/833,774
• Publication Number:
  US 20030022991A1
• Time in Patent Office: 691 Days
• Field of Search: 525/100, 525/101, 525/106, 525/474, 525/478, 525/479, 528/25, 528/29, 528/31, 528/32, 424/422, 424/486
• US Class Current: 525/101
• CPC Class Codes: C08G 65/336 containing silicon
• CPC Class Codes: C08G 77/42 Block-or graft-polymers containing polysiloxane sequences polymerising aliphatic unsaturated monomers on to a polysiloxane C08F283/12
• CPC Class Codes: C08G 77/442 containing vinyl polymer sequences

Abstract

Multicomponent networks or membranes of the present invention have good mechanical properties that are permeable to water, hydrocarbons, and oxygen. The networks contain at least two and preferably at least three covalently combined domains, i.e., a hydrophilic, a lipophilic and an oxyphilic polymer segment, that give rise to a multicontinuous domain microstructure. At least one of these domains includes poly(ethylene glycol).

Claims

1. A multicomponent network comprising the reaction product of at least a plurality of multifunctional, allyl terminated polyethylene glycols linked to a plurality of multifunctional siloxane compounds having at least two SiH moieties for each siloxane compound, wherein the reaction product further includes at least a plurality of multifunctional, allyl-terminated polyisobutylenes linked to the plurality of multifunctional siloxane compounds having at least two SiH moieties for each siloxane compound.

3. The multicomponent network of claim 1, wherein the reaction product further includes at least a plurality of multifunctional, vinyl-terminated polydimethylsiloxanes linked to the plurality of multifunctional siloxane compounds having at least two SiH moieties for each siloxane compounds.

4. The multicomponent network of claim 1, wherein said siloxane compounds are cyclosiloxanes.

5. The multicomponent network of claim 4, wherein said siloxane compounds are pentamethylcyclopentasiloxane.

6. The multicomponent network of claim 1, wherein the allyl terminated polyethylene glycols are ditelechelic.

7. The multicomponent network of claim 1, wherein the allyl terminated polyisobutylenes are ditelechelic.

10. The multicomponent network of claim 1, wherein the reaction product is hydrophilic, lipophilic, and oxyphilic.

12. The multicomponent network of claim 3, wherein the reaction product is hydrophilic, lipophilic, and oxyphilic.

16. The multicomponent network of claim 3, wherein the allyl terminated polyethylene glycols are ditelechelic.

2. A multicomponent network comprising the reaction product of at least a plurality of multifunctional, allyl terminated polyethylene glycols linked to a plurality of multifunctional siloxane compounds having at least two SiH moieties for each siloxane compound, wherein the reaction product further includes at least a plurality of multifunctional, vinyl-terminated polydimethylsiloxanes linked to the plurality of multifunctional siloxane compounds having at least two SiH moieties for each siloxane compound.

8. The multicomponent network of claim 2, wherein the vinyl terminated polydimethylsiloxanes are ditelechelic.

9. The multicomponent network of claim 2, wherein the reaction product is devoid of polyisobutylenes.

11. The multicomponent network of claim 2, wherein the reaction product is hydrophilic, lipophilic, and oxyphilic.

14. The multicomponent network of claim 2, wherein said siloxane compounds are cyclosiloxanes.

15. The multicomponent network of claim 14, wherein said siloxane compounds are pentamethylcyclopentasiloxane.

13. A multicomponent network comprising the hydrosilation reaction product of a plurality of ditelechelic, allyl-terminated polyethylene glycols, a plurality of ditelechelic, allyl-terminated polyisobutylenes, and a plurality of ditelechelic vinyl-terminated polydimethylsiloxanes, each linked to a plurality of pentamethylcyclopentasiloxanes having five SiH moieties for each of the pentamethylcyclopentasiloxanes.