Land-based desalination using positively buoyant or negatively buoyant/assisted buoyancy hydrate

• US 6,531,034 B1
• Filed: 08/17/1999
• Issued: 03/11/2003
• Est. Priority Date: 07/12/1999
• Status: Expired due to Fees

• Current Assignee: Water Generating Systems LLC
• Original Assignee: Marine Desalination Systems LLC
• Inventors: Max, Michael D.
• Primary Examiner(s): Hruskoci, Peter A.
• Application Number:
  US09/375,410
• Time in Patent Office: 1,302 Days
• Field of Search: 625/32, 625/33, 585/15, 210/712, 210/718, 210/737, 210/749, 210/747, 210/750, 210/765, 210/772, 210/766, 210/774, 210/787, 203/10, 203/100
• US Class Current: 203/10
• CPC Class Codes: B01D 2257/504 Carbon dioxide
• CPC Class Codes: B01D 53/62 Carbon oxides
• CPC Class Codes: C02F 1/20 by degassing, i.e. liberation of dissolved gases degasification of liquids in general B01D19/00; arrangement of degassing apparatus in boiler feed supply F22D
• CPC Class Codes: C02F 1/22 by freezing
• CPC Class Codes: C02F 1/26 by extraction
• CPC Class Codes: C02F 1/265 Desalination
• CPC Class Codes: C02F 1/5236 using inorganic agents
• CPC Class Codes: C02F 2103/08 Seawater, e.g. for desalination
• CPC Class Codes: C02F 2103/18 from the purification of gaseous effluents
• CPC Class Codes: Y02A 20/124 Water desalination
• CPC Class Codes: Y02C 20/40 of CO2
• CPC Class Codes: Y10S 203/08 Waste heat
• CPC Class Codes: Y10S 203/11 Batch distillation
• CPC Class Codes: Y10S 203/18 Control

Abstract

Methods and apparatus for desalination of salt water (and purification of polluted water) are disclosed. Salt (or otherwise polluted) water is pumped to a desalination installation and down to the base of a desalination fractionation column, where it is mixed with hydrate-forming gas to form either positively buoyant or negatively buoyant (assisted buoyancy) hydrate. The hydrate rises or is carried upward and dissociates (melts) into the gas and pure water. In preferred embodiments, residual salt water which is heated by heat given off during formation of the hydrate is removed from the system to create a bias towards overall cooling as the hydrate dissociates endothermically at shallower depths. In preferred embodiments, the input water is passed through regions of dissociation in heat-exchanging relationship therewith so as to be cooled sufficiently for hydrate to form at pressure-depth. The fresh water produced by the system is cold enough that it can be used to provide refrigeration, air conditioning, or other cooling; heat removed from the system with the heated residual water can be used for heating or other applications.

Claims

1. A method of desalinating or purifying saline or otherwise polluted water, said method comprising:

providing saline or otherwise polluted input water to a lower, hydrate formation region of a desalination fractionation installation that is located in a shaft formed in land and mixing said input water with a gas or gas mixture to produce gas hydrate, said gas hydrate, per se, having a specific gravity that is greater than the specific gravity of the input water and therefore being negatively buoyant relative to said input water, said mixing being performed at temperature and pressure conditions conducive to the formation of said gas hydrate;

causing said gas hydrate to be provided to a dissociation region of said desalination fractionation installation and allowing said gas hydrate to dissociate into fresh water and the hydrate-forming gas or gas mixture; and

collecting said fresh water;

wherein said mixing is controlled such that said gas hydrate forms assisted buoyancy gas hydrate masses which, in toto, are positively buoyant relative to the input water and which therefore rise naturally within said desalination fractionation installation.

2. The method of claim 1, wherein said assisted buoyancy gas hydrate masses are diverted laterally into said dissociation region as they rise within said desalination fractionation installation so as to be horizontally displaced relative to the lower, hydrate formation region of the desalination fractionation installation.

3. The method of claim 2, wherein some gas hydrate settles in the lower, hydrate formation region of said desalination fractionation installation, said method further comprising pumping said settled gas hydrate upward and into the dissociation region of said desalination fractionation installation.

4. The method of claim 3, further comprising separating said settled gas hydrate from residual fluid before said settled gas hydrate enters the dissociation region of said desalination fractionation installation.

5. The method of claim 1, further comprising removing heat liberated during exothermic formation of said gas hydrate by removing heated residual fluid through which said assisted buoyancy gas hydrate is rising.

6. The method of claim 1, further comprising cooling said input water by passing said input water through the dissociation region of said desalination fractionation installation in heat-exchanging relationship with endothermically dissociating gas hydrate disposed therein.

7. The method of claim 6, further comprising cooling said input water using means supplemental to said passing said input water through the dissociation region of said desalination fractionation installation.

8. A method of desalinating or purifying saline or otherwise polluted water, said method comprising:

providing saline or otherwise polluted input water to a lower, hydrate formation region of a desalination fractionation installation and mixing said input water with a gas or gas mixture to produce gas hydrate, said gas hydrate, per se, having a specific gravity that is greater than the specific gravity of the input water and therefore being negatively buoyant relative to said input water, said mixing being performed at temperature and pressure conditions conducive to the formation of said gas hydrate;

causing said gas hydrate to be provided to a dissociation region of said desalination fractionation installation and allowing said gas hydrate to dissociate into fresh water and the hydrate-forming gas or gas mixture; and

collecting said fresh water;

wherein said mixing is controlled such that substantially all of said gas forms negatively buoyant gas hydrate which settles in a lower, sump portion of said desalination fractionation installation and wherein said causing said gas hydrate to be provided to said dissociation region of said desalination fractionation installation comprises pumping settled gas hydrate from said lower, sump portion to said dissociation region.

9. The method of claim 8, further comprising removing heat liberated during exothermic formation of said gas hydrate by removing heated residual fluid that has been displaced upwardly by said settled gas hydrate, said displaced residual fluid being displaced upwardly through a conduit other than a conduit by which said input water is provided to the lower, hydrate formation region of the desalination fractionation installation.

10. The method of claim 8, further comprising cooling said input water by passing said input water through the dissociation region of said desalination fractionation installation in heat-exchanging relationship with endothermically dissociating gas hydrate disposed therein.

11. The method of claim 10, further comprising cooling said input water using means supplemental to said passing said input water through the dissociation region of said desalination fractionation installation.

12. The method of claim 8, wherein said pumping settled gas hydrate from said lower, sump portion to said dissociation region comprises transferring hydrate into a slurry holder tank disposed within said dissociation region;

allowing said hydrate to dissociate within said slurry holder tank into fresh water and said hydrate-forming gas or gas mixture;

passing residual, intergranular saline water through fresh water disposed within said dissociation region via one or more conduits extending from a bottom portion of said slurry holder tank toward a bottom portion of said dissociation region so as to avoid or minimize mixing of the residual, intergranular saline water with fresh water; and

removing the residual, intergranular saline water from said dissociation region.