Fabrication of molecular nanosystems

• US 6,531,107 B1
• Filed: 10/05/2000
• Issued: 03/11/2003
• Est. Priority Date: 10/14/1999
• Status: Expired due to Fees

• Current Assignee: Syracuse University
• Original Assignee: Syracuse University
• Inventors: Spencer, James T., Allis, Damian G.
• Primary Examiner(s): Langel, Wayne A.
• Application Number:
  US09/679,929
• Time in Patent Office: 887 Days
• Field of Search: 423/276, 423/659, 556/136, 556/140, 556/46, 568/1, 568/3, 568/4, 585/24, 585/25, 585/26, 585/350, 585/352
• US Class Current: 423/276
• CPC Class Codes: C01B 6/10 Monoborane; Diborane; Addition complexes thereof
• CPC Class Codes: C01P 2002/90 Other crystal-structural characteristics not specified above
• CPC Class Codes: C07F 5/027 Organoboranes and organoborohydrides
• CPC Class Codes: Y10S 977/84 Manufacture, treatment, or detection of nanostructure
• CPC Class Codes: Y10S 977/896 Chemical synthesis, e.g. chemical bonding or breaking

Abstract

The invention relates to structural subunits called “synthons” which are suitable for use in the design and manufacture of molecular nanostructures, machines, and devices.

The synthon comprises polyhedra units and other species which exhibit rigid structural frameworks, the availability of stereo- and regiochemically directed substitution patterns, synthetic availability and accessability with substitutional control, diversity of available structural arrangements with said polyhedra units and related species, and connecting means which function to join adjacent synthons.

Claims

1. A molecular synthon for the fabrication of larger molecular structures which comprises;

(a) one or more main group polyhedral clusters and

(b) a second molecular framework covalently linked to the main group polyhedral cluster(s).

2. The synthon of claim 1 in which the main group polyhedral cluster(s) is at least one selected from the group consisting of boranes, and other heteroboranes.

3. The synthon of claim 1 in which the second molecular framework through which to introduce either covalent bonding or electrostatic connectivity between synthons is at least one selected from the group consisting of main groups boranes, carboranes, other heteroboranes, and organic structures, including monocyclic hydrocarbons, polycyclic hydrocarbons, and organic functional groups.

4. The synthon of claim 1 in which the larger structures fabricated from the molecular synthons are assembled through the covalent attachment of the main group polyhedral frameworks to one another as to form a connected molecular scaffolding for the larger structures.

5. The synthon of claim 1 in which the larger structures fabricated from the molecular synthons are assembled by way of the second molecular framework through the use of covalent bonding or electrostatic interactions between these second molecular frameworks.

6. The synthon of claim 1 in which the second molecular framework provides for stability between synthons by way of connectivity between these second molecular frameworks either through the covalent and/or electrostatic attachment of these molecular frameworks to one another after their covalent attachment to the polyhedral cluster(s) or through their covalent and/or electrostatic attachment to one another prior to the covalent attachment of the polyhedral cluster(s).

7. The synthon of claim 1 in which the molecular synthons form extended arrays of connected synthons of indefinite synthon number through the covalent attachment of the polyhedral clusters to one another and either the covalent attachment to or electrostatic stabilization between the second molecular frameworks with said extended arrays of indefinite synthon number include at least one selected from the group consisting of helical structures, linear arrays, rod structures, two-dimensional extended arrays, and three-dimensional extended arrays.

8. The synthon of claim 1 in which the molecular synthons form discrete macromolecular structures or nanoscale assemblies through the covalent attachment of the polyhedral clusters to one another and either the covalent attachment to or electrostatic interactions between the second molecular frameworks with said discrete structures include at least one selected from the group consisting of ring structures, helical structures, linear structures, rod structures, two-dimensional discrete assemblies, and three-dimensional discrete assemblies.