Bleaching compositions

• US 6,534,463 B1
• Filed: 03/12/2001
• Issued: 03/18/2003
• Est. Priority Date: 09/16/1998
• Status: Expired due to Fees

• Current Assignee: The Procter & Gamble Company
• Original Assignee: The Procter & Gamble Company
• Inventors: Briatore, Andrea, Todini, Oreste, Grande, Giovanni
• Primary Examiner(s): Gupta, Yogendra N.
• Assistant Examiner(s): Petruncio, John M
• Application Number:
  US09/786,934
• Time in Patent Office: 736 Days
• Field of Search: 510/367, 510/302, 510/276, 510/326, 510/348
• US Class Current: 510/348
• CPC Class Codes: C11D 3/042 Acids
• CPC Class Codes: C11D 3/046 Salts
• CPC Class Codes: C11D 3/1213 Oxides or hydroxides, e.g. Al2O3, TiO2, CaO or Ca(OH)2
• CPC Class Codes: C11D 3/3942 Inorganic per-compounds C11D3/3902 takes precedence
• CPC Class Codes: C11D 3/3945 Organic per-compounds C11D3/3902 takes precedence
• CPC Class Codes: C11D 3/3947 Liquid compositions
• CPC Class Codes: C11D 3/3953 Inorganic bleaching agents C11D3/3951 takes precedence
• CPC Class Codes: C11D 3/3955 Organic bleaching agents C11D3/3951 takes precedence
• CPC Class Codes: C11D 3/3956 Liquid compositions

Abstract

The present invention relates to bleaching compositions comprising a bleach, a borate or boric acid or a mixture thereof and less than 5% by weight of the total composition of a metal oxide selected from the group consisting of Sn, Ti, Zn, Al, Bi, Ga, Ge, Sb and Mg or a mixture thereof. These bleaching compositions exhibit excellent fabric yellowing-prevention performance and/or fabric safety.

Claims

1. A bleaching composition comprising a bleach, a borate or boric acid or a mixture thereof and 0.001% to 5% by weight of the total composition of a metal oxide selected from the group consisting of oxides of Sn, Zn, Al, Bi, Ga, Ge, Sb and Mg or a mixture thereof.

2. A composition according to claim 1 wherein said bleach is a hypohalite bleach or a peroxygen bleach.

3. A composition according to claim 2 wherein said hypohalite bleach is an alkali metal or an alkaline earth metal hypochlorite.

4. A composition according to claim 2 wherein said peroxygen bleach is hydrogen peroxide or a source thereof.

5. A composition according to claim 1 wherein said composition is solid.

6. A composition according to claim 1 wherein said composition is liquid.

7. A composition according to claim 6 comprising a hypohalite bleach wherein said composition has a pH of from 8 to 14.

8. A composition according to claim 1 comprising up to 10% by weight of the total composition of an alkalinity source.

9. A composition according to claim 6 comprising a peroxygen bleach wherein said composition has a pH of from 1 to 9.

10. A composition according to claim 1 comprising up to 10% by weight of the total composition of an acid.

11. A composition according to claim 1 which comprises from 0.01% to 20% by weight of the total composition of said bleach.

12. A composition according to claim 1 which comprises from 0.01% to 10% by weight of the total composition of said borate or boric acid or a mixture thereof.

13. A composition according to any of the preceding claims wherein said borate is an alkali metal salt of borate or an alkyl borate or a mixture thereof.

14. A composition according to any of the preceding claims which comprises from 0.001% to 3% by weight of the total composition of said metal oxide.

15. A composition according to any of the preceding claims wherein said metal oxide is selected from the group consisting of SnO, SnO₂, ZnO, Al₂O₃, Bi₂O₃, Bi₂O₅, Ga₂O₃, GeO₂, GeO, Sb₂O₃, Sb₃O₅, MgO and a mixture thereof.

16. A composition according to any of the preceding claims which further comprises an optional ingredient selected from the group consisting of pH buffering components, bleach stable surfactants, pigments, dyes, optical brighteners, polymers, stabilizing agents, enzymes, chelating agents, radical scavengers, bleach activators, solvents, builders, hydrotropes and mixtures thereof.

17. A process of treating fabrics which comprises the step of contacting said fabrics with a composition according to any of the preceding claims, in its diluted form at a dilution level with water of up to 500:

1 (water;

composition).

18. A process according to claim 17 wherein said fabrics are washed with a detergent composition comprising at least one surface active agent before the step of contacting said fabrics with said composition and/or during the step where said fabrics are contacted with said composition and/or after a rinsing step after said composition has been removed.

19. A process of treating a fabric which comprises the steps of contacting said fabric with a composition according to any of claims 1 to 16, in its neat form, allowing said fabric to remain in contact with said composition for a period of time sufficient to treat said fabric, and then rinsing said fabric in water to remove said composition.

20. A process of treating a hard-surface with a composition according to any of the claims 1 to 16, wherein said process comprises the step of applying said composition to said hard-surface and optionally rinsing said hard-surface.

21. A method of preventing yellowing of fabric and/or enhancing fabric safety comprising adding a metal oxide selected from the group consisting of oxides of Sn, Ti, Zn, Al, Bi, Ga, Ge, Sb and Mg or a mixture thereof and a borate or boric acid or a mixture thereof to a bleaching composition to form a fabric bleaching composition and treating said fabric with said fabric bleaching composition.