Fractionation for full boiling range gasoline desulfurization

• US 6,540,907 B1
• Filed: 07/09/2001
• Issued: 04/01/2003
• Est. Priority Date: 07/09/2001
• Status: Expired due to Fees

• Current Assignee: UOP Llc (Honeywell International Inc.)
• Original Assignee: UOP Llc (Honeywell International Inc.)
• Inventors: Schultz, Michael A., Towler, Gavin P.
• Primary Examiner(s): Griffin, Walter D.
• Assistant Examiner(s): Arnold, Jr., James
• Application Number:
  US09/900,941
• Time in Patent Office: 631 Days
• Field of Search: 208/237, 208/347, 208/211
• US Class Current: 208/211
• CPC Class Codes: B01D 3/141 where at least one distillation column contains at least one dividing wall
• CPC Class Codes: C10G 2400/02 Gasoline
• CPC Class Codes: C10G 67/16 plural parallel stages only

Abstract

Savings in the processing of a naphtha boiling range feed containing a thiophene are achieved by fractionating the feed stream in a single dividing wall column to yield a C₆-minus overhead stream, a side-draw containing the majority of the C₆ and C₇ paraffins and olefins, and a bottoms stream comprising C₇ and heavier hydrocarbons. A dividing wall column provides better control of the concentration of both thiophene and toluene in the side-draw. Less of the valuable naphtha is lost and the amount of thiophene in the overhead product is minimized.

Claims

1. In a process for the treatment of an FCC naphtha fraction to remove sulfur containing compounds wherein the FCC naphtha fraction is separated by fractional distillation yielding at least light and heavy fractions, the improvement which comprises performing the fractional distillation in a dividing wall column and producing an intermediate fraction comprising C₇ olefins and thiophene.

2. A process for the desulfurization of a naphtha boiling range feed stock comprising sulfur compounds, which process comprises:

a.) passing the feedstock into a dividing wall column and separating the feed stock into a light fraction comprising mercaptans, olefinic hydrocarbons and paraffinic hydrocarbons having less than six carbon atoms, an intermediate fraction comprising C₆ and C₇ olefinic hydrocarbons and thiophene, and a heavy fraction which comprises sulfur compounds and hydrocarbons containing more than seven carbon atoms per molecule;

b.) passing the light fraction into an extractive first treating zone in which mercaptans are removed by contact with an aqueous alkaline solution to form a first treated stream;

c.) treating the intermediate fraction in a second treating zone, in which thiophenes are removed, to form a second treated stream;

d.) treating the heavy fraction in a third treating zone, in which sulfur containing compounds are subjected to hydrotreating, to form a third treated stream; and

e.) recovering treated products.

3. The process of claim 2 further characterized in that the recovery of thiophene in the light fraction is controlled to be less than 50 wt. ppm.

4. The process of claim 2 further characterized in that the recovery of C₇ olefinic hydrocarbons in the intermediate stream is greater than 30% of the C₇ olefin content of the feed stream.

5. The process of claim 2 further characterized in that the second treating zone comprises a solvent extraction zone in which thiophene is removed from the intermediate fraction.

6. The process of claim 5 in which the solvent comprises sulfolane or a sulfolane derivative.

7. The process of claim 5 in which the solvent comprises di methyl sulfoxide.

8. The process of claim 5 in which the solvent comprises tetra ethylene glycol.

9. The process of claim 2 further characterized in that the second treating zone comprises a selective hydrogenation zone in which thiophene is hydrogenated in the presence of olefins.

10. The process of claim 2 further characterized in that the treating of the intermediate fraction comprises hydrotreating followed by passage into a catalytic naphtha reforming zone.