Production of low-particulate bisphenol and use thereof in the manufacturing of polycarbonate

• US 6,545,187 B1
• Filed: 09/19/2001
• Issued: 04/08/2003
• Est. Priority Date: 09/19/2001
• Status: Expired due to Term

• Current Assignee: SABIC Global Technologies BV (Government of Saudi Arabia)
• Original Assignee: General Electric Company
• Inventors: Stokes, Edward Brittain, Nance, Darlene Hope, Chen, Fang Christine, Blubaugh, James Cristopher, Ordonez, Juan Rodriguez, Kissinger, Gaylord Michael, Quintana, Jose M.
• Primary Examiner(s): Shippen, Michael L.
• Application Number:
  US09/682,560
• Publication Number:
  US 20030055296A1
• Time in Patent Office: 566 Days
• Field of Search: 568/724, 568/727, 568/728, 528/196, 422/190
• US Class Current: 568/724
• CPC Class Codes: B01J 2219/00006 Large-scale industrial plants
• CPC Class Codes: C07C 37/74 by distillation
• CPC Class Codes: C07C 39/04 Phenol
• CPC Class Codes: C07C 39/16 Bis-(hydroxyphenyl) alkanes; Tris-(hydroxyphenyl)alkanes
• CPC Class Codes: C08G 64/24 and phenols
• CPC Class Codes: C08G 64/307 and phenols

Abstract

Low-particulate dihydric aromatic compounds such as bisphenol-A that can be used in the synthesis of low-particulate polycarbonates are prepared by introducing into a desorber column containing a non-aggregate packing material an adduct of bisphenol and phenol and optionally a stripping gas. The column is maintained at an operating temperature that is sufficiently high and an operating pressure that is sufficiently low such that the adduct is distilled. The stream of phenol and the stripping gas is recovered from the top of the column. A second stream containing bisphenol that is substantially free of added particulate matter is recovered from the bottom of the column. This purified stream of bisphenol-A can further be used in a method of producing optical-grade polycarbonate.

Claims

1. A method of producing a low-particulate dihydric aromatic compound, comprising the steps of:

(a) introducing into a desorber column possessing a non-aggregate packing material an adduct of a dihydric aromatic compound and phenol;

(b) providing an operating temperature range in the desorber column that is sufficiently high and an operating pressure in the column that is sufficiently low such that the adduct is distilled;

(c) discharging from the desorber column a first stream containing substantially all of the phenol; and

(d) discharging from the desorber column a second stream containing substantially all of the dihydric aromatic compound;

whereby the second stream is substantially free of particulate matter added in the desorber column.

2. The method of claim 1, wherein the non-aggregate packing material is selected from the group consisting of borosilicate glass, stainless steel, zirconia, and polytetrafluoroethylene.

3. The method of claim 1, wherein the non-aggregate packing material is made from borosilicate glass.

4. The method of claim 1, wherein a stripping gas is introduced to the column in countercurrent flow to the adduct.

5. The method of claim 4, wherein the stripping gas is selected from the group consisting of nitrogen, carbon dioxide and steam.

6. The method of claim 4, wherein the dihydric aromatic compound is a bisphenol.

7. The method of claim 4, wherein the dihydric aromatic compound is bisphenol-A.

8. The method of claim 7, wherein the operating temperature range in the column is about 172 to about 217°

C.

9. The method of claim 8, wherein the operating pressure of the column is in a range from about 35 trout 810 mm Hg.

10. The method of claim 4, wherein the operating temperature range in the column is about 172 to about 217°

C.

11. The method of claim 10, wherein the operating pressure of the column is in a range from about 35 to about 810 mm Hg.

12. The method of claim 4, wherein the operating pressure of the column is in a range from about 35 to about 810 mm Hg.

13. The method of claim 4 wherein the operating pressure of the column is below atmospheric pressure.

14. The method of claim 1, wherein less than 20,000 particulates per gram of bisphenol are added in the desorber column.

15. A method of manufacturing low-particulate polycarbonate, comprising the steps of:

(a) preparing a dihydric aromatic compound by a method comprising the steps of;

(i) introducing into a desorber column possessing a non-aggregate packing material an adduct of a dihydric aromatic compound and phenol;

(ii) providing an operating temperature range in the desorber column that is sufficiently high and an operating pressure in the column that is sufficiently low such that the adduct is distilled;

(iii) discharging from the desorber column a first stream containing substantially all of the phenol; and

(iv) discharging from the desorber column a second stream containing substantially all of the dihydric aromatic compound;

whereby the second stream is substantially free of particulate matter added in the desorber column; and

(b) reacting the dihydric aromatic compound from the second stream with a derivative of carbonic acid to form a polycarbonate to form a low-particulate polycarbonate.

16. The method of claim 15, wherein the non-aggregate packing material is selected from the group consisting of borosilicate glass, stainless steel, zirconia, and polytetrafluoroethylene.

17. The method of claim 15, wherein the non-aggregate packing material is made from borosilicate glass.

18. The method of claim 15, wherein a stripping gas is introduced to the column in countercurrent flow to the adduct.

19. The method of claim 18, wherein the operating temperature range in the column is about 172 to about 217°

C.

20. The method of claim 18, wherein the operating pressure of the column is in a range from about 35 to about 810 mm Hg.

21. The method of claim 18, wherein the operating pressure of the column is less than atmospheric pressure.

22. The method of claim 18, wherein the stripping gas is selected from the group consisting of nitrogen, carbon dioxide and steam.

23. The method of claim 15, wherein the derivative of carbonic acid is a carbonic diester.

24. The method of claim 23, wherein the carbonic diester is diphenyl carbonate.

25. The method of claim 15, wherein the derivative of carbonic acid is a carbonyl halide.

26. The method of claim 25, wherein the carbonyl halide is carbonyl chloride.

27. The method of claim 15, wherein less than 20,000 particulates per gram of bisphenol are added in the desorber column.

28. A facility for separation of an adduct of a dihydric phenol and phenol into separate streams of dihydric phenol and phenol, comprising a source of the adduct and a desorber column connected to the source of adduct, said desorber column being packed with a non-aggregate packing material.

29. The facility of claim 28, wherein the non-aggregate packing material is selected from the group consisting of borosilicate galls, stainless steel, zirconia and polytetrafluoroethylene.

30. The facility of claim 28, wherein the non-aggregate packing material is made from borosilicate glass.

31. The facility of claim 28, further comprising a source of stripping gas, connected to the desorber column to introduce stripping gas in counter-current flow to the adduct.

32. The facility of claim 31, wherein the source of stripping gas supplies a stripping gas selected from the group consisting of nitrogen, carbon dioxide and steam.

33. The facility of claim 28, wherein the source of adduct supplies an adduct of bisphenol and phenol.

34. The facility of claim 33, wherein the bisphenol is bisphenol-A.

35. The facility of claim 28, further comprising a ring pump connected to the desorber column for maintaining sub-atmospheric pressure in the desorber column during operation.

36. The facility of claim 35, wherein the non-aggregate packing material is selected from the group consisting of borosilicate galls, stainless steel, zirconia and polytetrafluoroethylene.

37. The facility of claim 35, wherein the non-aggregate packing material is made from borosilicate glass.

38. The facility of claim 35, further comprising a source of stripping gas, connected to the desorber column to introduce stripping gas in counter-current flow to the adduct.

39. The facility of claim 38, wherein the source of stripping gas supplies a stripping gas selected from the group consisting of nitrigen, carbon dioxide and steam.