Ink, image recording process, ink cartridge, recording unit, ink set, crust-preventing method and image forming apparatus

• US 6,547,381 B2
• Filed: 06/18/2001
• Issued: 04/15/2003
• Est. Priority Date: 06/23/2000
• Status: Expired due to Term

• Current Assignee: Canon Kabushiki Kaisha (Canon Inc.)
• Original Assignee: Canon Kabushiki Kaisha (Canon Inc.)
• Inventors: Osumi, Koichi, Watanabe, Tomonari, Mishina, Shinya
• Primary Examiner(s): Vo, Anh T. N.
• Assistant Examiner(s): Shah, Manish S
• Application Number:
  US09/881,803
• Publication Number:
  US 20020036677A1
• Time in Patent Office: 666 Days
• Field of Search: 347/100, 347/101, 347/96, 347/95
• US Class Current: 347/100
• CPC Class Codes: B41J 2/1404 Geometrical characteristics
• CPC Class Codes: B41J 2/1433 Structure of nozzle plates
• CPC Class Codes: B41J 2002/14387 Front shooter
• CPC Class Codes: B41J 2002/14403 including a filter
• CPC Class Codes: B41J 2002/14475 characterised by nozzle shapes or number of orifices per chamber
• CPC Class Codes: C09D 11/324 containing carbon black
• CPC Class Codes: C09D 11/40 Ink-sets specially adapted for multi-colour inkjet printing

Abstract

An ink comprises a coloring material and an aqueous medium wherein the coloring material contains a self-dispersing type carbon black, in which self-dispersing carbon black a hydrophilic group combines with the surface of a carbon black directly or through another atomic group, and which ink contains potassium ion in an amount of 0.6% or more of the weight of the carbon black.

Claims

1. An ink for ink-jet recording, comprising a coloring material and an aqueous medium, wherein the coloring material comprises a self-dispersing carbon black, including a hydrophilic group bound to the surface thereof directly or through another atomic group, the ink further comprising potassium ions in an amount of 0.6 wt % or more based on the weight of the self-dispersing carbon black, wherein the density of said hydrophilic group is at least 1.8 μ

mol/m².

2. The ink according to claim 1, wherein said hydrophilic group is selected from the group consisting of —

COOM, —

SO₃M, —

PO₃HM and —

PO₃M₂, wherein M is selected from the group consisting of hydrogen, alkali metal, ammonium and organic ammonium.

3. The ink according to claim 1 or 2, wherein said potassium ions are present as counter ions to said hydrophilic group.

4. The ink according to claim 1, wherein said potassium ions are derived from potassium hydroxide.

5. The ink according to claim 1, wherein pH of the ink is in the range of from 7 to 10.

6. The ink according to claim 1, wherein the ink contains monovalent cations of from 0.05 mol/L to 1 mol/L.

7. The ink according to claim 6, wherein said monovalent cation comprises potassium ions and at least one selected from the group consisting of alkali metal ions, ammonium ions and organic ammonium ions.

8. The ink according to claim 6, wherein the ink contains monovalent cations of from 0.1 mol/L to 0.5 mol/L.

9. An image recording process comprising the steps of applying energy to the ink of claim 1, and ejecting the ink from a recording head towards a recording medium.

10. The image recording process according to claim 9, wherein the recording head is capable of ejecting the ink in an amount of 40 ng per dot or less.

11. The image recording process according to claim 9, wherein the recording head has an ink flow path having a site where flow resistance of the ink is greatly changed.

12. The image recording process according to claim 9, wherein said energy is thermal energy.

13. The image recording process according to claim 12, wherein said thermal energy is applied by a heater in an ink flow path.

14. The image recording process according to claim 13, wherein said heater is situated opposite to an ejection opening for the ink.

15. The image recording process according to claim 13, wherein the recording head has a site where the direction of a main flow of the ink changes at an angle of at least 90°

.

16. The image recording process according to claim 9, wherein said energy is mechanical energy.

17. The image recording process according to any one of claims 9 to 16, wherein said recording medium is a plain paper.

18. A recording unit, comprising an ink container containing the ink of claim 1 and a recording head for ejecting the ink in the form of ink droplets by applying energy to the ink.

19. The recording unit according to claim 18, wherein said recording head is capable of ejecting the ink in amount of 40 ng per dot or less.

20. The recording unit according to claim 18, wherein said recording head has an ink flow path having a site where flow resistance of the ink is greatly changed.

21. The recording unit according to claim 18, wherein said energy is thermal energy.

22. The recording unit according to claim 21, wherein said thermal energy is applied by a heater arranged in an ink flow path.

23. The recording unit according to claim 22, wherein said heater is situated opposite to an ejection opening for the ink.

24. The recording unit according to claim 22, wherein said recording head has a site where the direction of a main flow of the ink changes at an angle of at least 90°

.

25. An ink cartridge, comprising an ink container containing the ink of claim 1.

26. An image recording apparatus, comprising a recording unit having an ink container containing the ink of claim 1 and a recording head for ejecting the ink in the form of ink droplets by applying energy to the ink.

27. An image recording apparatus, comprising an ink cartridge equipped with a container containing the ink of claim 1, and a recording head for ejecting the ink in the form of ink droplets by applying energy to the ink.

28. The image recording apparatus according to claim 27, which comprises an ink feed portion for feeding the ink contained in said ink cartridge to said recording head.

29. The image recording apparatus according to claim 26, wherein said recording head is capable of ejecting the ink in an amount of 40 ng per dot or less.

30. The image recording apparatus according to claim 26, wherein said recording head has an ink flow path having a site where flow resistance of the ink is greatly changed.

31. The image recording apparatus according to claim 26, wherein said energy is thermal energy.

32. The image recording apparatus according to claim 31, wherein said thermal energy is applied by a heater arranged in an ink flow path.

33. The image recording apparatus according to claim 32, wherein said heater is situated opposite to an ejection opening for the ink.

34. The image recording apparatus according to claim 32, wherein said recording head has a site where the direction of a main flow of the ink changes at an angle of at least 90°

.

35. A method of lessening crusting on a recording head comprising ejecting the ink of claim 1 from the recording head by applying energy to the ink.

36. An ink set, comprising in combination an ink comprising a coloring material selected from the group consisting of respective coloring materials for cyan, magenta, yellow, red, green and blue colors, and the ink of claim 1.

37. A method of lessening crusting on an ink-jet recording head equipped with an ink-ejection opening at a position opposite to an ink ejecting pressure-generating element in an ink-jet recording process comprising the step of ejecting the ink of claim 1 by means of the recording head.

38. A method of lessening crusting on an ink-jet recording head which has an ink flow path having a site where flow resistance of a liquid is greatly changed in an ink-jet recording process comprising the step of ejecting the ink of claim 1 by means of the recording head.

39. The method of lessening crusting according to claim 38, wherein the site where the flow resistance of the liquid is greatly changed is a portion changing the direction of the main flow of the liquid at an angle of at least 90°

.

40. A method of improving intermittent ejection stability in an ink-jet recording process comprising the step of repeating a process of applying energy to the ink of claim 1 to eject the ink from a recording head by an ink-jet system at a prescribed time interval.

41. A method of improving an intermittent ejection stability in an ink-jet recording process comprising the step of ejecting the ink of claim 1 plural times at a prescribed interval using a recording head which ejects the ink in a direction opposite to an ink ejecting pressure-generating element.

42. A method of improving an intermittent ejection stability in an ink-jet recording process comprising the step of ejecting the ink of claim 1 plural times at a prescribed time interval using an ink-jet recording head having an ink flow path having a site where flow resistance of a liquid is greatly changed.

43. The method of improving an intermittent ejection stability according to claim 42, wherein the site where the flow resistance of the liquid is greatly changed is a portion changing the direction of the main flow of the liquid at an angle of at least 90°

.

44. An image recording apparatus, comprising an ink container containing ink and a recording head for ejecting the ink in the form of ink droplets, the recording head provided with an ejection-energy-generating element for applying ejection-energy to the ink,

the ink comprising a coloring material and an aqueous medium wherein the coloring material comprises a self-dispersing carbon black, including a hydrophilic group bound to the surface thereof directly or through another atomic group, and wherein the ink comprises potassium ions in an amount of 0.6 wt % or more based on the weight of the self-dispersing carbon black, and

the recording head includes at least one site selected from the group consisting of:

(i) a site where the direction of a main flow of the ink changes at an angle of at least 90°

, the site being located upstream of the ejection-energy generating element; and

(ii) a site where the width of a main flow of the ink is 20 μ

m or less.