Solid oxide fuel cell having a monolithic heat exchanger and method for managing thermal energy flow of the fuel cell

• US 6,551,734 B1
• Filed: 10/27/2000
• Issued: 04/22/2003
• Est. Priority Date: 10/27/2000
• Status: Expired due to Fees

• Current Assignee: Delphi Technologies, Inc. (BorgWarner Incorporated)
• Original Assignee: Delphi Technologies, Inc. (BorgWarner Incorporated)
• Inventors: Thomas, Stephen M., Simpkins, Haskell, Labarge, William J.
• Primary Examiner(s): Ryan, Patrick
• Assistant Examiner(s): Cantelmo, Gregg
• Application Number:
  US09/699,275
• Time in Patent Office: 907 Days
• Field of Search: 429/13, 429/26, 429/30, 429/34
• US Class Current: 429/436
• CPC Class Codes: F28D 2021/0029 Heat sinks
• CPC Class Codes: F28F 21/04 of ceramic; of concrete; of natural stone
• CPC Class Codes: F28F 7/02 Blocks traversed by passages for heat-exchange media F28D7/0008 takes precedence
• CPC Class Codes: H01M 2300/0074 Ion conductive at high temperature
• CPC Class Codes: H01M 8/04014 Heat exchange using gaseous fluids; Heat exchange by combustion of reactants
• CPC Class Codes: H01M 8/04059 Evaporative processes for the cooling of a fuel cell
• CPC Class Codes: H01M 8/04074 Heat exchange unit structures specially adapted for fuel cell
• CPC Class Codes: H01M 8/12 operating at high temperature, e.g. with stabilised ZrO2 electrolyte
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

A thermal energy management system for solid oxide fuel cells includes a monolithic small cell extrusion type heat exchanger coupled to an SOFC stack. In operation, a flow of air having a selected temperature is passed through the heat exchanger cells and thermal energy flowing into and out of the SOFC stack is managed primarily by radiation coupling between the SOFC stack and the heat exchanger. The system further provides management of the temperature distribution around the SOFC to meet outer skin temperature design targets and to control the inlet gas temperatures for the SOFC. The system provides a compact, efficient method for SOFC thermal energy management and is particularly well suited for transportation applications.

Claims

1. A thermal energy management system for solid oxide fuel cells comprising:

a monolithic heat exchanger comprising an air inlet side, an air outlet side, and a plurality of cells for passing a flow of air therethrough;

said heat exchanger being coupled to an SOFC stack; and

a material disposed between said SOFC stack and said heat exchanger to control thermal coupling between said SOFC stack and said heat exchanger;

wherein in operation, a flow of inlet air having a selected temperature is passed through said heat exchanger cells and thermal energy flowing into and out of said SOFC stack is managed primarily by radiation coupling between said SOFC stack and said heat exchanger.

2. The thermal energy management system of claim 1, wherein said heat exchanger comprises ceramics, zirconium phosphate, silicon nitride, aluminum nitride, molybdenum disilicide, zirconia toughened aluminum oxide, aluminum phosphate, zirconium oxide, titanium carbide, aluminum oxide, zirconium carbide, zirconium disilicide, alumino-silicates, cordierite or silicon carbide.

3. The thermal energy management system of claim 1, wherein said heat exchanger preheats or cools one or a combination of input fuel stream and oxidizing gas stream feeding said SOFC stack.

4. The thermal energy management system of claim 1, further comprising:

an air gap provided between said SOFC stack and said heat exchanger and configured to control thermal coupling between said SOFC stack and said heat exchanger.

5. The thermal energy management system of claim 1, further comprising:

a material disposed between said SOFC stack and said heat exchanger to control thermal coupling between said SOFC stack and said heat exchanger; and

an air gap disposed between said SOFC stack and said heat exchanger and configured to control thermal coupling between said SOFC stack and said heat exchanger.

6. The thermal energy management system of claim 1, wherein said material is selected from the group consisting of a high emissivity material, a metal wall, metal media, or particles selected from the group consisting of silicon, silicon/boron/carbon oxide (Si_wB_xC_yO_z), aluminum nitride, aluminum borate, silicon nitride, boron carbide/aluminum-silicon, silicon carbide, aluminum/silicon alloy, iron/silicon alloy, boron carbide cermet with aluminum oxide, nickel/aluminum alloy, or a combination thereof.

12. The method of claim 1, wherein said material is selected from the group consisting of a high emissivity material, a metal wall, metal media, or particles selected from the group consisting of silicon, silicon/boron/carbon oxide (Si_wB_xC_yO_z), aluminum nitride, aluminum borate, silicon nitride, boron carbide/aluminum-silicon, silicon carbide, aluminum/silicon alloy, iron/silicon alloy, boron carbide cermet with aluminum oxide, nickel/aluminum alloy, or a combination thereof.

7. A method for managing the thermal energy flowing into and out of an SOFC system comprising:

coupling a heat exchanger to an SOFC stack, said monolithic heat exchanger comprising an air inlet side for introducing a flow of air, a plurality of cells for passing a flow of air therethrough, and an air outlet side for discharging said flow of air;

disposing a material between said SOFC stack and said heat exchanger and configuring said material to control thermal coupling between said SOFC stack and said heat exchanger; and

passing said air having a selected temperature through said heat exchanger cells so as to manage thermal energy flowing into and out of said SOFC stack primarily by radiation coupling between said SOFC stack and said heat exchanger.

8. The method of claim 7, wherein said heat exchanger comprises ceramics, zirconium phosphate, silicon nitride, aluminum nitride, molybdenum disilicide, zirconia toughened aluminum oxide, aluminum phosphate, zirconium oxide, titanium carbide, aluminum oxide, zirconium carbide, zirconium disilicide, alumino-silicates, cordierite or silicon carbide.

9. The method of claim 7, further comprising:

preheating or cooling one or a combination of input fuel stream and oxidizing gas stream feeding said SOFC stack with said heat exchanger.

10. The method of claim 7, further comprising:

providing an air gap between said SOFC stack and said heat exchanger and configuring said air gap to control thermal coupling between said SOFC stack and said heat exchanger.

11. The method of claim 7, further comprising:

providing an air gap between said SOFC stack and said heat exchanger and configuring said air gap to control thermal coupling between said SOFC stack and said heat exchanger; and

disposing a material between said SOFC stack and said heat exchanger and configuring said material to control thermal coupling between said SOFC stack and said heat exchanger.

13. A thermal energy management system for solid oxide fuel cells comprising:

an extruded ceramic monolithic heat exchanger comprising an air inlet side, an air outlet side, and a plurality of cells for passing a flow of air therethrough;

said heat exchanger being coupled to an SOFC stack; and

a material disposed between said SOFC stack and said heat exchanger to control thermal coupling between said SOFC stack and said heat exchanger;

wherein in operation, a flow of inlet air having a selected temperature is passed through said heat exchanger cells and thermal energy flowing into and out of said SOFC stack is managed primarily by radiation coupling between said SOFC stack and said heat exchanger.

14. The thermal energy management system of claim 13, further comprising:

an air gap disposed between said SOFC stack and said heat exchanger and configured to control thermal coupling between said SOFC stack and said heat exchanger.

15. The thermal energy management system of claim 13, wherein said material is selected from the group consisting of a high emissivity material, a metal wall, metal media, or particles selected from the group consisting of silicon, silicon/boron/carbon oxide (Si_wB_xC_yO_z), aluminum nitride, aluminum borate, silicon nitride, boron carbide/aluminum-silicon, silicon carbide, aluminum/silicon alloy, iron/silicon alloy, boron carbide cermet with aluminum oxide, nickel/aluminum alloy, or a combination thereof.

16. The thermal energy management system of claim 13, wherein said extruded ceramic heat exchanger is an extruded cordierite ceramic heat exchanger.

17. A method for managing the thermal energy flowing into and out of an SOFC system comprising:

coupling an extruded ceramic monolithic heat exchanger to an SOFC stack, said heat exchanger comprising an air inlet side for introducing a flow of air, a plurality of cells for passing a flow of air therethrough, and an air outlet side for discharging said flow of air;

disposing a material between said SOFC stack and said heat exchanger and configuring said material to control thermal coupling between said SOFC stack and said heat exchanger; and

passing said air having a selected temperature through said heat exchanger cells so as to manage thermal energy flowing into and out of said SOFC stack primarily by radiation coupling between said SOFC stack and said heat exchanger.

18. The method of claim 17, further comprising:

providing an air gap between said SOFC stack and said heat exchanger and configuring said air gap to control thermal coupling between said SOFC stack and said heat exchanger.

19. The method of claim 17, wherein said material is selected from the group consisting of a high emissivity material, a metal wall, metal media, or particles selected from the group consisting of silicon, silicon/boron/carbon oxide (Si_wB_xC_yO_x), aluminum nitride, aluminum borate, silicon nitride, boron carbide/aluminum-silicon, silicon carbide, aluminum/silicon alloy, iron/silicon alloy, boron carbide cermet with aluminum oxide, nickel/aluminum alloy, or a combination thereof.

20. The method of claim 17, wherein said extruded ceramic heat exchanger is an extruded cordierite ceramic heat exchanger.