Organic electroluminescent device

• US 6,552,488 B1
• Filed: 08/24/1999
• Issued: 04/22/2003
• Est. Priority Date: 08/24/1999
• Status: Expired due to Term

• Current Assignee: InnoLux Corporation
• Original Assignee: Agilent Technologies, Inc.
• Inventors: Roitman, Daniel B., Hargreaves, John S., Antoniadis, Homer, Seaward, Karen L.
• Primary Examiner(s): Patel, Ashok
• Application Number:
  US09/382,025
• Time in Patent Office: 1,337 Days
• Field of Search: 313/500, 313/503, 313/504, 313/506, 313/112, 313/512, 445/24, 427/66, 427/69, 427/58, 427/67, 345/45, 345/76
• US Class Current: 313/512
• CPC Class Codes: H01J 37/32082 Radio frequency generated discharge H01J37/32357, H01J37/32366, H01J37/32394 and H01J37/32403 take precedence
• CPC Class Codes: H10K 2102/3026 Top emission
• CPC Class Codes: H10K 50/844 Encapsulations
• CPC Class Codes: H10K 50/87 Arrangements for heating or cooling
• CPC Class Codes: H10K 59/12 Active-matrix OLED [AMOLED] displays
• CPC Class Codes: H10K 59/38 comprising colour filters or colour changing media [CCM]

Abstract

A color organic electroluminescent device includes color filters, light emitting layers and substrate integrated into a single assembly, with the light emitting layers lying between the substrate and the color filters. Unlike color electroluminescent devices where an image must be viewed through a transparent substrate, or where color filters are deposited upon another device and later combined with the assembly, the present disclosure calls for a transparent protective layer of silicon nitride or a similar material to be deposited over the light emitting layers to protect the light emitting layers from oxygen and moisture, and to serve as a platform for color filters. In order to achieve sufficient density in the protective layer and avoid defects, a cold plasma deposition or similar process is used for deposition of the protective layer. By viewing light through this protective layer instead of a substrate, nearly any substrate can be used.

Claims

1. In an organic electroluminescent device having a substrate, light emitting layers on top of the substrate, the light emitting layers including two electrode layers and an organic electroluminescent material therebetween, and at least one color filter, an improvement comprising:

creating a transparent protective layer on top of the light emitting layers, such that the light emitting layers lie between the substrate and the transparent protective layer; and

layering the color filter above the transparent protective layer, such that both the light emitting layers and the transparent protective layer lie in between the substrate and the color filter.

2. An improvement according to claim 1, wherein the transparent protective layer is impermeable to moisture.

3. An improvement according to claim 1, wherein the transparent protective layer comprises a layer of material chosen from the group consisting of aluminum dioxide, silicon dioxide, silicon oxynitride and silicon nitride, the layer being sufficiently dense to prevent moisture from passing therethrough.

4. An improvement according to claim 1, wherein the device comprises an addressable organic electroluminescent device.

5. An improvement according to claim 4, wherein the addressable organic electroluminescent device utilizes active matrix addressing.

6. An improvement according to claim 1, further comprising:

forming the device to be an organic electroluminescent device that generates a single color of light;

layering at least two color filters above the protective layer, each of the at least two color filters generating a color component of light from the single color.

7. An improvement according to claim 6, wherein the single color of light is white light.

8. An improvement according to claim 1, wherein the substrate is opaque.

9. An improvement according to claim 8, wherein the opaque substrate comprises internal vias for electrical connection.

10. An improvement according to claim 1, wherein the protective layer is between five hundred Angstroms and one micron in thickness.

11. An organic electroluminescent device, comprising:

a substrate;

a first electrode above the substrate, the first electrode being one of a cathode and an anode;

an organic electroluminescent material layer above the first electrode;

a second, transparent electrode above the organic electroluminescent layer, the second, transparent electrode being the other of the cathode and the anode;

a transparent protective layer above the second, transparent electrode; and

at least one color filter above the protective layer.

12. A device according to claim 11, wherein the transparent protective layer includes one of silicon nitride, aluminum dioxide and silicon dioxide, and has a density sufficient to prevent moisture from passing therethrough.

13. A device according to claim 11, wherein the device is an addressable electroluminescent device having multiple pixels and generates a single color of light, each pixel including at least two portions that each produce light of different colors from the single color, said device further comprising at least two color filters per pixel, the color filters positioned above the protective layer and side by side such that the first portion includes one color filter that generates a first color from the single color, and the second portion includes another color filter and generates a second, different color of light from the single color.

14. A device according to claim 13, wherein each color filter produces a primary color of light.

15. A device according to claim 11, wherein the transparent protective layer is substantially silicon nitride and has a thickness of between five hundred Angstroms and one micron.

16. A method of creating an organic electroluminescent device, using a substrate, light emitting layers including two electrodes and an organic electroluminescent material, a color filter and a transparent protective layer, said method comprising:

depositing the light emitting layers above the substrate;

creating the transparent protective layer above the light emitting layers, such that the light emitting layers are between the transparent protective layer and the substrate; and

layering the color filter above the protective layer, such that the light emitting layers and the protective layer are between the color filter and the substrate.

17. A method according to claim 16, wherein the organic electroluminescent material produces white light and wherein:

layering the color filter includes placing at least three separate color filters above the protective layer, such that each color filter produces light of a primary color by filtering light from the white light.

18. A method of creating an organic electroluminescent device, using a substrate, light emitting layers including two electrodes and an organic electroluminescent material, a color filter and a transparent protective layer, said method comprising:

depositing the light emitting layers above the substrate,

creating the transparent protective layer above the light emitting layers, such that the light emitting layers are between the transparent protective layer and the substrate; and

layering the color filter above the protective layer, such that the light emitting layers and the protective layer are between the color filter and the substrate, wherein, creating the transparent protective layer includes depositing the transparent protective layer using a deposition process upon the device including the organic electroluminescent material, but where the device is not heated above one hundred and forty degrees Celsius.

19. A method according to claim 18, wherein the deposition process is a plasma deposition process.