Method of making electroluminescent devices having varying electrical and/or optical properties

• US 6,558,219 B1
• Filed: 09/06/2000
• Issued: 05/06/2003
• Est. Priority Date: 03/13/1998
• Status: Expired due to Term

• Current Assignee: IPIFS Guarantee Corp.
• Original Assignee: Cambridge Display Technology Limited (Sumitomo Chemical Company Limited)
• Inventors: Pichler, Karl, Burroughes, Jeremy Henley, Ho, Peter, Bright, Christopher John
• Primary Examiner(s): Ramsey, Kenneth J.
• Assistant Examiner(s): HAYNES, MACK NELSON
• Application Number:
  US09/656,227
• Time in Patent Office: 972 Days
• Field of Search: 445/24, 427/66, 313/504, 313/506, 313/507, 428/690, 428/917
• US Class Current: 445/24
• CPC Class Codes: B82Y 10/00 Nanotechnology for information processing, storage or transmission, e.g. quantum computing or single electron logic
• CPC Class Codes: B82Y 30/00 Nanotechnology for materials or surface science, e.g. nanocomposites
• CPC Class Codes: H05B 33/10 Apparatus or processes specially adapted to the manufacture of electroluminescent light sources
• CPC Class Codes: H10K 50/11 characterised by the electroluminescent [EL] layers
• CPC Class Codes: H10K 85/111 comprising aromatic, heteroaromatic, or aryl chains, e.g. polyaniline, polyphenylene or polyphenylene vinylene
• CPC Class Codes: H10K 85/1135 Polyethylene dioxythiophene [PEDOT]; Derivatives thereof
• CPC Class Codes: H10K 85/114 Poly-phenylenevinylene; Derivatives thereof
• CPC Class Codes: H10K 85/115 Polyfluorene; Derivatives thereof
• CPC Class Codes: H10K 85/141 comprising aliphatic or olefinic chains, e.g. poly N-vinylcarbazol, PVC or PTFE
• CPC Class Codes: H10K 85/151 Copolymers
• CPC Class Codes: H10K 85/631 Amine compounds having at least two aryl rest on at least one amine-nitrogen atom, e.g. triphenylamine

Abstract

A method of forming an electroluminescent device, including the steps of forming a first charge carrier injecting layer for injecting charge carriers of a first polarity, forming an organic charge carrier transport layer over the first charge carrier injecting layer, the transport layer having an electronic and/or optical property which varies across the thickness of the transport layer, forming an organic light emissive layer over the transport layer, and forming a second charge carrier injecting layer over the light emissive layer for injecting charge carriers of a second polarity.

Claims

1. A method of forming an electroluminescent device, comprising the steps of:

forming a first charge carrier injecting layer for injecting charge carriers of a first polarity;

forming an organic charge carrier transport layer over the first charge carrier injecting layer, the transport layer having an electronic property and/or an optical property which varies across the thickness of the transport layer;

forming an organic light emissive layer over the transport layer; and

forming a second charge carrier injecting layer over the light emissive layer for injecting charge carriers of a second polarity.

2. A method as claimed in claim 1, wherein the step of forming a transport layer comprises the steps of depositing the transport layer and processing the transport layer to create the spatial variation in the said electronic and/or optical property.

3. A method as claimed in claim 2, wherein the transport layer comprises a conjugated material and the step of creating the variation in the electronic property and/or optical property comprises reducing the degree of conjugation of the conjugated material.

4. method as claimed in claim 2, wherein the step of processing the transport layer comprises exposing the transport layer to a reactive agent to promote a chemical reaction in the transport layer.

5. A method as claimed in claim 4, wherein the reaction is an oxidation reaction or reduction reaction.

6. A method as claimed in claim 4, wherein the reactive agent is an oxidising agent.

7. A method as claimed in claim 4, wherein the reactive agent is oxygen.

8. A method as claimed in claim 4, wherein the reactive agent is in the form of a plasma.

9. A method as claimed in claim 1, wherein the step of forming a transport layer comprises depositing the transport layer in a state in which the said electronic property or optical property varies across its thickness.

10. A method as claimed in claim 9, comprising the step of depositing the transport layer by a self-assembly method.

11. A method as claimed in claim 1, comprising the step of depositing the transport layer in the form of a series of sub-layers.

12. A method as claimed in claim 1, comprising the step of depositing the transport layer in the form of a series of bilayers each bilayer containing two sub-layers of different materials.

13. A method as claimed in claim 1, comprising the step of depositing the transport layer so as to comprise a series of sub-layers of a material wherein each sub-layer differs in electronic property and/or optical property.

14. A method as claimed in claim 13, wherein the said sub-layers of a material are graded in the said property across the thickness of the transport layer.

15. method as claimed in claim 13, wherein the said material comprises poly(styrenesulphonic acid).

16. A method as claimed in claim 15, wherein in at least some of the sub-layers the poly(styrenesulphonic acid) is doped with poly(ethylenedioxythiophene).

17. A method as claimed in claim 13, comprising the step of doping the sub-layers so as to achieve the difference in the electronic property and/or optical property.

18. A method as claimed in claim 1, wherein the electronic property is an energy level or energy level distribution.

19. A method as claimed in claim 18, wherein the electronic property is ionisation potential.

20. A method as claimed in claim 1, wherein in a direction from the first charge carrier injecting layer to the light emissive layer the ionisation potential of the transport layer varies away from the conduction band of the first charge carrier injecting layer.

21. A method as claimed in claim 1, wherein the charge carriers of a first polarity are positive charge carriers.

22. A method as claimed in claim 1, wherein in a direction from the first charge carrier injecting layer to the light emissive layer the ionisation potential varies towards the HOMO level of the light emissive layer.

23. A method as claimed in claim 1, wherein the transport layer comprises at least one of poly(styrenesulphonic acid) doped poly(ethylenedioxythiophene), BFA, polyaniline, and PPV.

24. A method of forming an electroluminescent device, comprising:

forming a first charge carrier injecting layer for injecting positive charge carriers;

forming an organic light emissive layer over the first charge carrier injecting layer, an electronic property and/or an optical property of the light emissive layer varying across the thickness of the emissive layer; and

forming a second charge injecting layer over the light emissive layer for injecting negative charge carriers.

25. A method as claimed in claim 24, wherein the step of forming a light emissive layer comprises the steps of depositing the emissive layer and processing the emissive layer to create the variation in the electronic property and/or optical property across the thickness of the emissive layer.

26. A method as claimed in claim 25, wherein the step of processing the emissive layer comprises exposing the emissive layer to a reactive agent to promote a chemical reaction in the emissive layer.

27. A method as claimed in claim 26, wherein the reaction is an oxidation reaction or a reduction reaction.

28. A method as claimed in claim 26, wherein the reactive agent is an oxidising agent.

29. A method as claimed in claim 26, wherein the reactive agent is oxygen.

30. A method as claimed in claim 26, wherein the reactive agent is in the form of a plasma.

31. A method as claimed in claim 25, wherein the emissive layer comprises a conjugated material and the step of creating the variation in the electronic property and/or optical property comprises reducing the degree of conjugation of the conjugated material.

32. A method as claimed in claim 25, wherein the light emissive layer has an optical gap that varies in a direction from the first charge carrier injecting layer to the second charge carrier injecting layer.

33. A method of forming an electroluminescent device comprising a first charge carrier injecting layer for injecting charge carriers of a first polarity, a second charge carrier injecting layer for injecting charge carriers of a second polarity and at least one organic layer located between the charge carrier injecting layers, the method comprising the step of at least partially oxidizing or reducing the organic layer.

34. A method as claimed in claim 33, wherein the oxidation or reduction provides a variation in an electronic property or optical property across the thickness of the organic layer.

35. A method as claimed in claim 33, wherein the organic layer is a charge transport layer.

36. A method as claimed in claim 33, wherein the organic layer is a light emissive layer.

37. A method as claimed in claim 33, wherein the step of oxidizing or reducing the organic layer comprises exposing the organic layer to an oxidising agent or a reducing agent.

38. A method as claimed in claim 37, wherein the oxidising agent or reducing agent is a reactive oxidizing agent or reducing agent.

39. A method as claimed in claim 38, wherein the oxidizing agent or reducing agent is an oxygen plasma.

40. A method as claimed in claim 33, wherein the step of oxidizing or reducing the organic layer comprises exposing the organic layer to light to perform a photo-oxidization process.

41. A method as claimed in claim 37, wherein the step of exposing comprises exposing a major surface of the organic layer.

42. A method as claimed in claim 33, wherein the step of oxidizing or-reducing the organic layer comprises creating a gradation of oxidation through at least part of the thickness of the layer.

43. A method as claimed in claim 42, wherein the gradation of oxidation results in a gradation of an electronic property and/or optical property.

44. A method as claimed in claim 43, wherein the property is an ionisation potential.

45. An electroluminescent device comprising:

a first charge carrier injecting layer for injecting positive charge carriers;

a second charge carrier injecting layer for injecting negative charge carriers;

an organic light emissive layer located between the charge carrier injecting layers; and

an organic charge carrier transport layer located between the light emissive layer and one of the charge carrier injecting layers, and comprising an organic material having an electronic property and/or an optical property which varies across the thickness of the transport layer.

46. An electroluminescent device as claimed in claim 45, wherein the electronic property and/or optical property is an energy level or energy level distribution responsible for transport of charge carriers.

47. An electroluminescent device as claimed in claim 45, wherein the electronic property and/or optical property is an ionisation level.

48. An electroluminescent device as claimed in claim 45, comprising a second organic charge carrier transport layer located between the light emissive layer and the other of the charge carrier injecting layers.

49. An electroluminescent device as claimed in claim 48, wherein the second organic charge carrier transport layer comprises an organic material having an ionisation potential for accepting positive charge carriers from the said other of the charge carrier injecting layers, which varies across the thickness of the second transport layer.

50. An electroluminescent device as claimed in claim 48, wherein the second organic charge carrier transport layer comprises an organic material having an electron affinity for accepting negative charge carriers from the said other of the charge carrier injecting layers, which varies across the thickness of the second transport layer.