Antimicrobial compositions for hard surfaces

• US 6,559,116 B1
• Filed: 09/27/2000
• Issued: 05/06/2003
• Est. Priority Date: 09/27/1999
• Status: Expired due to Term

• Current Assignee: The Procter & Gamble Company
• Original Assignee: The Procter & Gamble Company
• Inventors: Binski, Christopher James, Godfroid, Robert Allen, Morelli, Joseph Paul
• Primary Examiner(s): BOYER, CHARLES I
• Application Number:
  US09/671,080
• Time in Patent Office: 951 Days
• Field of Search: 510/238, 510/384, 510/356, 510/362, 510/365, 510/421, 510/504, 510/237, 510/235, 510/499
• US Class Current: 510/499
• CPC Class Codes: A47L 13/22 with liquid-feeding devices
• CPC Class Codes: A47L 13/256 for mops made of cloth
• CPC Class Codes: A47L 13/51 Storing of cleaning tools, e.g. containers therefor
• CPC Class Codes: A61L 2/18 Liquid substances or solutions comprising solids or dissolved gases
• CPC Class Codes: B05B 9/0861 the motor being electric
• CPC Class Codes: B05B 9/0866 the pump being a gear, centrifugal or screw-type pump
• CPC Class Codes: C11D 17/049 Cleaning or scouring pads; Wipes
• CPC Class Codes: C11D 3/3723 Polyamines or polyalkyleneimines
• CPC Class Codes: C11D 3/48 Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions

Abstract

Antimicrobial, hard surface cleaning compositions that effectively clean and reduce microorganisms on a surface without resulting in unacceptable filming and/or streaking residue on the surface, generally comprise (a) cationic antimicrobial active; (b) nitrogen-containing polymer; and (c) surfactant. Preferred antimicrobial, hard surface cleaning compositions for use in no-rinse cleaning methods comprise (a) from about 0.001% to about 0.5%, by weight of the composition, of surfactant; (b) cationic antimicrobial active; and (c) nitrogen-containing polymer. Methods of cleaning and reducing microorganisms on hard surfaces comprises contacting the surfaces with such compositions and preferably allowing the compositions to dry on the surface without rinsing the composition from the surface using water or other rinsing solution.

Claims

1. An antimicrobial, hard surface cleaning composition comprising:

(a) from about 0.001% to about 15%, by weight of said composition, of a surfactant selected from the group consisting of nonionic surfactant, anionic surfactant, zwitterionic surfactant, amphoteric surfactant, and mixtures thereof,

(b) a cationic antimicrobial active;

(c) a nitrogen-containing polymer, wherein said nitrogen-containing polymer is selected from the group consisting of;

(i) polyalkyleneimines;

(ii) modified polyamines having the formulae;

(aa) (PA)_w(T)_x;

(bb) (PA)_w(L)_z;

or

(cc) [(PA)_w(T)_x]_y[L]_z; and

(iii) mixtures thereof;

 

wherein PA is a grafted or non-grafted modified or unmodified polyamine backbone unit, T is an amide forming polycarboxylate crosslinking unit, and L is a non-amide forming crosslinking unit, provided that for compounds of type (i) and (iii) the indices w and x have values such that the ratio of w to x is from 0.8;

1 to 1.5;

1;

for compounds of type (ii) the indices w and z have values such that said modified polyamine compounds comprises from about 0.05 to about 2 parts by weight of said L unit;

for compounds of type (iii) the indices y and z have values such that said modified polyamine compound comprises from about 0.05 to about 2 parts by weight of said L unit; and

(d) aqueous carrier comprising water and optional organic solvent.

2. A cleaning composition according to claim 1, wherein said cationic antimicrobial active is selected from the group consisting of quaternary ammonium antimicrobial active, biguanide antimicrobial active, and mixtures thereof.

3. A cleaning composition according to claim 2, wherein said cationic antimicrobial active comprises at least one quaternary ammonium antimicrobial active and at least one biguanide antimicrobial active.

4. A cleaning composition according to claim 3, wherein said cationic antimicrobial active comprises didecyldimethylammonium chloride and chlorhexidine diacetate.

5. A cleaning composition according to claim 1, wherein said cationic antimicrobial active is present at a level of from about 0.005% to about 10%, by weight of the composition.

6. A cleaning composition according to claim 5, wherein said cationic antimicrobial active is present at a level of from about 0.005% to about 5%, by weight of the composition.

7. A cleaning composition according to claim 1, wherein said nitrogen-containing polymer has a molecular weight of from about 50,000 to about 15,000,000 Daltons.

8. A cleaning composition according to claim 7, wherein said nitrogen-containing polymer has a molecular weight of from about 350,000 to about 15,000,000 Daltons.

9. A cleaning composition according to claim 1, wherein said nitrogen-containing polymer is present at level of from about 0.005% to about 10%, by weight of said composition.

10. A cleaning composition according to claim 9, wherein said nitrogen-containing polymer is present at a level of from about 0.005% to about 5%, by weight of said composition.

11. A cleaning composition according to claim 1, wherein said nitrogen-containing polymer contains basic nitrogen groups.

12. A cleaning composition according to claim 1, wherein said nitrogen-containing polymer is essentially free of quaternary ammonium groups.

13. A cleaning composition according to claim 1, wherein said cleaning composition comprises from about 50% to about 99.99%, by weight of said composition, of aqueous carrier;

and wherein said aqueous carrier comprises from about 50% to about 100%, by weight of said aqueous carrier, of water and from about 0% to about 50%, by weight of said aqueous carrier, of solvent.

14. A cleaning composition according to claim 13, wherein said solvent is selected from the group consisting of propoxy propanol, butoxypropanol, isopropanol, and mixtures thereof.

15. A cleaning composition according to claim 1, wherein said composition provides a contact angle of less than about 30°

, as measured according to the Contact Angle Measurement Test Method.

16. A method of cleaning a hard surface and reducing microorganisms on said surface, said method comprising the step of contacting said surface with an antimicrobial, hard surface cleaning composition according to claim 1.

17. A cleaning composition according to claim 1, wherein said surfactant is present at a level of from about 0.001% to about 0.5%, by weight of the composition.

18. A cleaning composition according to claim 17, wherein said surfactant is present at a level of from about 0.005% to about 0.3%, by weight of the composition.

19. A cleaning composition according to claim 1, wherein said surfactant is a nonionic surfactant.

20. A cleaning composition according to claim 19, wherein said nonionic surfactant is an alcohol alkoxylate surfactant.

21. A cleaning composition according to claim 6, wherein said cationic antimicrobial active is present at a level of from about 0.005% to about 1%, by weight of the composition.

22. A cleaning composition according to claim 21, wherein said cationic antimicrobial active is present at a level of from about 0.005% to about 0.5%, by weight of the composition.

23. A cleaning composition according to claim 10, wherein said nitrogen-containing polymer is present at level of from about 0.005% to about 1%, by weight of said composition.

24. A cleaning composition according to claim 23, wherein said nitrogen-containing polymer is present at a level of from about 0.005% to about 0.3%, by weight of said composition.

25. A cleaning composition according to claim 1, wherein said cleaning composition comprises from about 98% to about 99.99%, by weight of said composition, of aqueous carrier;

and wherein said aqueous carrier comprises from about 50% to about 100%, by weight of said aqueous carrier, of water and from about 0% to about 50%, by weight of said aqueous carrier, of solvent.

26. A cleaning composition according to claim 25, wherein said solvent is selected from the group consisting of propoxy propanol, butoxypropanol, isopropanol, and mixtures thereof.

27. A cleaning composition according to claim 1, wherein said composition provides a contact angle of less than about 30°

, as measured according to the Contact Angle Measurement Test Method.

28. A cleaning composition according to claim 1, wherein said composition further comprises one or more additional components selected from the group consisting of suds suppressor, buffer, perfume, colorant, and mixtures thereof.

29. A method of cleaning a hard surface and reducing microorganisms on said surface, said method comprising the steps of:

contacting said surface with an antimicrobial, hard surface cleaning composition comprising;

(a) from about 0.001% to about 15%, by weight of said composition, of a surfactant selected from the group consisting of nonionic surfactant, anionic surfactant, zwitterionic surfactant, amphoteric surfactant, and mixtures thereof;

(b) a cationic antimicrobial active;

(c) a nitrogen-containing polymer, wherein said nitrogen-containing polymer is selected from the group consisting of;

(i) polyalkyleneimines;

(ii) modified polyamines having the formulae;

(aa) (PA)_w(T)_x;

(bb) (PA)_w(L)_z;

or

(cc) [(PA)_w(T)_x]_y[L]_z; and

(iii) mixtures thereof;

 

wherein PA is a grafted or non-grafted modified or unmodified polyamine backbone unit, T is an amide forming polycarboxylate crosslinking unit, and L is a non-amide forming crosslinking unit, provided that for compounds of type (i) and (iii) the indices w and x have values such that the ratio of w to x is from 0.8;

1 to 1.5;

1;

for compounds of type (ii) the indices w and z have values such that said modified polyamine compounds comprises from about 0.05 to about 2 parts by weight of said L unit;

for compounds of type (iii) the indices y and z have values such that said modified polyamine compound comprises from about 0.05 to about 2 parts by weight of said L unit; and

(d) aqueous carrier comprising water and optional organic solvent; and

 

allowing said composition to dry on said surface without rinsing said surface with a rinse solution comprising water.

30. The method of claim 29, wherein said method further comprises the step of wiping said surface with an absorbent pad, said absorbent pad having a t₁₂₀₀ absorbent capacity of at least about 1 g/g.

31. The method of claim 30, wherein said surface is wiped to dryness with said absorbent pad.

32. The method of claim 30, wherein said absorbent pad comprises superabsorbent material.

39. The method of claim 30, wherein said absorbent pad has a t₁₂₀₀ absorbent capacity of at least about 5 g/g.

40. The method of claim 39, wherein said absorbent pad has a t₁₂₀₀ absorbent capacity of at least about 10 g/g.

33. A method of cleaning a hard surface and reducing microorganisms on said surface, said method comprising the step of contacting said surface with an antimicrobial, hard surface cleaning composition comprising:

(a) from about 0.001% to about 15%, by weight of said composition, of a surfactant selected from the group consisting of nonionic surfactant, anionic surfactant, zwitterionic surfactant, amphoteric surfactant, and mixtures thereof;

(b) a cationic antimicrobial active;

(c) a nitrogen-containing polymer wherein said nitrogen-containing polymer is selected from the group consisting of;

(i) polyalkyleneimines;

(ii) modified polyamines having the formulae;

(aa) (PA)_w(T)_x;

(bb) (PA)_w(L)_z;

or

(cc) [(PA)_w(T)_x]_y[L]_z; and

(iii) mixtures thereof;

 

wherein PA is a grafted or non-grafted modified or unmodified polyamine backbone unit, T is an amide forming polycarboxylate crosslinking unit, and L is a non-amide forming crosslinking unit, provided that for compounds of type (i) and (iii) the indices w and x have values such that the ratio of w to x is from 0.8;

1 to 1.5;

1;

for compounds of type (ii) the indices w and z have values such that said modified polyamine compounds comprises from about 0.05 to about 2 parts by weight of said L unit;

for compounds of type (iii) the indices y and z have values such that said modified polyamine compound comprises from about 0.05 to about 2 parts by weight of said L unit; and

(d) aqueous carrier comprising water and optional organic solvent;

 

wherein said surface is contacted with said composition by spraying said composition onto said surface using a non-manually powered spray dispenser.

34. A method according to claim 33, wherein said spray dispenser is a manually operated trigger spray dispenser.

35. A method according to claim 33, wherein said spray dispenser is a non-manually powered spray dispenser.

36. A method according to claim 35, wherein said non-manually powered spray dispenser is incorporated onto or into a handle of a cleaning implement.

37. A kit for cleaning and reducing microorganisms on hard surfaces, said kit comprising:

a container having therein an antimicrobial, hard surface cleaning composition comprising;

(a) from about 0.001% to about 15%, by weight of said composition, of a surfactant selected from the group consisting of nonionic surfactant, anionic surfactant, zwitterionic surfactant, amphoteric surfactant, and mixtures thereof;

(b) a cationic antimicrobial active;

(c) a nitrogen-containing polymer, wherein said nitrogen-containing polymer is selected from the group consisting of;

(i) polyalkyleneimines;

(ii) modified polyamines having the formulae;

(aa) (PA)_w(T)_x;

(bb) (PA)_w(L)_z;

or

(cc) [(PA)_w(T)_x]_y[L]_z; and

(iii) mixtures thereof;

 

wherein PA is a grafted or non-grafted modified or unmodified polyamine backbone unit, T is an amide forming polycarboxylate crosslinking unit, and L is a non-amide forming crosslinking unit, provided that for compounds of type (i) and (iii) the indices w and x have values such that the ratio of w to x is from 0.8;

1 to 1.5;

1;

for compounds of type (ii) the indices w and z have values such that said modified polyamine compounds comprises from about 0.05 to about 2 parts by weight of said L unit;

for compounds of type (iii) the indices y and z have values such that said modified polyamine compound comprises from about 0.05 to about 2 parts by weight of said L unit; and

(d) aqueous carrier comprising water and optional organic solvent; and

 

a disposable cleaning pad having a t₁₂₀₀ absorbent capacity of at least about 1 g/g.

38. A kit according to claim 37, wherein said kit further comprises a cleaning implement comprising a handle and a mop head, wherein said disposable cleaning pad can be removably attached to said mop head of said cleaning implement.

41. The method of claim 37, wherein said absorbent pad has a t₁₂₀₀ absorbent capacity of at least about 5 g/g.

42. The method of claim 41, wherein said absorbent pad has a t₁₂₀₀ absorbent capacity of at least about 10 g/g.