Method for measuring spectral absorption in a body and device therefor
First Claim
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1. A method of measuring the spectral absorption of a body placed between a source for emitting electromagnetic radiation and a detector for detecting said radiation, the method comprising the following steps:
- emitting said electromagnetic radiation in a determined spectral range towards said body;
filtering the electromagnetic radiation; and
detecting the electromagnetic radiation attenuated by the absorption due the body and deducing therefrom a measure of the spectral absorption of said body, the filtering, and detection steps being combined and implemented by a quantum type detector which presents spectral sensitivity having an absorption front at a given wavelength that corresponds to the bandgap of said detector and delivers a signal corresponding to the electromagnetic energy received by said quantum detector, said method including using the absorption front of the spectral sensitivity of the quantum detector to deduce therefrom the measure of the spectral absorption of the body.
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Abstract
The spectral absorption of a body, placed between a source for emitting electromagnetic radiation and a detector for detecting the radiation, is measured. The technique includes emitting the electromagnetic radiation in a determined spectral range towards the body, filtering the electromagnetic radiation, and detecting the electromagnetic radiation attenuated by the absorption due to the body and deducing therefrom a measure of the spectral absorption of the body. The filtering and detection steps are implemented by a detector of the quantum type. The technique also applies to determining the calorific value of a gas, for measuring the energy of electromagnetic radiation, and an apparatus for implementing the technique.
23 Citations
29 Claims
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1. A method of measuring the spectral absorption of a body placed between a source for emitting electromagnetic radiation and a detector for detecting said radiation, the method comprising the following steps:
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emitting said electromagnetic radiation in a determined spectral range towards said body;
filtering the electromagnetic radiation; and
detecting the electromagnetic radiation attenuated by the absorption due the body and deducing therefrom a measure of the spectral absorption of said body, the filtering, and detection steps being combined and implemented by a quantum type detector which presents spectral sensitivity having an absorption front at a given wavelength that corresponds to the bandgap of said detector and delivers a signal corresponding to the electromagnetic energy received by said quantum detector, said method including using the absorption front of the spectral sensitivity of the quantum detector to deduce therefrom the measure of the spectral absorption of the body. - View Dependent Claims (2, 3, 4, 5, 6, 16, 17, 18, 19, 20, 21, 22)
moving the absorption front of the spectral sensitivity of the quantum detector from a position corresponding to a wavelength λ
0 towards a position corresponding to a wavelength λ
1, both of which wavelengths are included in the spectral range of the emitted electromagnetic radiation; and
combining the signals delivered by the quantum detector for the respective positions of the absorption front corresponding to the wavelengths λ
0 and λ
1 and deducing therefrom the measure of the spectral absorption of the body in the wavelength interval lying between λ
0 and λ
1.
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3. A method according to claim 2, further comprising;
- taking the difference between the signals delivered by the quantum detector for each of the positions of the absorption front corresponding to the wavelengths λ
0 and λ
1.
- taking the difference between the signals delivered by the quantum detector for each of the positions of the absorption front corresponding to the wavelengths λ
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4. A method according to claim 2, further comprising:
- taking the ratio of the signals delivered by the quantum detector for each of the positions of the absorption front corresponding to the wavelengths λ
0 and λ
1.
- taking the ratio of the signals delivered by the quantum detector for each of the positions of the absorption front corresponding to the wavelengths λ
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5. A method according to any one of claims 2 to 4, wherein moving the absorption front of the spectral sensitivity of the quantum detector includes varying a physical parameter on which the position of said absorption front depends.
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6. Application of the method according to claim 1, in which said body is a gas.
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16. Apparatus for measuring the spectral absorption of a body relative to electromagnetic radiation to implement the method according to claim 1 the apparatus comprising:
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at least one source for emitting said electromagnetic radiation over a determined spectral range towards said body;
a quantum type detector for filtering said electromagnetic radiation and for detecting said electromagnetic radiation and delivering an electrical signal representative of the measure of the spectral absorption of said body.
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17. Apparatus according to claim 16, in which the quantum detector presents spectral sensitivity having an absorption front at a given wavelength that corresponds to the bandgap of said detector and delivering a signal corresponding to the electromagnetic energy received by said quantum detector, said apparatus further comprising:
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means for moving the absorption front of the spectral sensitivity of the quantum detector from a position corresponding to a wavelength λ
0 towards a position corresponding to a wavelength λ
1, both of which wavelengths lie in the spectral range of the emitted electromagnetic radiation; and
means for combining the signals delivered by the quantum detector for each of the positions of the absorption front corresponding to the wavelengths λ
0 and λ
1 and for deducing the measure of the spectral absorption of said body in the wavelength interval lying between λ
0 and λ
1.
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18. Apparatus according to claim 17, in which the means for moving the absorption front include means for varying a physical parameter on which the position of said absorption front depends.
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19. Apparatus according to claim 18, in which the physical parameter is temperature and the means for varying the temperature of the quantum detector includes an element powered by a variable electricity source and using Peltier effect junctions with which said quantum detector is maintained in thermal contact together with a thermometer element associated with said quantum detector.
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20. Apparatus according to claim 17, in which the means for combining the signals delivered by the quantum detector at each of the positions of the absorption front corresponding to the wavelengths λ
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0 and λ
1 are constituted by means for taking the difference between said signals.
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0 and λ
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21. Apparatus according to claim 17, in which the means for combining the signals delivered by the quantum detector at each of the positions of the absorption front corresponding to the wavelengths λ
-
0 and λ
1 are constituted by means for taking the ratio of said signals.
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0 and λ
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22. The use of the apparatus according to any one of claims 16 to 21, in which the body is a gas.
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7. A method of determining the calorific value of a gas including fuel components, the method comprising:
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emitting said electromagnetic radiation through said gas in a determined spectral range in which the gas presents absorption;
filtering the electromagnetic radiation; and
detecting the electromagnetic radiation attenuated by the absorption due to the fuel components, said filtering and detection steps being combined and implemented by a quantum type detector which presents spectral sensitivity having an absorption from corresponding to the bandgap of said detector, while successively moving said absorption front of the detector to positions corresponding to successive wavelengths λ
0, . . . , λ
n included is in the spectral range, said detector delivering a signal S(λ
i) corresponding to the electromagnetic energy received by the quantum detector at each of the position of the absorption front at wavelength λ
i;
combining the successive signals delivered by the quantum detector S(λ
i), i=0, . . . , n so as to isolate the spectral absorption of fuel components over each wavelength interval (λ
i;
λ
i+1); and
comparing the above obtained signal combinations with signal combinations previously obtained during a calibration step on a reference gas of known composition, and deducing therefrom the calorific value of the gas. - View Dependent Claims (8, 9, 10, 23, 24, 25, 28, 29)
taking the difference S(λ
i+1)−
S(λ
i) between the signals delivered by the quantum detector at each of the positions of the absorption front corresponding to the successive wavelengths λ
0, . . . λ
n, taken in consecutive pairs.
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9. A method according to claim 7, further comprising:
taking the ratio S(λ
i+1)/S(λ
i) of the signals delivered by the quantum detector at each of the positions of the absorption front corresponding to the successive wavelengths.
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10. A method according to any one of claims 7 to 9, wherein moving the absorption front of the the quantum detector includes varying a physical parameter on which the position of said absorption front depends.
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23. Apparatus for determining the calorific value of a gas constituted by fuel components, by implementing the method according to any one of claims 7 to 9, the apparatus comprising:
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at least one source for emitting said electromagnetic radiation through the gas in a determined spectral range in which the gas presents absorption;
a quantum detector presenting spectral sensitivity that has an absorption front corresponding to the bandgap of said detector for filtering said electromagnetic radiation and for detecting said electromagnetic radiation attenuated by the absorption due to the fuel components;
means for moving said absorption front of the spectral sensitivity of the detector to positions corresponding to successive wavelengths λ
0, . . . , λ
n included in the determined spectral range, said detector delivering a signal S (λ
i) corresponding to the electromagnetic energy received by the quantum detector for each of the positions of the absorption front at wavelength λ
i;
means firstly for combining successive signals delivered by the quantum detector S(λ
i), i=0, . . . , n in such a manner as to isolate the spectral absorption of the fuel components in each wavelength interval (λ
i;
λ
i+1); and
means for comparing the above-obtained signal combinations with signal combinations obtained previously during a calibration step on a reference gas of known composition, and secondly for deducing the calorific value of a gas.
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24. Apparatus according to claim 23, in which the means for combining the signals delivered by the quantum detector for each of the positions of the absorption front corresponding to the successive wavelengths λ
-
0, . . . , λ
n are constituted by means for taking the difference S(λ
i+1)−
S(λ
i) between said signals taken in consecutive pairs.
-
0, . . . , λ
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25. Apparatus according to claim 23, in which the means for combining the signals delivered by the quantum detector for each of the positions of the absorption front corresponding to the successive wavelengths λ
-
0 and λ
1 are constituted by means for taking the ratio S(λ
i+1)/S(λ
i) of said signals taken in consecutive pairs.
-
0 and λ
-
28. Apparatus according to claim 23, in which the means for moving the absorption front are constituted by means for varying a physical parameter on which the position of said absorption front depends.
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29. Apparatus according to claim 28, in which the physical parameter is temperature and the means for varying the temperature of the quantum detector comprise an element powered by a variable electricity source and using Peltier effect junctions with which said quantum detector is maintained in thermal contact together with a thermometer element associated with said quantum detector.
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11. A method of measuring the energy of electromagnetic radiation, the method comprising:
-
emitting said electromagnetic radiation in a determined spectral range;
filtering the electromagnetic radiation; and
detecting the electromagnetic radiation and deducing therefrom a measure of the energy of said electromagnetic radiation, the filtering and detection steps being combined and implemented by a quantum type detector which presents special sensitivity having an absorption front at a given wavelength that corresponds to the bandgap of said detector and delivering a signal corresponding to the electromagnetic energy received by said quantum detector, the method including using the absorption front of the spectral sensitivity of the quantum detector to deduce therefrom the measure of the energy of said electromagnetic radiation. - View Dependent Claims (12, 13, 14, 15)
moving the absorption front of the spectral sensitivity of the quantum detector from a position corresponding to a wavelength λ
0 to a position corresponding to wavelength λ
1 both of which lie in the spectral range of the emitted electromagnetic radiation; and
combining the signals delivered by the quantum detector at each of the positions of the absorption front corresponding to the wavelengths λ
0 and λ
1 and in deducing therefrom the measure of the energy of the electromagnetic radiation in the wavelength interval lying between λ
0 and λ
1.
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13. A method according to claim 12, further comprising;
- taking the difference between the signals delivered by the quantum detector at the positions of the absorption front corresponding to the wavelengths λ
0 and λ
1 respectively.
- taking the difference between the signals delivered by the quantum detector at the positions of the absorption front corresponding to the wavelengths λ
-
14. A method according to claim 12, further comprising:
- taking the ratio of the signals delivered by the quantum detector for each of the positions of the absorption front corresponding to the wavelengths λ
0 and λ
1 respectively.
- taking the ratio of the signals delivered by the quantum detector for each of the positions of the absorption front corresponding to the wavelengths λ
-
15. A method according to any one of claims 12 to 14, wherein moving the absorption front of the spectral sensitivity of the quantum detector includes varying a physical parameter on which the position of said absorption front depends.
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26. Apparatus for measuring the energy of electromagnetic radiation, the apparatus comprising:
-
at least one source for emitting said electromagnetic radiation over a determined spectral range;
a quantum type detector for filtering said electromagnetic radiation and for detecting said electromagnetic radiation and delivering an electrical signal representative of the measure of the energy of said electromagnetic radiation. - View Dependent Claims (27)
means for moving the absorption front of the spectral sensitivity of the quantum detector from a position corresponding to a wavelength λ
0 towards a position corresponding to a wavelength λ
1, both of which wavelengths are included in the spectral range of the emitted electromagnetic radiation; and
means for combining the signals delivered by the quantum detector for each of the positions of the absorption front corresponding to the wavelengths λ
0 and λ
1, and for deducing therefrom the measure of the energy of said electromagnetic radiation in the wavelength interval lying between λ
0 and λ
1.
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Current AssigneeSchlumberger SA (Schlumberger NV)
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Original AssigneeSchlumberger Resource Management Services Incorporated (Schlumberger NV)
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InventorsGrasdepot, François
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Primary Examiner(s)Lee, John R.
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Assistant Examiner(s)SMITH, JOHNNIE L
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Application NumberUS09/744,646Time in Patent Office829 DaysField of Search356/432US Class Current356/432CPC Class CodesG01J 5/20 using resistors, thermistor...G01N 21/3504 for analysing gases, e.g. m...
