Process for producing pulp with a mixture of formic acid and acetic acid as cooking chemical

• US 6,562,191 B1
• Filed: 11/03/2000
• Issued: 05/13/2003
• Est. Priority Date: 05/05/1998
• Status: Expired due to Fees

• Current Assignee: Chempolis Oy
• Original Assignee: Chempolis Oy
• Inventors: Rousu, Päivi, Rousu, Pasi, Rousu, Esa
• Primary Examiner(s): ALVO, MARC S
• Application Number:
  US09/674,678
• Time in Patent Office: 921 Days
• Field of Search: 162/76, 162/70, 162/29, 162/37, 162/16, 162/38, 162/94, 162/95, 162/96, 162/97, 162/98, 162/99, 162/91
• US Class Current: 162/38
• CPC Class Codes: D21C 3/003 with organic compounds D21C3/20 and D21C3/222 take precedence
• CPC Class Codes: D21C 3/20 with organic solvents or in solvent environment

Abstract

A process based on formic acid cooking for producing pulp from herbaceous plants and deciduous trees by using acetic acid as an additional cooking chemical. The obtained pulp can be used in fine paper and board production as short-fibered material, for instance. The invention also relates to a process for adjusting the hemicellulose content of the pulp in connection with the formic acid cooking by using acetic acid as an additional cooking chemical.

Claims

1. A formic acid based cooking process for producing pulp from herbaceous plants and deciduous trees by adjusting the hemicellulose content of pulp, said method comprising:

cooking said pulp in a cooking acid composition at a cooking temperature ranging from 110 to 140°

C. for a cooking time ranging from 20 to 80 minutes,

wherein said cooking acid composition includes formic acid in an amount ranging from 40 to 80% and acetic acid in an amount ranging from 10 to 30%.

2. A process according to claim 1, wherein the cooking temperature ranges from 115to 125°

C.

3. A process according to claim 1, wherein a regenerated mixed acid containing formic acid and acetic acid is used as the cooking acid composition.

4. A process according to claim 3, wherein the regenerated mixed acid is obtained by evaporating the used cooking liquor to a dry solids content of 50 to 80% and distilling the mixture of formic acid, acetic acid and water thus obtained by removing water in a pressure of 2 to 3 bar and recovering the mixture of formic acid and acetic acid for use in cooking.

5. A process according to claim 1, further comprising a pulp bleaching step.

6. A process according to claim 5, further comprising using the pulp in a subsequent papermaking process.

7. A formic acid based cooking process according to claim 1 for producing pulp from herbaceous plants and deciduous trees by adjusting the hemicellulose content of pulp

wherein said cooking acid composition includes acetic acid in an amount ranging from 10 to 15%.

8. A formic acid based cooking process according to claim 1 for producing pulp from herbaceous plants and deciduous trees by adjusting the hemicellulose content of pulp

wherein said pulp is cooked at a cooking pressure ranging from 1.5 to 3 bar.

9. A formic acid based cooking process according to claim 1 for producing pulp from herbaceous plants and deciduous trees by adjusting the hemicellulose content of pulp

wherein regenerated mixed acid containing formic acid and acetic acid included into the spent cooking liquor obtained from the cooking is used as said cooking acid composition.

10. The process according to claim 1, wherein the acetic acid ranges from 10 to 15%.