Land-based desalination using positively buoyant or negatively buoyant/assisted buoyancy hydrate

• US 6,562,234 B2
• Filed: 10/08/2002
• Issued: 05/13/2003
• Est. Priority Date: 07/12/1999
• Status: Expired due to Fees

• Current Assignee: Marine Desalination Systems LLC
• Original Assignee: Marine Desalination Systems LLC
• Inventors: Max, Michael D.
• Primary Examiner(s): Hruskoci, Peter A.
• Application Number:
  US10/266,259
• Publication Number:
  US 20030029713A1
• Time in Patent Office: 217 Days
• Field of Search: 622/39, 622/40, 622/385, 625/32, 625/33, 621/23, 202/83, 202/121, 203/10, 203/100, 210/170, 210/177, 210/181, 210/182, 210/195.1, 210/202, 210/205, 585/15
• US Class Current: 210/170.11
• CPC Class Codes: B01D 2257/504 Carbon dioxide
• CPC Class Codes: B01D 53/62 Carbon oxides
• CPC Class Codes: C02F 1/20 by degassing, i.e. liberation of dissolved gases degasification of liquids in general B01D19/00; arrangement of degassing apparatus in boiler feed supply F22D
• CPC Class Codes: C02F 1/22 by freezing
• CPC Class Codes: C02F 1/26 by extraction
• CPC Class Codes: C02F 1/265 Desalination
• CPC Class Codes: C02F 1/5236 using inorganic agents
• CPC Class Codes: C02F 2103/08 Seawater, e.g. for desalination
• CPC Class Codes: C02F 2103/18 from the purification of gaseous effluents
• CPC Class Codes: Y02A 20/124 Water desalination
• CPC Class Codes: Y02C 20/40 of CO2
• CPC Class Codes: Y10S 203/08 Waste heat
• CPC Class Codes: Y10S 203/11 Batch distillation
• CPC Class Codes: Y10S 203/18 Control

Abstract

Methods and apparatus for desalination of salt water (and purification of polluted water) are disclosed. Salt (or otherwise polluted) water is pumped to a desalination installation and down to the base of a desalination fractionation column, where it is mixed with hydrate-forming gas to form either positively buoyant or negatively buoyant (assisted buoyancy) hydrate. The hydrate rises or is carried upward and dissociates (melts) into the gas and pure water. In preferred embodiments, residual salt water which is heated by heat given off during formation of the hydrate is removed from the system to create a bias towards overall cooling as the hydrate dissociates endothermically at shallower depths. In preferred embodiments, the input water is passed through regions of dissociation in heat-exchanging relationship therewith so as to be cooled sufficiently for hydrate to form at pressure-depth. The fresh water produced by the system is cold enough that it can be used to provide refrigeration, air conditioning, or other cooling; heat removed from the system with the heated residual water can be used for heating or other applications.

Claims

1. An installation for desalinating or purifying saline or otherwise polluted input water, said installation comprising:

a desalination fractionation installation having a lower, hydrate formation region;

an input water conduit which is arranged to provide input water to said hydrate formation region;

a supply conduit which is arranged to provide a hydrate-forming substance to said hydrate formation region;

a hydrate dissociation region disposed at an upper portion of said installation; and

a residual saline or polluted water removal portion that is configured and located so as to remove from said installation residual saline or polluted water that has been warmed by heat of exothermic formation of said hydrate;

wherein said desalination fractionation installation is located in land and comprises a shaft extending downward into the ground to sufficient depth for the weight of water contained therein to naturally produce pressure conditions conducive to formation of hydrate of said hydrate-forming substance at a lower region of said shaft, said hydrate formation region being located within said lower region of said shaft, and

wherein said desalination fractionation installation is configured such that said input water is at least partially cooled toward temperature conditions conducive to formation of hydrate of said hydrate-forming substance before said input water is mixed with said hydrate-forming substance.

2. The installation of claim 1, wherein said hydrate dissociation region comprises a stacked series of canted shelves having apertures therein to permit rising or settling fluid to pass therethrough.

3. The installation of claim 1, wherein said input water conduit passes through said hydrate dissociation region such that water passing through said input water conduit is placed in heat exchanging relationship with hydrate dissociating in said hydrate dissociation region.

4. The installation of claim 3, further comprising supplemental cooling means arranged to cool input water passing through said input water conduit.

5. The installation of claim 1, wherein said lower, hydrate formation region is configured as a hydrate settling catch sump, said installation further comprising a hydrate slurry conduit communicating between said hydrate settling catch sump and said hydrate dissociation region and configured to pump hydrate slurry from said hydrate settling catch sump to said hydrate dissociation region.

6. The installation of claim 5, wherein said dissociation region comprises one of more slurry holding tanks configured to receive hydrate slurry from above, said slurry holding tanks each having one or more conduits extending from dissociation region.

7. The installation of claim 5, further comprising a residual fluid riser conduit communicating with said hydrate settling catch sump and configured to convey away from said hydrate settling catch sump residual fluid displaced by negatively buoyant hydrate settling within said catch sump.

8. The installation of claim 1, wherein said hydrate-forming substance produces hydrate that is negatively buoyant, and

wherein said hydrate dissociation region is laterally displaced relative to said hydrate formation region and is configured to catch negatively buoyant hydrate settling out of residual fluid flowing into said dissociation region, whereby negatively buoyant hydrate is substantially prevented from settling into said hydrate formation region.

9. The installation of claim 8, further comprising a flow diverter region configured to divert upwardly flowing fluid laterally into said hydrate dissociation region.

10. The installation of claim 8, wherein said lower, hydrate formation region comprises a hydrate collection sump, said installation further comprising a hydrate slurry conduit which conveys hydrate slurry from said hydrate collection sump to said hydrate dissociation region.

11. The installation of a claim 10, wherein said hydrate slurry conduit comprises a fluid separator which separates hydrate from residual fluid.

12. The installation of claim 1, wherein said residual saline or polluted water removal portion comprises a screened water trap.

13. The installation of claim 1, wherein said residual saline or polluted water removal portion comprises a centrifuge.