Land-based desalination using buoyant hydrate

• US 6,565,715 B1
• Filed: 07/12/1999
• Issued: 05/20/2003
• Est. Priority Date: 07/12/1999
• Status: Expired due to Fees

• Current Assignee: Marine Desalination Systems LLC
• Original Assignee: Marine Desalination Systems LLC
• Inventors: Max, Michael David
• Primary Examiner(s): Manoharan, Virginia
• Application Number:
  US09/350,906
• Time in Patent Office: 1,408 Days
• Field of Search: 203/10, 203/23, 203/DIG.17, 203/49, 203/100, 203/11, 203/48, 203/2, 203/27, 203/DIG.8, 625/32, 625/33, 210/704, 210/707, 210/737, 210/774, 232/95, 233/00
• US Class Current: 203/10
• CPC Class Codes: B01D 2257/504 Carbon dioxide
• CPC Class Codes: B01D 53/62 Carbon oxides
• CPC Class Codes: C02F 1/20 by degassing, i.e. liberation of dissolved gases degasification of liquids in general B01D19/00; arrangement of degassing apparatus in boiler feed supply F22D
• CPC Class Codes: C02F 1/22 by freezing
• CPC Class Codes: C02F 1/26 by extraction
• CPC Class Codes: C02F 1/265 Desalination
• CPC Class Codes: C02F 1/5236 using inorganic agents
• CPC Class Codes: C02F 2103/08 Seawater, e.g. for desalination
• CPC Class Codes: C02F 2103/18 from the purification of gaseous effluents
• CPC Class Codes: Y02A 20/124 Water desalination
• CPC Class Codes: Y02C 20/40 of CO2
• CPC Class Codes: Y10S 203/08 Waste heat
• CPC Class Codes: Y10S 203/11 Batch distillation
• CPC Class Codes: Y10S 203/18 Control

Abstract

Methods and apparatus for desalination of salt water (and purification of polluted water) are disclosed. Salt water is pumped to a desalination installation and down to the base of a desalination fractionation column, where it is mixed with hydrate-forming gas to form positive buoyant hydrate. The hydrate rises and dissociates (melts) into the gas and pure water. In preferred embodiments, residual salt water which is heated by heat given off during formation of the hydrate is removed from the system to create a bias towards overall cooling as the hydrate dissociates endothermically at shallower depths. In preferred embodiments, the input water is passed through regions of dissociation in heat-exchanging relationship therewith so as to be cooled sufficiently for hydrate to form at pressure-depth. The fresh water produced by the system is cold enough that it can be used to provide refrigeration, air conditioning, or other cooling; heat removed from the system with the heated residual water can be used for heating or other applications.

Claims

1. A method of desalinating or purifying saline or polluted input water, respectively, said method comprising:

providing said input water to a hydrate formation region of a desalination fractionation installation that is located in land and causing said input water to be mixed with a hydrate-forming substance under temperature conditions and pressure conditions conducive to formation of hydrate of said hydrate-forming substance such that hydrate spontaneously forms, said desalination fractionation installation comprising a shaft extending downward into the ground to sufficient depth for the weight of water contained therein to naturally produce said pressure conditions conductive to formation of said hydrate at a lower region of said shaft, said hydrate formation of said hydrate at a lower region of said shaft, said hydrate formation region being located within said lower region of said shaft;

extracting heat energy from said desalination fractionation installation by removing residual saline or polluted water that has been warmed by heat of exothermic formation of said hydrate;

providing said hydrate to a hydrate dissociation region of said installation; and

allowing said hydrate to dissociate into fresh water and the hydrate-forming substance in a dissociation region of said installation;

said method further comprising at least partially cooling said input water toward said temperature conditions conducive to formation of said hydrate before said input water is mixed with said hydrate-forming substance.

2. The method of claim 1, wherein the input water is at least partially cooled by being passed in heat-exchanging relationship through said dissociation region, whereby heat is absorbed from said input water by said hydrate as said hydrate dissociates endothermically.

3. The method of claim 1, wherein said hydrate-forming substance is gaseous.

4. The method of claim 1, wherein said hydrate-forming substance forms positively buoyant hydrate and wherein said providing said hydrate to said hydrate dissociation region of said installation comprises allowing said hydrate to rise naturally to said hydrate dissociation region.

5. The method of claim 1, wherein said hydrate-forming substance is gaseous and forms positively buoyant hydrate and wherein said providing said hydrate to said hydrate dissociation region of said installation comprises allowing said hydrate to rise naturally to said hydrate dissociation region.