Process for fabricating organic semiconductor devices using ink-jet printing technology and device and system employing same

• US 6,566,153 B1
• Filed: 03/19/2001
• Issued: 05/20/2003
• Est. Priority Date: 10/14/1998
• Status: Expired due to Fees

• Current Assignee: Regents of the University of California (University of California)
• Original Assignee: Regents of the University of California (University of California)
• Inventors: Yang, Yang
• Primary Examiner(s): Nelms, David
• Assistant Examiner(s): LE, THAO P
• Application Number:
  US09/601,068
• Time in Patent Office: 792 Days
• Field of Search: 438/14, 438/21, 438/57, 438/29, 257/40
• US Class Current: 438/29
• CPC Class Codes: H10K 50/11 characterised by the electroluminescent [EL] layers
• CPC Class Codes: H10K 50/125 specially adapted for multicolour light emission, e.g. for emitting white light
• CPC Class Codes: H10K 50/17 Carrier injection layers
• CPC Class Codes: H10K 59/12 Active-matrix OLED [AMOLED] displays
• CPC Class Codes: H10K 59/17 Passive-matrix OLED displays
• CPC Class Codes: H10K 59/221 Static displays, e.g. displaying permanent logos
• CPC Class Codes: H10K 71/135 using ink-jet printing
• CPC Class Codes: H10K 85/10 Organic polymers or oligomers
• CPC Class Codes: H10K 85/111 comprising aromatic, heteroaromatic, or aryl chains, e.g. polyaniline, polyphenylene or polyphenylene vinylene
• CPC Class Codes: H10K 85/113 Heteroaromatic compounds comprising sulfur or selene, e.g. polythiophene
• CPC Class Codes: H10K 85/1135 Polyethylene dioxythiophene [PEDOT]; Derivatives thereof
• CPC Class Codes: H10K 85/114 Poly-phenylenevinylene; Derivatives thereof
• CPC Class Codes: H10K 85/141 comprising aliphatic or olefinic chains, e.g. poly N-vinylcarbazol, PVC or PTFE
• CPC Class Codes: H10K 85/143 Polyacetylene; Derivatives thereof
• CPC Class Codes: H10K 85/154 Ladder-type polymers
• CPC Class Codes: H10K 85/30 Coordination compounds
• CPC Class Codes: H10K 85/324 comprising aluminium, e.g. Alq3
• CPC Class Codes: H10K 85/615 Polycyclic condensed aromatic hydrocarbons, e.g. anthracene
• CPC Class Codes: H10K 85/631 Amine compounds having at least two aryl rest on at least one amine-nitrogen atom, e.g. triphenylamine

Abstract

An emission system for presenting visual image is disclosed. The emissive system typically contains first electrodes deposited over and in contact with a substrate. One or more conjugated organic buffer layers are then deposited over and in contact with the first electrodes, and second electrodes are subsequently deposited over the conjugated organic buffer layers. The conjugated organic buffer layers regulate current flow between the first electrodes and the second electrodes. Either before or after the deposition of each conjugated organic buffer layer, but before the deposition of the second electrodes, conjugated organic deposits are ink-jet printed such that they are in contact with at least one conjugated organic buffer layer. The conjugated organic deposits help to generate an indicator when a voltage stimulus is applied across the first electrodes and the second electrodes. Depending on the material of the conjugated organic deposits, the indicator may be luminescence, fluorescence, conductivity, or the like. A voltage source is used for selectively applying the voltage stimulus across the first electrodes and the second electrodes.

Claims

1. A process for fabricating a semiconductor device capable of producing an indicator in response to a stimulus, the process comprising:

supporting at least one first electrode over a substrate;

supporting at least one conjugated organic buffer layer above the at least one first electrode such that one conjugated organic buffer layer is in contact with each first electrode;

ink-jet printing at least one conjugated organic deposit above the at least one first electrode such that each conjugated organic deposit is in contact with at least one conjugated organic buffer layer; and

supporting at least one second electrode over an uppermost conjugated organic buffer layer.

2. A process as recited in claim 1, wherein the step of supporting at least one second electrode over an uppermost conjugated organic buffer layer comprises the steps of:

ink-jet printing at least one organic mask over and in contact with the uppermost conjugated organic buffer layer, the at least one organic mask having low adhesion strength when in contact with the uppermost conjugated organic buffer layer;

supporting second electrode material over and in contact with the at least one organic mask and the uppermost conjugated organic buffer layer, the second electrode material having high adhesion strength when in contact with the uppermost conjugated organic buffer layer and the at least one organic mask;

applying adhesive sheeting to the second electrode material; and

removing the adhesive sheeting, wherein the at least one organic mask and second electrode material above the at least one organic mask will also be removed.

3. A process as recited in claim 1, wherein the step of supporting at least one second electrode over an uppermost conjugated organic buffer layer comprises the steps of:

shadow masking areas on the uppermost conjugated organic buffer layer where no second electrode material is to be deposited using dividers; and

ink-jet printing second electrode material between the dividers.

4. A process for fabricating semiconductor devices capable of producing an indicator in response to a stimulus, the process comprising:

supporting a plurality of source electrodes over a substrate;

supporting a plurality of gate electrodes over the substrate;

supporting a plurality of transistors between the plurality of source electrodes and the plurality of gate electrodes, each transistor having a source terminal coupled to a source electrode, a gate terminal coupled to a gate electrode, and a drain terminal;

supporting a second electrode over the plurality of transistors;

supporting a conjugated organic buffer layer between the plurality of transistors and the second electrode such that the conjugated organic buffer layer is in contact with the drain terminals of the plurality of transistors and the second electrode;

ink-jet printing a plurality of conjugated organic deposits above each transistor such that the plurality of conjugated organic deposits are in contact with the conjugated organic buffer layer and the second electrode.

5. A process for fabricating a semiconductor device capable of producing an indicator in response to a stimulus, the process comprising:

ink-jet printing at least one conjugated organic deposit over a substrate; and

supporting a first conjugated organic buffer layer over each conjugated organic deposit such that each conjugated organic deposit is in contact with the first conjugated organic buffer layer.

6. A process as recited in claim 5, wherein preceding the step of ink-jet printing at least one conjugated organic deposit over a substrate, the process further includes the step of supporting at least one first electrode and second electrode pair over the substrate such that each conjugated organic deposit is ink-jet printed over a first electrode and second electrode pair.

7. A process as recited in claim 5, further including the steps of:

ink-jet printing at least one additional layer of at least one conjugated organic deposit over the first conjugated organic buffer layer; and

supporting an additional conjugated organic buffer layer over each additional layer of at least one conjugated organic deposit such that each additional layer of at least one conjugated organic deposit is in contact with the additional conjugated organic buffer layer.

8. A process as recited in claim 7, wherein preceding the step of ink-jet printing at least one additional layer of at least one conjugated organic deposit over the first conjugated organic buffer layer, the process further includes the step of supporting at least one first electrode and second electrode pair over the first conjugated organic buffer layer such that each conjugated organic deposit is ink-jet printed over a first electrode and second electrode pair.