Highly efficient OLEDs using doped ambipolar conductive molecular organic thin films

• US 6,573,651 B2
• Filed: 12/18/2000
• Issued: 06/03/2003
• Est. Priority Date: 12/18/2000
• Status: Expired due to Term

• Current Assignee: The Trustees of Princeton University (Princeton University)
• Original Assignee: The Trustees of Princeton University (Princeton University)
• Inventors: Adachi, Chihaya, Baldo, Marc A., Forrest, Stephen R.
• Primary Examiner(s): Philogene, Haissa
• Assistant Examiner(s): VO, TUYET THI
• Application Number:
  US09/740,183
• Publication Number:
  US 20020113545A1
• Time in Patent Office: 897 Days
• Field of Search: 313/504, 313/506, 313/502, 313/503, 428/690, 428/691, 428/917, 257/40, 257/87, 257/89, 315/169.1, 315/169.3
• US Class Current: 313/504
• CPC Class Codes: H10K 2101/10 Triplet emission
• CPC Class Codes: H10K 50/11 characterised by the electroluminescent [EL] layers
• CPC Class Codes: H10K 50/14 Carrier transporting layers
• CPC Class Codes: H10K 50/17 Carrier injection layers
• CPC Class Codes: H10K 85/341 Transition metal complexes, e.g. Ru(II)polypyridine complexes H10K85/331 takes precedence
• CPC Class Codes: H10K 85/60 Organic compounds having low molecular weight H10K85/10 - H10K85/50 take precedence
• CPC Class Codes: H10K 85/631 Amine compounds having at least two aryl rest on at least one amine-nitrogen atom, e.g. triphenylamine
• CPC Class Codes: Y10T 428/24942 including components having same physical characteristic in differing degree

Abstract

The present invention is directed to simplified OLED structures comprising an anode layer, a hole injecting layer (HIL) in direct contact with the anode layer, an emissive organic electron transporting layer (ETL) in direct contact with the hole injecting layer, and a cathode layer in direct contact with the emissive organic electron transporting layer. The hole injecting material used in the hole injecting layer is characterized, in particular, as being an organic material having an ionization potential that is not more than about 0.7 eV greater than the ionization potential of the material used for the anode layer. The emissive organic electron transporting layer comprises an organic electron transporting material and an organic hole-trapping emissive material, for example, an organic phosphorescent material that produces emission from a triplet excited state of an organic molecule.

Claims

1. An organic light emitting device, comprising:

an anode layer comprising an anode material having a characteristic ionization potential;

an organic hole injecting layer comprising an organic hole injecting material having a characteristic ionization potential, the organic hole injecting layer being in direct contact with the anode layer, wherein the ionization potential of the organic hole injecting material is not more than 0.7 eV greater than the ionization potential of the anode material;

an organic electron transporting layer comprising an organic electron transporting material and an organic hole-trapping emissive material, the organic electron transporting layer being in direct contact with the organic hole injecting layer; and

a cathode layer in direct contact with the organic electron transporting layer.

2. The organic light emitting device of claim 1, wherein the ionization potential of the organic hole injecting material is not more than about 0.5 eV greater than the ionization potential of the anode material.

3. The organic light emitting device of claim 1, wherein the organic hole-trapping emissive material is a phosphorescent material.

4. The organic light emitting device of claim 3, wherein the phosphorescent material has a characteristic ionization potential and the organic electron transporting material has a characteristic ionization potential and the characteristic ionization potential of the phosphorescent material is at least about 0.5 eV less than the characteristic ionization potential of the organic electron transporting material.

5. The organic light emitting device of claim 3, wherein the characteristic ionization potential of the phosphorescent material is at least about 0.7 eV less than the characteristic ionization potential of the organic electron transporting material.

6. The organic light emitting device of claim 3, wherein the characteristic electron affinity of the organic electron transporting material is not more than about 0.5 eV greater than the characteristic electron affinity of the phosphorescent material.

7. The organic light emitting device of claim 3, wherein the anode comprises ITO.

8. The organic light emitting device of claim 3, wherein the organic hole injecting material comprises 4,4′

,4″

-tris(3-methylphenylphenylamino)triphenylamine.

9. The organic light emitting device of claim 3, wherein the electron transporting material comprises 4,4′

-N,N′

-dicarbazole-biphenyl.

10. The organic light emitting device of claim 3, wherein the phosphorescent material comprises fac tris(2-phenylpyridine)iridium.

11. The organic light emitting device of claim 3, wherein the cathode layer comprises magnesium and silver.

12. The organic light emitting device of claim 3, wherein the phosphorescent material has a characteristic electron affinity and the organic electron transporting material has a characteristic electron affinity and the characteristic electron affinity of the organic electron transporting material is equal to or greater than the characteristic electron affinity of the phosphorescent material.

13. The organic light emitting device of claim 12, wherein the cathode layer comprises a cathode material having a characteristic work function and the characteristic work function of the cathode material is not more than about 0.75 eV greater than the characteristic electron affinity of the organic electron transporting material.

14. The organic light emitting device of claim 12, wherein the characteristic work function of the cathode material is not more than about 0.5 eV greater than the characteristic electron affinity of the organic electron transporting material.

15. The organic light emitting device of claim 3, wherein the phosphorescent material has a characteristic ionization potential and the characteristic ionization potential of the phosphorescent material is approximately equal to or greater than the characteristic ionization potential of the organic hole injecting material.

16. The organic light emitting device of claim 15, wherein the characteristic ionization potential of the phosphorescent material is not more than 0.7 eV greater than the characteristic ionization potential of the organic hole injecting material.

17. The organic light emitting device of claim 16, wherein the characteristic ionization potential of the phosphorescent material is not more than 0.5 eV greater than the characteristic ionization potential of the organic hole injecting material.

18. An organic light emitting device, comprising:

an ITO anode layer;

a hole injecting layer comprising 4,4′

,4″

-tris(3-methylphenylphenylamino)triphenylamine, the hole injecting layer being in direct contact with the ITO anode layer;

an emissive layer comprising 4,4′

-N,N′

-dicarbazole-biphenyl doped with fac tris(2-phenylpyridine)iridium, the emissive layer being in direct contact with the hole injecting layer; and

a cathode layer comprising magnesium and silver, the cathode layer being in direct contact with the emissive layer.

19. The organic light emitting device of claim 18, wherein fac tris(2-phenylpyridine)iridium comprises 7 weight percent of the emissive layer.