Process for producing fiber-reinforced silicon carbide composites

• US 6,576,076 B1
• Filed: 02/17/2000
• Issued: 06/10/2003
• Est. Priority Date: 03/01/1999
• Status: Expired due to Fees

• Current Assignee: Agency of Industrial Science & Technology (Government of Japan)
• Original Assignee: Agency of Industrial Science & Technology (Government of Japan)
• Inventors: Tani, Eiji
• Primary Examiner(s): Mayes, Curtis
• Application Number:
  US09/505,686
• Time in Patent Office: 1,209 Days
• Field of Search: 156/89.25, 156/89.26, 156/89.28, 264/682, 264/29.5, 264/29.6, 264/29.1, 264/29.7
• US Class Current: 156/89.26
• CPC Class Codes: C04B 35/571 obtained from Si-containing polymer precursors or organosilicon monomers
• CPC Class Codes: C04B 35/573 obtained by reaction sintering or recrystallisation
• CPC Class Codes: C04B 35/65 Reaction sintering of free metal- or free silicon-containing compositions C04B35/573, C04B35/591 take precedence
• CPC Class Codes: C04B 35/80 Fibres, filaments, whiskers, platelets, or the like

Abstract

A fiber-reinforced silicon carbide composite is produced by preparing a fiber prepreg containing a powdered silicon and a resin and molding the prepreg to yield a green body having a desired shape, or laminating a fiber prepreg containing a resin and a woven fabric prepreg containing a powdered silicon and a resin in alternate order and molding the laminate to yield a green body having a desired shape; carbonizing the green body at 900° to 1350° C. in an inert atmosphere; subjecting the carbonized body to reaction sintering at a temperature of 1300° C. or more in vacuo or in an inert atmosphere to form open pores; and infiltrating molten silicon into the sintered body having open pores at a temperature of about 1300° to 1800° C. in vacuo or an inert atmosphere.

Claims

1. A process for producing a fiber-reinforced silicon carbide composite, said process comprising the steps of:

laminating first fiber prepregs containing resin and second fiber prepregs containing silicon powder and resin, in alternate order;

molding the laminate into a desired shape to yield a green body;

carbonizing the green body at a temperature in the range of about 900°

C. to about 1350°

C. in an inert atmosphere to yield a carbonized composite;

subjecting the carbonized composite to reaction sintering at a temperature of about 1300°

C. or higher in vacuo or in an inert atmosphere to form open pores in a fiber region containing silicon powder; and

infiltrating molten silicon into the open pores of the sintered composite at a temperature in the range of about 1300°

C. to about 1800°

C. in vacuo or in an inert atmosphere.

2. The process according to claim 1, wherein a resin impregnation-carbonization procedure is performed one to five times after the carbonization of the green body to yield the carbonized composite.

3. The process according to claim 1, wherein the resin is at least one selected from the group consisting of a phenol resin, a furan resin, pitch, and an organometallic polymer.

4. The process according to claim 1, wherein the resin is at least one selected from the group consisting of a phenol resin, a furan resin, pitch, and an organometallic polymer and wherein said resin further comprises a carbon powder, a graphite powder, carbon black, or an aggregate.

5. The process according to claim 1, wherein the resin is at least one selected from the group consisting of a phenol resin, a furan resin, pitch, and an organometallic polymer, and wherein said resin further comprises at least one antioxidant selected from the group consisting of silicon carbide, silicon nitride, mullite, molybdenum disilicide, molybdenum, boron carbide, and powdered boron.

6. The process according to claim 1, wherein said silicon powder is metallic silicon or a silicon alloy with magnesium, aluminum, titanium, chromium, manganese, iron, cobalt, nickel, copper, zinc, zirconium, niobium, or molybdenum.

7. The process according to claim 1, wherein said silicon powder is a fine powder having a mean particle diameter not exceeding 20 μ

m.

8. The process according to claim 1, wherein the proportion of silicon powder to the resin is determined so that the atomic ratio, Si/C, of silicon to carbon derived from the resin ranges from 0.1 to 4.

9. The process according to claim 1, wherein said fiber prepreg comprises a fibrous reinforcement and is at least one of a long fiber or a short fiber, wherein said fiber is selected from carbon fibers, silicon carbide fibers, silicon nitride fibers and oxide fibers.

10. The process according to claim 1, wherein a fiber to contain the silicon powder and resin is composed of porous woven or nonwoven fabrics, or porous resin or plastic sheets.