Method and apparatus for removing floating substances and salts from a liquid by means of a membrane filtration

• US 6,576,136 B1
• Filed: 05/11/2001
• Issued: 06/10/2003
• Est. Priority Date: 11/13/1998
• Status: Expired due to Fees

• Current Assignee: Dhv Water BV, Stork Friesland BV (Fluor Corporation), N.V. Waterleiding Friesland
• Original Assignee: Dhv Water BV, N.V. Waterleiding Friesland
• Inventors: Van Der Meer, Walterus Gijsberrus Joseph, De Moel, Petrus Jacob, Van Dalfsen, Harm
• Primary Examiner(s): DRODGE, JOSEPH W
• Application Number:
  US09/831,589
• Time in Patent Office: 760 Days
• Field of Search: 210/194, 210/195.2, 210/198.2, 210/321.65, 210/321.69, 210/321.76, 210/321.85, 210/636, 210/637, 210/650, 210/651, 210/702, 210/712, 210/805, 210/198.1, 210/639, 552/88
• US Class Current: 210/636
• CPC Class Codes: B01D 2311/04 Specific process operations in the feed stream; Feed pretreatment
• CPC Class Codes: B01D 2311/2626 Absorption or adsorption
• CPC Class Codes: B01D 2311/2642 Aggregation, sedimentation, flocculation, precipitation or coagulation
• CPC Class Codes: B01D 2321/168 Use of other chemical agents
• CPC Class Codes: B01D 2321/185 Aeration
• CPC Class Codes: B01D 61/027 Nanofiltration
• CPC Class Codes: B01D 61/04 Feed pretreatment
• CPC Class Codes: B01D 65/02 Membrane cleaning or sterilisation ; Membrane regeneration
• CPC Class Codes: B01D 65/08 Prevention of membrane fouling or of concentration polarisation

Abstract

A membrane filtration for removing floating substances and salts from a liquid, uses vertically positioned capillary or tube membranes which are suitable for performing nano or hyper-filtration. Repeatedly and consecutively the following steps are performed: a) a permeate is produced without discharge of concentrate for a predetermined period of time; b) then a gas, for example air, is guided along side the membrane, at least almost without discharge of permeate and without discharge of concentrate; c) and finally a concentrate is discharged without discharge of permeate. During step a) and step c) use can be made of a combined supply of liquid and gas. An apparatus for performing this method is described as well.

Claims

1. Method for removing floating substances and salts from a liquid by means of membrane filtration, characterized, in that use is made only of vertically positioned spiral wound and/or plate and frame type tubular membranes, which are pore sized for nano or hyper-filtration, and wherein repeatedly and consecutively the steps are performed which comprise:

a. producing a permeate without concentrate discharge during a predetermined period of time;

b. guiding a gas through the membrane, with minimal permeate discharge and without concentrate discharge; and

c. discharging concentrate without discharging permeate.

2. Method according to claim 1, characterized, in that during step c. concentrate is discharged by a combined liquid/gas supply.

3. Method according to claim 2, characterized, in that during step c. chemicals are added to the liquid.

4. Method according to claim 1, characterized, in that during step b. the supply of gas is performed at a pressure which is lower than the operational pressure during step a.

5. Method according to claim 1, characterized, in that the period of time during which step a. is performed, is determined by means of the increase of the pressure resistance the permeate encounters across the membrane.

6. Method according to claim 1, characterized, in that pulverized charcoal and/or flocculants are added to the liquid.

7. Method according to claim 1, characterized, in that during step a. and/or step b. and/or step c. a recirculation of a concentrate across the membrane is performed.

8. A method according to claim 1 wherein said gas is air.

9. A method according to claim 1 wherein said membranes are capillary membranes.

10. Aparatus for removing floating substances and salts from a liquid by means of membrane filtration, concentrate discharge pipe, characterized by comprising vertically positioned spiral wound and/or plate and frame type tubular membranes, and which are pore sized for nano or hyper-filtration, a gas supply pipe which is connected parallel to the liquid supply pipe and terminating in the liquid supply pipe, control valves for opening and closing the liquid supply pipe, the gas supply pipe, a permeate discharge pipe and a concentrate discharge pipe, and further comprising control means for controlling the control valves, such that repeatedly and consecutively:

a. the liquid supply pipe and the permeate discharge pipe are opened and the gas supply pipe and the concentrate discharge pipe are closed, during a previously determined period of time;

b. the gas supply pipe only is opened; and

c. the permeate discharge pipe is closed and at least the liquid supply pipe and the concentrate discharge pipe are opened.

11. Apparatus according to claim 10, characterized, in that the control means are such that during step c. the gas supply pipe is opened as well.

12. Apparatus according to claim 11, characterized, in that means are provided for adding, during step c., chemicals to the liquid.

13. Apparatus according to claim 10, characterized, in that means are provided for controlling the supply pressure of the gas and/or liquid.

14. Apparatus according to claim 10, characterized, in that sensor means are connected to the control means for determining the pressure resistance which is encountered by the permeate across the membrane.

15. Apparatus according to claim 10, characterized, in that means are provided for adding pulverised coal and/or flocculants to the liquid.

16. Apparatus according to claim 10, characterized, in that a recirculation pipe which connects the concentrate discharge pipe with the liquid supply pipe is provided.

17. An apparatus according to claim 10 wherein said membranes are tubular membranes.