Water-resistant cable

• US 6,577,796 B2
• Filed: 04/06/2001
• Issued: 06/10/2003
• Est. Priority Date: 10/07/1998
• Status: Expired due to Term

• Current Assignee: Prysmian Cavi E Sistemi Italia Srl (Prysmian SPA)
• Original Assignee: Pirelli Cavi e Sistemi S.P.A. (Prysmian SPA)
• Inventors: Colombo, Gianfranco, Anelli, Pietro
• Primary Examiner(s): Sanghavi, Hemang
• Assistant Examiner(s): Knauss, Scott A
• Application Number:
  US09/827,161
• Publication Number:
  US 20020041744A1
• Time in Patent Office: 795 Days
• Field of Search: 385/100-114, 174/77.R, 174/92, 174/93, 174/23.R
• US Class Current: 385/112
• CPC Class Codes: G02B 6/441 built up from sub-bundles G02B6/4429, G02B6/4439, G02B6/4479 take precedence
• CPC Class Codes: G02B 6/4433 Double reinforcement laying in straight line with optical transmission element
• CPC Class Codes: G02B 6/44384 the means comprising water blocking or hydrophobic materials G02B6/4439, G02B6/4479 take precedence
• CPC Class Codes: H01B 7/28 Protection against damage caused by moisture, corrosion, chemical attack or weather
• CPC Class Codes: H01B 7/288 using hygroscopic material or material swelling in the presence of liquid

Abstract

The present invention relates to a cable, in particular an optical fiber cable, which is resistant to the radial permeation and to the longitudinal propagation of water. This cable contains a water-soluble polymer material which is a water-swellable and water-soluble material. In particular, this cable is characterized in that, following the ingress of water into this cable, the propagation of water is impeded on account of the combined effect of the swelling of the water-soluble material and the formation of an aqueous solution of said material which has a predetermined viscosity, so as to impede the passage of the residual water. Preferably, the water-soluble material is chosen from polyacrylamide, modified polyvinyl alcohol, vinyl alcohol/vinyl acetate copolymers, polyvinylpyrrolidone, and mixtures thereof, the material preferably being a vinyl alcohol/vinyl acetate copolymer. The material can advantageously be extruded to form tubular elements for containing optical fibers, for example, two-layer tubular elements in which the inner layer is made of water-soluble material and the outer layer is made of a conventional polymer such as PE, PP or PBT.

Claims

1. An optical fibre cable comprising a longitudinal cavity extending along the length of the cable, at least one optical fibre housed inside said longitudinal cavity, said longitudinal cavity further comprising a solid and compact element within it, wherein said solid and compact element comprises a water-soluble polymer material which, following accidental ingress of water into the cable, is capable of forming an aqueous solution with a predetermined viscosity such as to block the flow of water within 10 meters of the point of ingress.

2. An optical fibre cable according to claim 1, wherein said solid and compact element comprises about 30% by weight or more of the water-soluble polymer material.

3. An optical fibre cable according to claim 1, wherein said solid and compact element comprises about 50% or more of the water-soluble polymer material.

4. An optical fibre cable according to claim 1, wherein said solid and compact element comprises more than about 75% by weight of the water-soluble polymer material.

5. An optical fibre cable according to claim 1, wherein said solid and compact element is a structural element of the cable and contains and protects the at least one optical fibre disposed within said longitudinal cavity.

6. An optical fibre cable according to claim 5, wherein said structural element is a tubular element and said longitudinal cavity is defined by the inner volume of said tubular element.

7. An optical fibre cable according to claim 6, wherein said tubular element comprises a two-layer wall in which the inner layer is made from the water-soluble solid material and the outer layer is made from a water-insoluble polymer material.

8. An optical fibre cable according to claim 7, wherein said tubular element comprises a third outer layer made of water-soluble solid polymer material.

9. An optical fibre cable according to claim 6, wherein said tubular element is made from a single sheath of said water-soluble solid material.

10. An optical fibre cable according to claim 5, wherein said structural element which contains the at least one optical fibre is a grooved core comprising at least one groove longitudinally disposed on the outer surface of said core and the longitudinal cavity is defined by the inner volume within said groove.

11. An optical fibre cable according to claim 10, wherein at least the walls of said groove are made from a water-soluble solid polymer material.

12. An optical fibre cable according to claim 10, wherein said grooved core is made completely from said water-soluble solid polymer material.

13. An optical fibre cable according to claim 1, wherein the solid and compact element made of water-soluble polymer material is a tape.

14. An optical fibre cable according to claim 1, wherein the water-soluble polymer material has a solubility in water of at least about 100 g/l.

15. An optical fibre cable according to claim 11 wherein said aqueous solution has a viscosity of at least about 10⁴ cP at 20°

C.

16. An optical fibre cable according to claim 14, wherein said aqueous solution contains an amount of water-soluble polymer material of between about 100 g/l and about 250 g/l.

17. An optical fibre cable according to claim 1, wherein in the presence of a relative humidity of greater than 75% outside said cavity, the relative humidity inside said cavity is maintained below about 75% for a predetermined period of time.

19. An optical fibre cable according to claim 1 or 18, wherein the water-soluble polymer material is a water-swellable material.

20. An optical fibre cable according to claim 1 or 18, wherein the water-soluble material is polyacrylamide, modified polyvinyl alcohol, vinyl alcohol/vinyl acetate copolymer, polyvinylpyrrolidone or mixtures thereof.

21. An optical fibre cable according to claim 20, wherein the water-soluble material is a vinyl alcohol/vinyl acetate copolymer obtained by partial hydrolysis of the acetate groups of a polyvinyl acetate homopolymer.

22. An optical fibre cable according to claim 21, wherein the degree of hydrolysis of the acetate groups of the polyvinyl acetate homopolymer is between about 50% and about 95%.

23. An optical fibre cable according to claim 20, wherein the vinyl alcohol/vinyl acetate copolymer has a viscosity index of greater than about 5.

24. An optical fibre cable according to claim 1 or 18, wherein the water-soluble polymer material has a breaking load of greater than about 15 MPa and an elastic modulus of greater than about 200 MPa.

25. An optical fibre cable according to claim 1, wherein the ratio between the cross section of said cavity and the perimeter of said water-soluble element in contact with said cavity is less than about 0.5 mm.

26. An optical fibre cable according to claim 25, wherein, when the water-soluble polymer forms an aqueous solution having a viscosity of at least about 10⁴ cP when contacted with water, said ratio is less than about 0.4 mm.

27. An optical fibre cable according to claim 1, wherein the cross section of the solid element made of water-soluble material is not less than about 10% of the free cross section of the cavity with which said solid element is associated.

28. An optical fibre cable according to claim 1, wherein the cross section of the solid element made of water-soluble material is not less than about 20% of the free cross section of the cavity with which said solid element is associated.

29. An optical fibre cable according to claim 1, wherein the cross section of the solid element made of water-soluble material is not less than about 40% of the free cross section of the cavity with which said solid element is associated.

18. An optical fibre cable comprising a cavity and a solid and compact element associated with said cavity, wherein said solid and compact element comprises a water-soluble polymer material and wherein, in the presence of a relative humidity of substantially less than or equal to about 80%, the water-soluble polymer material absorbs an amount of water of less than about 25% of the amount of water which can be absorbed by the water-soluble solid material under saturation conditions.