Water-based system for altering wettability of porous media

• US 6,579,572 B2
• Filed: 08/13/2001
• Issued: 06/17/2003
• Est. Priority Date: 08/13/2001
• Status: Expired due to Term

• Current Assignee: Intevep, S.A. (PDVSA Gas SA)
• Original Assignee: Intevep, S.A. (PDVSA Gas SA)
• Inventors: Araujo, Mariela, Araujo, Yani Carolina, Ranson, Aaron, Espin, Douglas, Chavez, Juan Carlos, Genolet, Luis Carlos
• Primary Examiner(s): BARR, MICHAEL E
• Application Number:
  US09/928,568
• Publication Number:
  US 20030031788A1
• Time in Patent Office: 673 Days
• Field of Search: 427/430.1, 427/230
• US Class Current: 427/430.1
• CPC Class Codes: C09K 8/845 containing inorganic compounds
• CPC Class Codes: C09K 8/88 macromolecular compounds
• CPC Class Codes: Y10S 977/773 Nanoparticle, i.e. structure having three dimensions of 100 nm or less
• CPC Class Codes: Y10S 977/89 Deposition of materials, e.g. coating, cvd, or ald

Abstract

A method for altering wettability of a reservoir formation includes the steps of providing a water-based fluid containing a wettability altering coating system; and flowing the fluid into a reservoir so as to coat the reservoir with the coating system.

Claims

1. A method for altering wettability of a reservoir formation, comprising the steps of:

providing a water-based fluid containing a wettability altering coating system; and

flowing said fluid into a reservoir so as to coat said reservoir with said coating system, wherein said coating system comprises wettability altering nanoparticles.

3. The method according to claim 1 or 2, wherein said coating system comprises a combination of organic and inorganic components having a nanoparticle size.

4. The method according to claim 3, wherein said organic components are polymeric structures and wherein said flowing step adsorbs said polymeric structures on surfaces of said reservoir.

5. The method according to claim 4, wherein the coating system forms a film around grains of said reservoir whereby wettability of said reservoir is altered.

6. The method according to claim 1, wherein said coating system comprises organic components selected from the group consisting of silanes, alkoxysilanes with fluorinated chains, alkylcarbonyl and combinations thereof.

7. The method according to claim 1 or 2, wherein said coating system comprises inorganic components selected from the group consisting of silicon, aluminum, titanium, zirconium and combinations thereof.

8. The method according to claim 1 or 2, wherein said reservoir has a wettability index of less than about −

0.3 or greater than about 0.3, and further comprising selecting said coating system so that said flowing step provide said reservoir with a wettability index of between about −

0.3 and about 0.3.

9. The method according to claim 1 or 2, wherein said flowing step comprises pumping said fluid into said reservoir through a well positioned on the surface to said reservoir.

10. The method according to claim 1 or 2, wherein said flowing step comprises flooding said reservoir with said fluid under pressure, and holding said pressure until said coating system is cured.

11. The method according to claim 1 or 2, wherein said flowing step is carried out so as to penetrate said formation with at least about 0.2 pore volumes of said fluid.

12. The method according to claim 1 or 2, wherein said reservoir has a wetting condition selected from the group consisting of water wet and oil wet, and wherein said coating system coats said reservoir so as to provide said reservoir with a wetting condition.

2. A method for altering wettability of a reservoir formation, comprising the steps of:

providing a water-based fluid containing a wettability altering coating system; and

flowing said fluid into a reservoir so as to coat said reservoir with said coating system, wherein said coating system comprises organic components selected from the group consisting of silanes, alkoxysilanes with fluorinated chains alkylcarbonyl and combinations thereof, wherein said silanes have a particle size of less than about 200 nm, said alkoxysilanes have a particle size of less than about 100 nm and said alkylcarbonyl has a particle size of less than about 50 nm.