Magnetic recording tape with controlled Hc and magnetic flux/unit area value and controlled Cl/Fe intensity

• US 6,579,592 B1
• Filed: 06/03/1999
• Issued: 06/17/2003
• Est. Priority Date: 11/29/1996
• Status: Expired due to Fees

• Current Assignee: Fujifilm Corporation (Fujifilm Holdings Corporation)
• Original Assignee: Fuji Photo Film Co Limited (Fujifilm Holdings Corporation)
• Inventors: Inaba, Hiroo, Takano, Hiroaki, Matsubaguchi, Satoshi, Suzuki, Masaki, Doushita, Hiroaki, Ejiri, Kiyomi
• Primary Examiner(s): Thibodeau, Paul
• Assistant Examiner(s): Bernatz, Kevin M.
• Application Number:
  US09/324,754
• Time in Patent Office: 1,475 Days
• Field of Search: 428/332, 428/402, 428/696, 428/694.BY, 428/694.BS, 428/694.BB, 428/694.BR, 428/900, 428/323, 428/141, 428/425.9, 428/522, 428/694.BC, 428/694.BA
• US Class Current: 428/141
• CPC Class Codes: G11B 5/70 on a base layer
• CPC Class Codes: G11B 5/70621 containing Co metal or alloys
• CPC Class Codes: Y10T 428/24355 Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
• CPC Class Codes: Y10T 428/25 Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
• CPC Class Codes: Y10T 428/26 Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
• CPC Class Codes: Y10T 428/2982 Particulate matter [e.g., sphere, flake, etc.]
• CPC Class Codes: Y10T 428/31609 Particulate metal or metal compound-containing
• CPC Class Codes: Y10T 428/31935 Ester, halide or nitrile of addition polymer

Abstract

A magnetic recording tape is described, which comprises a plastic support having provided thereon a magnetic layer comprising a ferromagnetic metal powder dispersed in a binder, wherein the magnetic layer has the product P of the coercivity Hc (Oe) in the in-plane machine direction of the tape and the magnetic flux φm (G·cm) of from 100 to 160.

Claims

1. A magnetic recording tape which comprises a support having thereon a magnetic layer comprising a ferromagnetic metal powder and a binder, wherein said magnetic layer has the product P of the following formula:

2. The magnetic recording tape as claimed in claim 1, wherein the ferromagnetic metal powder has a specific surface area S_BET measured by the BET method of 30 m²/g to less than 50 m²/g and saturation magnetization σ

_s of 140 to 170 emu/g.

3. The magnetic recording tape as claimed in claim 1, wherein the ferromagnetic metal powder has a specific surface area S_BET measured by the BET method of 40 m²/g to less than 50 m²/g and saturation magnetization σ

_s of 150 to 170 emu/g.

4. The magnetic recording tape as claimed in claim 1, wherein the coercivity Hc of said ferromagnetic metal powder is from 1,950 to 2,750 Oe.

5. The magnetic recording tape as claimed in claim 1, wherein said ferromagnetic metal powder comprises more than 50% by weight of Fe and containing 10 to 40 atomic % of Co, 2 to 20 atomic % of Al, and 1 to 15 atomic % of Y, each based on Fe.

6. The magnetic recording tape as claimed in claim 1, wherein said magnetic layer has a thickness of from 0.05 to 0.3 μ

m, a coercivity Hc of 2,000 to 2,400 Oe, saturation magnetization per unit area φ

m of 0.03 to 0.13 G·

cm.

7. The magnetic recording tape as claimed in claim 1, wherein said binder contains a polyurethane resin containing a cyclic hydrocarbon group and an ether bond.

8. The magnetic recording tape as claimed in claim 1, wherein said magnetic layer contains 15 to 40 parts by weight of binder based on 100 parts of the ferromagnetic metal powder.

9. The magnetic recording tape as claimed in claim 1, wherein said magnetic layer further contains at least one abrasive selected from the group consisting of α

-alumina, chromium oxide, α

-iron oxide and an artificially synthesized diamond.

10. The magnetic recording tape as claimed in claim 1, wherein a back coating layer comprising a binder having dispersed therein inorganic particles is provided on the surface of the support opposite to the magnetic layer-coated side.

11. The magnetic recording tape as claimed in claim 1, wherein the product P is 110 to 150.

12. The magnetic recording tape as claimed in claim 1, wherein the product P is 120 to 140.

13. The magnetic recording tape as claimed in claim 1, wherein said saturation magnetization per unit area φ

m is 0.04 to 0.10 G·

cm.

14. The magnetic recording tape as claimed in claim 1, wherein the surface roughness Ra of said magnetic layer is equal to or less than 3 nm.

15. The magnetic recording tape as claimed in claim 1, wherein the squareness ratio of said magnetic recording tape in the machine direction of the tape is 0.85 or more.

16. The magnetic recording tape as claimed in claim 15, wherein the binder resin comprises a polyurethane resin and an isocyanate compound, and the total amount of the polyurethane resin and the isocyanate compound is 50% by weight or more based on the total amount of the binder resin.

17. The magnetic recording tape as claimed in claim 1, wherein said ferromagnetic metal powder has a long axis length of 0.05 to 0.13 μ

m and crystallite size of 80 to 200 Å

, and the thickness of the magnetic layer is 0.05 to 0.5 μ

m and SFD in the machine direction of 0.41 or less.

18. The magnetic recording tape as claimed in claim 17, wherein said SFD is from 0.15 to 0.30.

19. The magnetic recording tape as claimed in claim 1, wherein said magnetic layer further contains carbon black.

20. The magnetic recording tape as claimed in claim 19, wherein said carbon black is contained in an amount of 0.1 to 30% by weight based on the weight of the ferromagnetic metal powder.

21. The magnetic recording tape as claimed in claim 1, wherein a nonmagnetic layer containing one or more inorganic powders is provided between said support and said magnetic layer.

22. The magnetic recording tape as claimed in claim 21, wherein said one or more inorganic powders is titanium dioxide or α

-iron oxide.

23. The magnetic recording tape as claimed in claim 22, wherein said nonmagnetic layer further contains carbon black.

24. The magnetic recording tape as claimed in claim 22, further comprising a polyurethane resin, wherein said polyurethane resin is a reaction product of diols and an organic diisocyanate, said diols contain a first diol containing a cyclic hydrocarbon group and having a molecular weight of 50 to less than 500 in an amount of 17 to 40% by weight based on said polyurethane resin, and a second diol having an average molecular weight of 500 to 5,000 in an amount of 10 to 50% by weight based on said polyurethane resin, and the ether bond in the second diol is contained in the amount of 1.0 to 5.0 mmol/g as an ether group based on the weight of said polyurethane resin ferromagnetic metal powder.

25. The magnetic recording tape as claimed in claim 24, wherein said polyurethane resin has a number average molecular weight of 18,000 to 56,000 and a weight average molecular weight of 30,000 to 100,000.

26. The magnetic recording tape as claimed in claim 24, wherein said polyurethane resin has Tg of 30 to 150°

C.

27. The magnetic recording tape as claimed in claim 24, wherein the molecular structure of said polyurethane resin comprises at least one polar group selected from the group consisting of —

SO₃M and —

OSO₃M (wherein M represents a hydrogen atom, an alkali metal ion, an alkaline earth metal ion, or an ammonium ion) in an amount of 1×

10<sup>−

5</sup> to 2×

10<sup>−

4</sup> eq/g.

28. The magnetic recording tape as claimed in claim 24, wherein the molecular structure of said polyurethane resin comprises from 3 to 20 OH groups (in average).

29. The magnetic recording tape as claimed in claim 24, wherein said binder is cured by the reaction with an isocyanate curing agent.

30. The magnetic recording tape as claimed in claim 24, wherein said binder further contains a vinyl chloride polymer containing vinyl chloride as a recurring unit.