Process for removing free fatty acids from fats and oils of biological origin or their steam distillates

• US 6,579,996 B2
• Filed: 10/20/2001
• Issued: 06/17/2003
• Est. Priority Date: 04/21/1999
• Status: Expired due to Fees

• Current Assignee: Eckhard Weidner, König, Wolfgang, Martin Drescher, Siegfried Peter
• Original Assignee: Eckhard Weidner, König, Wolfgang, Martin Drescher, Siegfried Peter
• Inventors: König, Wolfgang, Drescher, Martin, Weidner, Eckhard, Peter, Siegfried
• Primary Examiner(s): Carr, Deborah D.
• Application Number:
  US10/046,063
• Publication Number:
  US 20020111504A1
• Time in Patent Office: 605 Days
• Field of Search: 554/184, 554/185
• US Class Current: 554/15
• CPC Class Codes: C11B 3/06 with bases

Abstract

A method for removing free fatty acids from fats or oils of biological origin or their steam distillates by extracting the free fatty acids with a mixture of basic organic nitrogen compounds and water as an extraction medium at a temperature below the boiling point of the organic nitrogen compounds. The content of the basic organic nitrogen compounds in the extraction medium is 20-30% by weight. In this manner, the formation of a viscous soapstock which is difficult to remove is prevented. The boiling point of the basic organic nitrogen compounds used is the same as or above boiling point of water and below the boiling point of the fatty acids to be extracted in order to enable simple recovery of the extraction medium.

Claims

1. A process for removing free fatty acids from fats or oils of biological origin by extracting the free fatty acids with a mixture of basic organic nitrogen compounds and water as extraction medium at a temperature below the boiling point of the organic nitrogen compounds, where the content of the basic organic nitrogen compounds in the extraction medium is at least about 20% by weight and at most about 60% by weight, and the boiling point of the basic organic nitrogen compound(s) used is equal to or above the boiling point of water and below the boiling point of the fatty acids to be extracted.

2. The process according to claim 1, wherein the basic nitrogen compound(s) in the refined fat or oil obtained by the extraction is/are extracted by means of water or aqueous solutions of volatile acids.

3. The process according to claim 1, wherein when fats and oils having a free fatty acid content of about 50% by weight or more are being deacidified, alkanes and/or an ester, are added to the starting materials to be deacidified in a concentration which is sufficient for the system of extraction medium, alkane and starting material to divide into two phases.

5. The process according to claim 3, wherein the basic nitrogen compound(s) in the alkane phase and/or ester phase is/are extracted by means of water or aqueous solutions of volatile acids.

6. The process according to claim 2, wherein the organic nitrogen compound(s) dissolved in the water or the aqueous solution of volatile acids after the extraction step is/are separated off by distillation.

7. The process according to claim 3, wherein the alkane used is selected from the group consisting of propane, butane, pentane, hexane, heptane, heptane fraction, octane and a mixture thereof.

8. The process according to claim 3, wherein the ester used is selected from the group consisting of ethyl acetate, propyl acetate, butyl acetate and a mixture thereof.

9. The process according to claim 1, wherein the extracted fatty acids are separated off from the extraction medium by distillation at atmospheric pressure or reduced pressure of the extraction medium comprising fatty acids.

10. The process according to claim 1, wherein the basic organic nitrogen compound used is a tertiary amine.

11. The process according to claim 1, wherein the basic organic nitrogen compound used is selected from the group consisting of 2-dimethylaminoethanol, 2-methylaminodiethanol, 4-methylmorpholine, 2-diisopropylaminoethanol, 2-dibutylaminoethanol, 2-dimethylaminopropanol, 1-dimethylamino-2-propanol, 2-dimethylaminoethanol, 2-methylamino-1-butanol, 2-(methylethylamino)ethanol, dimethylformamide, morpholine, pyridine, 2-dimethylamino-2-methyl-1-propanol, 4-methylpyridine, 1-methylpyrrole, 2-dibutylaminoethanol, 2-dimethylaminoethylamine, monoethanolamine, 3-dimethylamino-1-propanol, dimethylamino-2-propanone, 1-dimethylamino-1-propylenamine, and a mixture of these compounds.

12. The process according to claim 1, wherein the content of the basic organic nitrogen compounds in the extraction medium is between about 30% by weight and about 40% by weight.

13. The process according to claim 3, wherein the ester is an acetate.

17. The process according to claim 5, wherein the organic nitrogen compound(s) dissolved in the water or the aqueous solution of volatile acids after the extraction step is/are separated off by distillation.

4. The process for removing free fatty acids from steam distillates of fats or oils of biological original comprising:

extracting the free fatty acids with a mixture of basic organic nitrogen compounds and water as extraction medium at a temperature below the boiling point of the organic nitrogen compounds, wherein the content of the basic organic nitrogen compounds in the extraction medium is at least about 40% by weight and at most about 60% by weight, and the boiling point of the basic organic nitrogen compound(s) used is equal to or above the boiling point of water and below the boiling point of the fatty acids to be extracted; and

adding from 1 to 4 parts, of alkane and/or of an ester, to 1 part of the liquid homogeneous mixture obtained in the preceding extraction step.

14. The process according to claim 4, wherein the ester is an acetate.

15. The process according to claim 4, wherein the content of the basic organic nitrogen compounds in the extraction medium is at least about 50% by weight.

16. The process according to claim 4, wherein from 2 to 4 parts of alkane and/or an ester are added to 1 part of the liquid homogeneous mixture obtained in the extraction step.

18. The process according to claim 4, wherein the alkane used is selected from the group consisting of propane, butane, pentane, hexane, heptane, heptane fraction, octane or a mixture thereof.

19. The process according to claim 4, wherein the ester used is selected from the group consisting of ethyl acetate, propyl acetate, butyl acetate and a mixture thereof.

20. The process according to claim 4, wherein the extracted fatty acids are separated off from the extraction medium by distillation at atmospheric pressure or reduced pressure of the extraction medium comprising the fatty acids.

21. The process according to claim 4, wherein the basic organic nitrogen compound used is a tertiary amine.

22. The process according to claim 4, wherein the basic organic nitrogen compound used is selected from the group consisting of 2-dimethylaminoethanol, 2-methylaminodiethanol, 4-methylmorpholine, 2-diisopropylaminoethanol, 2-dibutyl-aminoethanol, 2-dimethylaminopropanol, 1-dimethylamino-2-propanol, 2-dimethylaminoethanol, 2-methylamino-1-butanol, 2-(methylethylamino)ethanol, dimethylformamide, morpholine, pyridine, 2-dimethylamino-2-methyl-1-propanol, 4-methylpyridine, 1-methylpyrrole, 2-dibutylaminoethanol, 2-dimethylaminoethylamine, monoethanolamine, 3-dimethylamino-1-propanol, dimethylamino-2-propanone, 1-dimethylamino-1-propylenamine, and a mixture of these compounds.