Biological fluid absorbing pressure sensitive adhesives

• US 6,583,220 B1
• Filed: 02/29/2000
• Issued: 06/24/2003
• Est. Priority Date: 08/29/1997
• Status: Expired due to Term

• Current Assignee: Avery Dennison Corporation
• Original Assignee: Avery Dennison Corporation
• Inventors: Lipman, Roger D. A.
• Primary Examiner(s): MULLIS, JEFFREY C
• Application Number:
  US09/486,618
• Time in Patent Office: 1,211 Days
• Field of Search: 525/54.31, 525/54.3, 525/54.32, 525/88, 525/92.L, 525/98, 525/99
• US Class Current: 525/54.3
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C09J 153/02 Vinyl aromatic monomers and conjugated dienes

Abstract

A pressure-sensitive adhesive material made of an elastic mixture comprising a continuous phase formed from a physically cross-linked solid rubber such as a styrene-olefin-styrene block copolymer, for example a styrene-isoprene-styrene block copolymer, and a compatible liquid rubber, such as a liquid styrene-isoprene, and a discontinuous phase substantially comprised of one or more “swellable polymers”, absorbents that are swellable in water. Additives such as polybutenes, polyisobutylene, mineral oil, stabilizers and other rubbers, may be present. Water soluble polymers may be added to the swellable absorbents to form part of the discontinuous phase. The pressure-sensitive adhesives the advantage over the prior are that they avoid the need to include materials known to irritate skin and mucous membranes. In particular, prior art compositions have needed to include substantial quantities of tackifying resins, which could cause problems particularly in wound dressings. The preferred compositions of the invention include no resins although minor amounts of up to 15 wt. %, preferably not more than 5%, of resinous materials may be included. The adhesive layer can be combined with a non-adhesive, water impervious film and can be used in wound care, ostomy care and in other medical products.

Claims

1. A pressure-sensitive adhesive material comprising a mixture of:

(a) a continuous phase formed from a physically cross-linked solid rubber, a compatible liquid rubber, other than polyisobutylene and 0 to 9.37 wt. % of tackifiers other than said rubbers, based on the total composition, wherein the weight ratio of said liquid rubber to said solid rubber is from 3;

2 to 7;

1; and

(b) 10 to 70% by weight, based on the total adhesive material, of a discontinuous phase comprising one or more hydrophilic polymers that are soluble and/or swellable in water.

2. An adhesive material according to claim 1 wherein the discontinuous phase includes at least one insoluble but water-absorbent and swellable polymer.

3. An adhesive material according to claim 2 wherein the water insoluble polymer is selected from cross-linked sodium carboxymethyl cellulose, crystalline sodium carboxymethyl cellulose, cross-linked dextran, calcium alginate, starch-acrylonitrile graft polymer, starch sodium polyacrylate, gluten, polymers of methylvinyl ether and maleic acid and derivatives thereof.

4. An adhesive material according to claim 1 wherein the discontinuous phase includes one or more water soluble hydrocolloids.

5. An adhesive material according to claim 4 wherein the soluble hydrocolloid is selected from sodium carboxymethyl cellulose, pectin, gelatin, guar gum, locust bean gum, collagen, karaya gum, alginic acid, sodium alginates, sodium-calcium alginates, polyvinyl alcohol, polyvinyl pyrrolidone, polyethylene glycols and polypropylene glycol.

7. An adhesive material according to claim 1 wherein the cross-linked solid rubber of the continuous phase (a) includes at least one linear or radial A-B-A block copolymer based on styrene-butadiene, styrene isoprene or hydrogenated styrene-diene copolymers.

8. An adhesive material according to claim 7 wherein the continuous phase (a) comprises up to 85% by weight relative to the A-B-A block copolymer(s) of one or more styrene-butadiene, styrene isoprene or hydrogenated styrene-diene AB block copolymers.

9. An adhesive material according to claim 8 wherein the AB block copolymer(s) are present in an amount of 10 to 50% by weight relative to the A-B-A block copolymer(s).

10. An adhesive material according to claim 1 wherein the liquid rubber has a molecular weight of 25,000 to 50,000.

11. An adhesive material according to claim 1 wherein the liquid rubber has a glass transition temperature of less than −

50°

C.

12. An adhesive material according to claim 1 wherein the liquid rubber has a viscosity at 38°

C. to 50 to 1000 Pas.

13. An adhesive material according to claim 1 wherein the weight ratio of liquid rubber to solid rubber within the continuous phase (a) is at least 2:

1.

14. An adhesive barrier or dressing for medical use, comprising a non-adhesive, waterproof film having coated thereon a layer of a pressure-sensitive adhesive material according to claim 1.

15. An adhesive barrier or dressing for medical use, comprising a non-adhesive, waterproof film having coated thereon a layer of pressure-sensitive adhesive material according to claim 1.

16. An adhesive material according to claim 1 wherein said continuous phase (a) additionally contains up to 80% by weight of at least one polyisobutylene having a viscosity average molecular weight of 36,000 to 70,000.

17. An adhesive material according to claim 1 which contains not more than 5% by weight of resinous material other than low molecular weight polymers and said rubbers.

18. An adhesive material according to claim 1 which contains no resinous materials other than low molecular weight polymers and said rubbers.

6. An adhesive material according to claim wherein the hydrophilic polymer phase (b) comprises 20 to 55% by weight of the total adhesive material.