Low reflection, high transmission, touch-panel membrane

• US 6,583,935 B1
• Filed: 09/19/2000
• Issued: 06/24/2003
• Est. Priority Date: 05/28/1998
• Status: Expired due to Term

• Current Assignee: Eastman Performance Films, LLC (Eastman Chemical Company)
• Original Assignee: CPFilms Inc. (Eastman Chemical Company)
• Inventors: Wrzesinski, Andrew, Saif, Mohtashim, Memarian, Hassan
• Primary Examiner(s): Juba, Jr., John
• Application Number:
  US09/665,053
• Time in Patent Office: 1,008 Days
• Field of Search: 359/580, 359/582, 359/585, 428/333, 200/512, 200/514, 313/479
• US Class Current: 359/582
• CPC Class Codes: B32B 15/08 of synthetic resin
• CPC Class Codes: B32B 27/06 as the main or only constituent of a layer, which is next to another layer of the same or of a different material next to a layer of a particular substance B32B9/045; next to a bituminous or tarry layer B32B11/046; next to a water setting substance layer B32B13/12; next to a metal layer B32B15/08; next to a glass layer B32B17/10; next to a layer formed of natural mineral fibres or particles B32B19/045; next to a wood layer B32B21/08; next to a cellulosic plastic layer B32B23/08; next to a natural or synthetic rubber layer B32B25/08
• CPC Class Codes: G02B 1/116 including electrically conducting layers
• CPC Class Codes: G06F 3/041 Digitisers, e.g. for touch screens or touch pads, characterised by the transducing means
• CPC Class Codes: G06F 3/0412 Digitisers structurally integrated in a display
• CPC Class Codes: Y10T 428/261 In terms of molecular thickness or light wave length

Abstract

Low reflective, flexible, transparent, laminates having a sheet of flexible plastic substrate, a conductive outer layer on one side of the sheet, and an anti-reflective stack of at least one pair of oxide layers on at least one of the sides of the sheet, adapted for use as touch panel membrane electrodes in screen interface displays. A preferred laminate includes a flexible, polyethylene terephthalate sheet substrate having on one side a outer conductive surface of indium tin oxide and on one or both sides an anti-reflective stack of oxide layers, e.g., a stack of a layer of silicon dioxide and a layer of indium tin oxide. Preferred laminates have at least 90% transmission and less than 2% reflection of visible light in the range of 460 to 700 nm and are especially useful as touch panel electrodes, e.g., on computer display screens.

Claims

1. A low reflective, transparent electrode comprising:

(a) a sheet of flexible plastic substrate having first and second sides;

(b) a first hardcoat adjacent to said first side of said substrate and a second hardcoat adjacent to said second side of said substrate, said first and second hardcoats being anti-glare hardcoats;

(c) an anti-reflective stack adjacent to said first or second hardcoat, said anti-reflective stack comprising at least one pair of layers of materials of different refractive index; and

(d) a conductive outer layer adjacent to said anti-reflective stack.

2. The electrode according to claim 1 wherein said conductive outer layer comprises a conductive metal oxide or a conductive polymer.

3. The electrode according to claim 1 wherein said conductive outer layer consists essentially of indium tin oxide.

4. The electrode of claim 1 wherein said electrode has an average visible light reflection of not more than 6% and visible light transmission of at least 80% in the visible light range of 400 to 700 nm.

5. The electrode according to claim 1 having an average visible light reflection of not more than 2% and visible light transmission of at least 90% in the visible light range of 400 to 700 nm.

6. The electrode according to claim 1 in a form of a wound roll of continuous web.

7. The electrode according to claim 1 in which said first and second anti-glare hardcoats are clear.

8. The electrode of claim 1 in which said first or second hardcoat is adjacent to said anti-reflective stack and said hardcoat adjacent to said anti-reflective stack is selected to provide an anti-reflective characteristic so that said hardcoat adjacent to said anti-reflective stack functions as an anti-reflective layer of said stack in addition to providing a durability characteristic of a hardcoat layer.

9. The electrode according to claim 1 which is configured for application other than a touch screen application.

10. The electrode according to claim 1 in which said flexible polymer substrate is polyethylene terephthalate.

11. In a device where data is entered by pressure activation on the surface of a display screen having a membrane electrode, the improvement wherein said membrane electrode comprises at least one flexible, transparent electrode wherein said flexible transparent electrode comprises:

(a) a sheet of flexible plastic substrate having first and second sides;

(b) a first hardcoat adjacent to said first side of said substrate and a second hardcoat adjacent to said second side of said substrate;

(c) an anti-reflective stack adjacent to said first or second hardcoat, said anti-reflective stack comprising at least one pair of layers of materials of different refractive index; and

(d) a conductive outer layer adjacent to said anti-reflective stack.

12. A low reflective, transparent electrode comprising:

a) a sheet of flexible plastic substrate having first and second sides;

b) a first hardcoat adjacent to said first side of said substrate and a second hardcoat adjacent to said second side of said substrate;

c) a first anti-reflective stack adjacent to said first hardcoat, said first anti-reflective stack comprising at least one pair of layers of materials of different refractive index;

d) a second anti-reflective stack adjacent to said second hardcoat, said second anti-reflective stack comprising at least one pair of layers of materials of different refractive index, said first or said second anti-reflective stack being nonconductive; and

e) a conductive outer layer adjacent to said first anti-reflective stack or said second anti-reflective stack.

13. The electrode according to claim 12 wherein said conductive outer layer comprises a conductive metal oxide or a conductive polymer.

14. The electrode according to claim 12 wherein said conductive outer layer consists essentially of indium tin oxide.

15. The electrode of claim 12 wherein said electrode has an average visible light reflection of not more than 6% and visible light transmission of at least 80% in the visible light range of 400 to 700 nm.

16. The electrode according to claim 12 having an average visible light reflection of not more than 2% and visible light transmission of at least 90% in the visible light range of 400 to 700 nm.

17. The electrode according to claim 12 in a form of a wound roll of continuous web.

18. The electrode according to claim 12 wherein said first or second anti-reflective stack comprises at least one pair of layers comprising a layer of silicon dioxide and an adjacent layer of indium tin oxide.

19. The electrode according to claim 12 wherein said first or second anti-reflective stack is conductive.

20. The electrode, according to claim 12 in which said first and second hardcoats are clear hardcoats.

21. The electrode of claim 12 in which said first hardcoat is adjacent to said first anti-reflective stack and said first hardcoat adjacent to said anti-reflective stack is selected to provide an anti-reflective characteristic so that said first hardcoat adjacent to said first anti-reflective stack functions as an anti-reflective layer of said first anti-reflective stack in addition to providing a durability characteristic of a hardcoat layer;

or said second hardcoat is adjacent to said second anti-reflective stack and said second hardcoat adjacent to said second anti-reflective stack is selected to provide an anti-reflective characteristic so that said second hardcoat adjacent to said second anti-reflective stack functions as an anti-reflective layer of said second anti-reflective stack in addition to providing a durability characteristic of a hardcoat layer.

22. The electrode according to claim 12 which further comprises an outer layer of a low surface energy material on a side opposite the outer conductive layer.

23. The electrode according to claim 12 which is configured for application other than a touch screen application.

24. In a device where data is entered by pressure activation on the surface of a display screen having a membrane electrode, the improvement wherein said membrane electrode comprises at least one flexible transparent electrode wherein said flexible transparent electrode comprises:

a) a sheet of flexible plastic substrate having first and second sides;

b) a first hardcoat adjacent to said first side of said substrate and a second hardcoat adjacent to said second side of said substrate;

c) a first anti-reflective stack adjacent to said first hardcoat, said first anti-reflective stack comprising at least one pair of layers of materials of different refractive index;

d) a second anti-reflective stack adjacent to said second hardcoat, said second anti-reflective stack comprising at least one pair of layers of materials of different refractive index; and

e) a conductive outer layer adjacent to said first anti-reflective stack or said second anti-reflective stack.

25. A low reflective transparent electrode comprising:

a) a sheet of flexible polymeric substrate;

b) a hardcoat adjacent to one side of said polymeric substrate;

c) a first anti-reflective stack adjacent to said hardcoat and a second anti-reflective stack adjacent to said substrate, said first or second anti-reflective stack being nonconductive and said first and second anti-reflective stacks each comprising at least one pair of layers of materials having different refractive index; and

d) a conductive outer layer on said first anti-reflective stack or on said second anti-reflective stack.

26. The electrode of claim 25 wherein said conductive outer layer is adjacent to said first anti-reflective stack.

27. The electrode of claim 25 wherein said conductive outer layer is adjacent to said second anti-reflective stack.

28. The electrode according to claim 25 wherein said hardcoat is either a clear hardcoat or an anti-glare hardcoat.

29. The electrode according to claim 25 wherein said conductive outer layer comprises a conductive metal oxide or a conductive polymer.

30. The electrode according to claim 25 wherein said conductive outer layer consists essentially of indium tin oxide.

31. The electrode of claim 25 wherein said electrode has an average visible light reflection of not more than 6% and visible light transmission of at least 80% in the visible light range of 400 to 700 nm.

32. The electrode according to claim 25 having an average visible light reflection of not more than 2% and visible light transmission of at least 90% in the visible light range of 400 to 700 nm.

33. The electrode according to claim 26 in a form of a wound roll of continuous web.

34. An electrode according to claim 25 wherein said first or second anti-reflective stack comprises at least one pair of layers comprising a layer of silicon dioxide and an adjacent layer of indium tin oxide.

35. The electrode of claim 25 wherein said hardcoat is selected to provide mechanical durability and to provide an anti-reflective characteristic so that said hardcoat in combination with said anti-reflective stack has an anti-reflective function.

36. The electrode according to claim 25 which further comprises having an outer layer of a low surface energy material on a side opposite the outer conductive layer.

37. The electrode according to claim 25 which is configured for application other than for the touch screen application.

38. The electrode of claim 25 wherein said substrate is polyethylene terephthalate and said outer conductive layer comprises a layer of indium tin oxide and said first or second anti-reflective stack comprises at least one layer of silicon dioxide and at least one layer of indium tin oxide adjacent to said layer of silicon dioxide.

39. In a device where data is entered by pressure activation on the surface of a display screen having a membrane electrode, the improvement wherein said membrane electrode comprises at least one flexible transparent electrode wherein said flexible transparent electrode comprises;

a) a sheet of flexible polymeric substrate;

b) a hardcoat adjacent to one side of said polymeric substrate;

c) a first anti-reflective stack adjacent to said hardcoat and a second anti-reflective stack adjacent to said substrate, said first and second anti-reflective stacks each comprising at least one pair of layers of materials having different refractive index; and

d) a conductive outer layer on said first anti-reflective stack or on said second anti-reflective stack.

40. A low reflective, transparent electrode comprising:

(a) a sheet of flexible plastic substrate having first and second sides;

(b) a first hardcoat adjacent to said first side of said substrate and a second hardcoat adjacent to said second side of said substrate, said first hardcoat being a clear hardcoat and said second hardcoat being an anti-glare hardcoat;

(c) an anti-reflective stack adjacent to said first or second hardcoat, said anti-reflective stack comprising at least one pair of layers of materials of different refractive index; and

(d) a conductive outer layer adjacent to said anti-reflective stack.

41. A low reflective, transparent electrode comprising:

a) a sheet of flexible plastic substrate having first and second sides;

b) a first hardcoat adjacent to said first side of said substrate and a second hardcoat adjacent to said second side of said substrate, said first and second hardcoats being anti-glare hardcoats;

c) a first anti-reflective stack adjacent to said first hardcoat, said first anti-reflective stack comprising at least one pair of layers of materials of different refractive index;

d) a second anti-reflective stack adjacent to said second hardcoat, said second anti-reflective stack comprising at least one pair of layers ,of materials of different refractive index, and

e) a conductive outer layer adjacent to said first anti-reflective stack or said second anti-reflective stack.

42. A low reflective, transparent electrode comprising:

a) a sheet of flexible plastic substrate having first and second sides;

b) a first hardcoat adjacent to said first side of said substrate and a second hardcoat adjacent to said second side of said substrate, said first hardcoat being a clear hardcoat and said second hardcoat being an anti-glare hardcoat;

c) a first anti-reflective stack adjacent to said first hardcoat, said first anti-reflective stack comprising at least one pair of layers of materials of different refractive index;

d) a second anti-reflective stack adjacent to said second hardcoat, said second anti-reflective stack comprising at least one pair of layers of materials of different refractive index; and

e) a conductive outer layer adjacent to said first anti-reflective stack or said second anti-reflective stack.