Organic light-emitting device

• US 6,586,876 B2
• Filed: 05/22/2001
• Issued: 07/01/2003
• Est. Priority Date: 01/18/2001
• Status: Expired due to Term

• Current Assignee: Display Vectors LLC (Jeffrey M. Gross)
• Original Assignee: Industrial Technology Research Institute
• Inventors: Tsai, Rung-Ywan, Hua, Mu-Yi, Chao, Ching-Ian, Chang, Chia-Shy
• Primary Examiner(s): Jones, Deborah
• Assistant Examiner(s): Piziali, Andrew T
• Application Number:
  US09/861,528
• Publication Number:
  US 20020094422A1
• Time in Patent Office: 770 Days
• Field of Search: 428/212, 428/428, 428/432, 428/448, 428/697, 428/699, 428/701, 428/702, 428/426, 428/446, 428/457, 428/469, 428/472, 428/688, 428/689, 313/505, 313/509
• US Class Current: 313/509
• CPC Class Codes: B32B 27/06 as the main or only constituent of a layer, which is next to another layer of the same or of a different material next to a layer of a particular substance B32B9/045; next to a bituminous or tarry layer B32B11/046; next to a water setting substance layer B32B13/12; next to a metal layer B32B15/08; next to a glass layer B32B17/10; next to a layer formed of natural mineral fibres or particles B32B19/045; next to a wood layer B32B21/08; next to a cellulosic plastic layer B32B23/08; next to a natural or synthetic rubber layer B32B25/08
• CPC Class Codes: B32B 7/023 Optical properties
• CPC Class Codes: H10K 2101/80 Composition varying spatially, e.g. having a spatial gradient
• CPC Class Codes: H10K 50/85 Arrangements for extracting light from the devices
• CPC Class Codes: H10K 50/858 comprising refractive means, e.g. lenses
• CPC Class Codes: Y10T 428/24926 including ceramic, glass, porcelain or quartz layer
• CPC Class Codes: Y10T 428/24942 including components having same physical characteristic in differing degree
• CPC Class Codes: Y10T 428/31678 Of metal

Abstract

The present invention relates to an organic light-emitting device which provides an electroluminescence (EL) or photoluminescence (PL) device with high external quantum efficiency. The present invention forms a composite film layer with continuously changing refraction indices between an ITO transparent electrode and a substrate made of plastic or glass. The refraction index of the composite film layer is the same as the ITO electrode at the interface with the ITO electrode. It decreases along the direction perpendicular to the substrate in a linear or nonlinear way. The refraction index is the same as that of the plastic or glass at the interface with the substrate. This way can avoid reflection due to the difference in the refraction index across the interface. The excited light originally trapped in the ITO electrode can be guided outwards. A preferred mean is to incorporate a photon wave guide formed at the interface between the substrate and the air to increase the external quantum efficiency of this type of organic light-emitting devices.

Claims

1. An organic light-emitting device comprising:

a substrate, which is light-transmitting;

a transparent ITO electrode, which is above an upper surface of the substrate as an anode;

a composite film layer with a gradually varying refraction index, which is sandwiched between the substrate and the transparent ITO electrode, and whose refraction indices at the two interfaces are substantially the same as those of the ITO electrode and the substrate, respectively, as it varies along the direction perpendicular to the substrate;

an organic light-emitting layer, which is formed on the ITO electrode; and

a metal conduction electrode, which is formed on the organic light-emitting layer.

2. The device of claim 1, wherein the substrate is a glass substrate.

3. The device of claim 1, wherein the substrate is a plastic substrate.

4. The device of claim 3, wherein the plastic substrate material is selected from the group comprising acrylic, epoxy, polyethylene terephthalate (PET), and polycarbonate (PC).

5. The device of claim 1, wherein the substrate further has a photon wave guide at an interface that is exposed to air, the photon wave guide being directly formed on a surface of the substrate and its effective refraction index decreasing along a direction perpendicular to the substrate from the substrate to the air.

6. The device of claim 5, wherein the photon wave guide is composed of a plurality of pyramid objects disposed along one dimension.

7. The device of claim 5, wherein the photon wave guide is composed of a plurality of cubic objects disposed periodically along one dimension and the periodic length is smaller than the wavelengths of visible light.

8. The device of claim 5, wherein the photon wave guide is composed of a plurality of triangular ridges disposed in parallel.

9. The device of claim 5, wherein the photon wave guide is composed of a plurality of rectangular ridges disposed in parallel and periodically and the periodic length is smaller than the wavelengths of visible light.

10. The device of claim 5, wherein the photon wave guide is composed of a plurality of geometrical objects disposed periodically.

11. The device of claim 5, wherein the photon wave guide is pressed and printed on the substrate by thermal roll pressing.

12. The device of claim 5, wherein the photon wave guide is made by reactive ion beam etching along with gray scale masking.

13. The device of claim 1, wherein the composite film layer with a gradually varying refraction index is a mixture of two materials with different refraction indices.

14. The device of claim 13, wherein one of the materials is a high refraction index material that is selected from the group consisting of ZrO₂, TiO₂, Ta₂O₅, and Nb₂O₅, whose refraction indices are all greater than 1.8.

15. The device of claim 13, wherein one of the materials is a low refraction index material that is selected from the group consisting of SiO₂, MgF₂, and CaF₂, whose refraction indices are all smaller than 1.5.

16. An organic light-emitting device, comprising:

a light-transmitting substrate having a predetermined refraction index;

a light-transmitting anode electrode having a refraction index that is different from the refraction index of the substrate, the anode electrode being spaced apart from the substrate;

a composite film layer sandwiched between the substrate and the anode electrode so as to have an interface with the substrate and an interface with the anode electrode, the composite film layer having a refraction index that varies, in a direction perpendicular to the substrate, from a first value adjacent the interface with the substrate to a second value adjacent the interface with the anode electrode, the first value being substantially the same as the refraction index of the substrate and the second value being substantially the same as the refraction index of the anode electrode;

an organic light-emitting layer on the anode electrode; and

a cathode electrode on the light-emitting layer,

wherein the composite film layer is a multi layer structure composed of a plurality of films made of at least two materials with different refraction indices, and the refraction index of the composite film layer varies as a function of the thickness of each film and the composition ratio of the at least two materials therein.

17. The device of claim 16, wherein each film in the composite film layer is formed between the substrate and the anode electrode using low-temperature ion-assisted electron beam coevaporation.

18. The device of claim 16, wherein each film in the composite film layer is formed between the substrate and the anode electrode by coevaporation.

19. The device of claim 16, wherein the refraction index of the composite film layer is a linear function of its thickness.

20. The device of claim 16, wherein the refraction index of the composite film layer is a stair-shape function of its thickness.