Low solids gas generant having a low flame temperature

• US 6,589,375 B2
• Filed: 03/02/2001
• Issued: 07/08/2003
• Est. Priority Date: 03/02/2001
• Status: Expired due to Fees

• Current Assignee: Tally Defense Systems, Inc.
• Original Assignee: Nammo Talley, Inc. (Nammo AS)
• Inventors: Ludwig, Christopher P., McFadden, Dan, Dupont, James, Deppert, Thomas M., Knowlton, Gregory D., Salafia, Christian
• Primary Examiner(s): Delcotto, Gregory
• Application Number:
  US09/798,547
• Publication Number:
  US 20030094225A1
• Time in Patent Office: 858 Days
• Field of Search: 149/45, 149/74, 149/88, 149/92
• US Class Current: 149/45
• CPC Class Codes: C06B 23/009 Wetting agents, hydrophobing agents, dehydrating agents, antistatic additives, viscosity improvers, antiagglomerating agents, grinding agents and other additives for working up
• CPC Class Codes: C06B 23/04 for cooling the explosion gases including antifouling and flash suppressing agents
• CPC Class Codes: C06D 5/06 by reaction of two or more solids

Abstract

A low-solids gas generating composition and a method of generating a gas with low solids by preparing and combusting the low-solids gas generating composition. The compositions of the invention include a mixture of a basic copper nitrate oxidizer and a fuel selected for the group consisting of 5-nitro-uracil, guanidine 5-nitro-uracil salt, ammonium 5-nitro-uracil salt, aminoguanidine 5-nitro-uracil salt, hydrazine 5-nitro-uracil salt, triamino 5-nitro-uracil salt, guanidine 5-nitro-barbituric acid salt, ammonium 5-nitro-barbituric acid salt, hydrazine 5-nitro-barbituric acid salt, aminoguanidine 5-nitro-barbituric acid salt, triaminoguanidine 5-nitro-barbituric acid salt, and mixtures thereof, wherein the oxidizer-fuel mixture is within about 4 percent of stoichiometric balance, and produces no more than about 0.06 cubic centimeters of solids per gram of gas generating composition on combustion. The compositions of the invention may further include at least one of cupric oxalate hemi-hydrate, sub-micron fumed silica, and graphite.

Claims

1. A low-solids gas generating composition, comprising a mixture of a basic copper nitrate oxidizer, a fuel selected for the group consisting of 5-nitro-uracil, guanidine 5-nitro-uracil salt, ammonium 5-nitro-uracil salt, aminoguanidine 5-nitro-uracil salt, hydrazine 5-nitro-uracil salt, triamino 5-nitro-uracil salt, guanidine 5-nitro-barbituric acid salt, ammonium 5-nitro-barbituric acid salt, hydrazine 5-nitro-barbituric acid salt, aminoguanidine 5-nitro-barbituric acid salt, triaminoguanidine 5-nitro-barbituric acid salt, and mixtures thereof, and sub-micron fumed silica, wherein the oxidizer-fuel mixture is within about 4 percent of stoichiometric balance, and produces no more than about 0.06 cubic centimeters of solids per gram of gas generating composition on combustion.

2. The gas generating composition of claim 1, further comprising graphite.

3. The gas generating composition of claim 1, further comprising cupric oxalate hemi-hydrate.

4. The gas generating composition of claim 1, wherein the gas generant is in the form of pressed pellets, grains, or granules.

5. The gas generating composition of claim 1, comprising 5-nitro-uracil, basic copper nitrate, and fumed silica.

6. The gas generating composition of claim 5, comprising from about 17.2 to about 39.3 percent 5-nitro-uracil, from about 82 to about 60.1 percent basic copper nitrate, and up to about 0.8 percent fumed silica.

7. The gas generating composition of claim 1, comprising 5-nitro-uracil, basic copper nitrate, fumed silica, and anhydrous activated Al₂O₃.

8. The gas generating composition of claim 7, comprising from about 16.5 to about 37.7 percent 5-nitro-uracil, from about 78.7 to about 57.7 percent basic copper nitrate, up to about 0.8 percent fumed silica, and up to about 4 percent anhydrous activated Al₂O₃.

9. The gas generating composition of claim 1, comprising guanidine 5-nitro-uracil salt, basic copper nitrate and fumed silica.

10. The gas generating composition of claim 9, comprising from about 13.6 to about 32.3 percent guanidine 5-nitro-uracil salt, from about 84.7 to about 66.4 percent basic copper nitrate, and up to about 1.7 percent fumed silica.

11. The gas generating composition of claim 1, comprising ammonium 5-nitro-uracil salt, basic copper nitrate and fumed silica.

12. The gas generating composition of claim 11, comprising from about 15.3 to about 35.6 percent ammonium 5-nitro-uracil salt, from about 83 to about 63 percent basic copper nitrate, and up to about 1.7 percent fumed silica.

13. The gas generating composition of claim 1, comprising aminoguanidine 5-nitro-uracil salt, basic copper nitrate and fumed silica.

14. The gas generating composition of claim 13, comprising from about 22.8 to about 32.7 percent aminoguanidine 5-nitro-uracil salt, from about 75.7 to about 66 percent basic copper nitrate, and up to about 1.5 percent fumed silica.

15. The gas generating composition of claim 1, comprising hydrazine 5-nitro-uracil salt, basic copper nitrate and fumed silica.

16. The gas generating composition of claim 15, comprising from about 15.5 to about 36 percent hydrazine 5-nitro-uracil salt, from about 82.8 to about 62.7 percent basic copper nitrate, and up to about 1.7 percent fumed silica.

17. The gas generating composition of claim 1, comprising triaminoguanidine 5-nitro-uracil salt, basic copper nitrate and fumed silica.

18. The gas generating composition of claim 17, comprising from about 14.2 to about 33.4 percent triaminoguanidine 5-nitro-uracil salt, from about 84.4 to about 65.3 percent basic copper nitrate, and up to about 1.7 percent fumed silica.

19. The gas generating composition of claim 1, comprising guanidine 5-nitro-barbituric acid salt, basic copper nitrate, and fumed silica.

20. The gas generating composition of claim 19, comprising from about 15.7 to about 36.5 percent guanidine 5-nitro-barbituric acid salt, from about 82.6 to about 62.3 percent basic copper nitrate, and up to about 1.7 percent fumed silica.

21. The gas generating composition of claim 1, comprising ammonium 5-nitro-barbituric acid salt, basic copper nitrate and fumed silica.

22. The gas generating composition of claim 21, comprising from about 18.4 to about 41.8 percent ammonium 5-nitro-barbituric acid salt, from about 80 to about 57 percent basic copper nitrate, and up to about 1.6 percent fumed silica.

23. The gas generating composition of claim 1, comprising hydrazine 5-nitro-barbituric acid salt, basic copper nitrate and fumed silica.

24. The gas generating composition of claim 23, comprising from about 18.4 to about 41.7 percent hydrazine nitro-barbituric acid salt, from about 80 to about 57.2 percent basic copper nitrate, and up to about 1.6 percent fumed silica.

25. The gas generating composition of claim 1, comprising aminoguanidine 5-nitro-barbituric acid salt, basic copper nitrate and fumed silica.

26. The gas generating composition of claim 25, comprising from about 15.8 to about 36.7 percent aminoguanidine 5-nitro-barbituric acid salt, from about 82.5 to about 62.1 percent basic copper nitrate, and up to about 1.7 percent fumed silica.

27. The gas generating composition of claim 1, comprising triaminoguanidine 5-nitro-barbituric acid salt, basic copper nitrate and fumed silica.

28. The gas generating composition of claim 27, comprising from about 16 to about 37.1 percent triaminoguanidine 5-nitro-barbituric acid salt, from about 82.4 to about 61.7 percent basic copper nitrate, and up to about 1.6 percent fumed silica.

29. The gas generating composition of claim 1, comprising basic copper nitrate, cupric oxalate hemi-hydrate, 5-nitro-uracil, and fumed silica.

30. The gas generating composition of claim 29, comprising from about 50 to about 27.9 percent basic copper nitrate, about 50 percent cupric oxalate hemi-hydrate, and up to about 22.1 percent 5-nitro-uracil.

31. The gas generating composition of claim 1, comprising basic copper nitrate, cupric oxalate hemi-hydrate, guanidine 5-nitro-uracil salt, and fumed silica.

32. The gas generating composition of claim 31, comprising from about 50 to about 31.7 percent basic copper nitrate, about 50 percent cupric oxalate hemi-hydrate, and up to about 18.3 percent guanidine 5-nitro-uracil salt.

33. The gas generating composition of claim 1, comprising basic copper nitrate, guanidine nitrate, 5-nitro-uracil, cupric oxalate hemi-hydrate, graphite and fumed silica.

34. The gas generating composition of claim 1, comprising about 40.4 percent basic copper nitrate, about 6.6 percent guanidine nitrate, about 18.6 percent 5-nitro-uracil, about 33.3 percent cupric oxalate hemi-hydrate, about 0.3 percent graphite, and about 0.8 percent fumed silica.

35. A method of generating a gas with low-solids, the method comprising:

preparing a mixture comprising a basic copper nitrate oxidizer, a fuel selected for the group consisting of 5-nitro-uracil, guanidine 5-nitro-uracil salt, ammonium 5-nitro-uracil salt, aminoguanidine 5-nitro-uracil salt, hydrazine 5-nitro-uracil salt, triamino 5-nitro-uracil salt, guanidine 5-nitro-barbituric acid salt, ammonium 5-nitro-barbituric acid salt, hydrazine 5-nitro-barbituric acid salt, aminoguanidine 5-nitro-barbituric acid salt, triaminoguanidine 5-nitro-barbituric acid salt, and mixtures thereof, and sub-micron fumed silica wherein the oxidizer-fuel mixture is within about 4 percent of stoichiometric balance;

combusting the mixture, thereby producing a gas and no more than about 0.06 cubic centimeters of solids per gram of gas generating composition on combustion.

36. The method of claim 35, further comprising adding at least one of cupric oxalate hemi-hydrate and graphite to the mixture of oxidizer and fuel.