Aromatic polyester composition

• US 6,590,044 B2
• Filed: 08/15/2002
• Issued: 07/08/2003
• Est. Priority Date: 06/26/1998
• Status: Expired due to Fees

• Current Assignee: Teijin Limited
• Original Assignee: Teijin Limited
• Inventors: Yoshida, Yoichi, Suzuki, Minoru, Nagano, Hiroki
• Primary Examiner(s): RAYFORD, SANDRA M
• Application Number:
  US10/218,592
• Publication Number:
  US 20030082322A1
• Time in Patent Office: 327 Days
• Field of Search: 525/437, 525/444
• US Class Current: 525/437
• CPC Class Codes: C08G 63/189 containing a naphthalene ring
• CPC Class Codes: C08L 2666/18 Polyesters or polycarbonates according to C08L67/00 - C08L69/00; Derivatives thereof
• CPC Class Codes: C08L 67/02 Polyesters derived from dicarboxylic acids and dihydroxy compounds C08L67/06 takes precedence
• CPC Class Codes: Y10T 428/1352 Polymer or resin containing [i.e., natural or synthetic]
• CPC Class Codes: Y10T 428/1379 Contains vapor or gas barrier, polymer derived from vinyl chloride or vinylidene chloride, or polymer containing a vinyl alcohol unit
• CPC Class Codes: Y10T 428/31786 Of polyester [e.g., alkyd, etc.]

Abstract

An aromatic polyester composition includes 5 to 95 wt % of an ethylene naphthalenedicarboxylate copolymer and 95 to 5 wt % of an ethylene terephthalate (co)polymer, has a compatibility between these polymers of 0.15 to 0.5, and has a melting point which lowers depending on the content of ethylene naphthalenedicarboxylate. This composition has excellent compatibility, transparency, barrier properties and heat resistance and is an excellent raw material for forming various molded products, particularly bottles. A bottle and its production process are also disclosed.

Claims

1. An aromatic polyester composition comprising:

(A) (a) an ethylene naphthalenedicarboxylate copolymer which contains an ethylene naphthalenedicarboxylate unit in an amount of 94 to 80 mol % based on the total of all the recurring units and an ethylene terephthalate units and/or an ethylene isophthalate unit in an amount of 6 to 20 mol % based on the total of all the recurring units and a diethylene glycol unit in an amount of 0.8 to 2.5 wt % and which has a number of terminal carboxyl groups of 40 eq/10⁶ g or less and a total number of terminal groups of 95 eq/10⁶ g or more, and (b) an ethylene terephthalate (co)polymer which contains an ethylene terephthalate unit in an amount of 100 to 80 mol % based on the total of all the recurring units and an ethylene naphthalenedicarboxylate unit and/or an ethylene isophthalate unit in an amount of 0 to 20 mol % based on the total of all the recurring units and a diethylene glycol unit in an amount of 1.2 to 2.4 wt % and which has a number of terminal carboxyl groups of 30 eq/10⁶ g or less, an intrinsic viscosity of 0.7 or more and a melting temperature of 250°

C. or less, the contents of the ethylene naphthalenedicarboxylate copolymer and the ethylene terephthalate (co)polymer being 5 to 95 wt % and 95 to 5 wt % based on the total weight of these, respectively;

(B) compatibility between the ethylene naphthalenedicarboxylate copolymer and the ethylene terephthalate (co)polymer being 0.15 to 0.5; and

(C) the relationship represented by the following expression (1) being satisfied when the proportion of the ethylene naphthalenedicarboxylate unit to the total of all the recurring units of the ethylene naphthalenedicarboxylate copolymer and all the recurring units of the ethylene terephthalate (co)polymer is 50 mol % or less;

 

Tm≦

254−

28×

EN 

 

(1)

wherein EN is the molar fraction of the ethylene naphthalenedicarboxylate unit in the polyester composition and Tm is the melting point (°

C.) of the polyester composition,

 

and the relationship represented by the following expression (2) being satisfied when the proportion of the ethylene naphthalenedicarboxylate unit to the total of all the recurring units of the ethylene naphthalenedicarboxylate copolymer and all the recurring units of the ethylene terephthalate (co)polymer is more than 50 mol %;

2. The aromatic polyester composition of claim 1, wherein the contents of the ethylene naphthalenedicarboxylate copolymer and the ethylene terephthalate (co)polymer are 5 to 50 wt % and 95 to 50 wt % based on the total weight of these, respectively.

3. The aromatic polyester composition of claim 1, wherein the ethylene naphthalenedicarboxylate copolymer contains acetaldehyde in an amount of as much as 20 ppm.

4. The aromatic polyester composition of claim 1, wherein the ethylene terephthalate (co)polymer contains antimony and/or germanium in an amount of 40 to 250 ppm.

5. The aromatic polyester composition of claim 1, wherein the ethylene terephthalate (co)polymer contains acetaldehyde in an amount of as much as 3 ppm.

6. The aromatic polyester composition of claim 1, wherein the ethylene terephthalate (co)polymer has a crystallinity of 60% or less.

7. The aromatic polyester composition of claim 1, wherein the compatibility is 0.2 to 0.4.

8. The aromatic polyester composition of claim 1, which contains at least one of either antimony or germanium and phosphorus and satisfies the relationships represented by the following expressions (3) and (4):

9. The aromatic polyester composition of claim 1 which has a haze value of 3% or less.

10. A molded product of the aromatic polyester composition of claim 1.

11. The molded product of claim 10 which is a preform.

12. The molded product of claim 10 which is a film or sheet.