Reactive dyes, processes for their preparation and their use
First Claim
1. A reactive dye of the formula (1) in whichR1, R2, R3 and R4 independently of one another are hydrogen or substituted or unsubstituted C1-C4alkyl, (R5)0-2 and (R6)0-2 independently of one another are 0 to 2 identical or different substituents selected from the group consisting of C1-C4alkyl, C1-C4alkoxy, C2-C4alkanoylamino, halogen, carboxyl, sulfo, carbamoyl, N-C1-C4alkylcarbamoyl, N,N-di-C1-C4alkylcarbamoyl, C1-C4alkylsulfonyl, sulfamoyl, N-C1-C4alkylsulfamoyl and N,N-di-C1-C4alkylsulfamoyl, A is hydrogen or C1-C4alkyl which is unsubstituted or substituted by hydroxyl, sulfo, carboxyl or sulfato;
- phenyl or naphthyl which are unsubstituted or substituted by C1-C4alkyl, C1-C4alkoxy, C2-C4alkanoylamino, hydroxyl, carboxyl, carbamoyl, sulfo or halogen;
phenyl-C1-C4alkylene which is unsubstituted or substituted in the phenyl ring by C1-C4alkyl, C1-C4alkoxy, C2-C4alkanoylamino, hydroxyl, carboxyl, sulfo, carbamoyl, ureido or halogen;
or C5-C7cycloalkyl which is unsubstituted or substituted by C1-C4alkyl, B1 is a C2-C12alkylene radical, which can be interrupted by 1, 2 or 3 members selected from the group consisting of —
NH—
, —
N(CH3)—
or —
O— and
is unsubstituted or substituted by hydroxyl, sulfo, sulfato, cyano or carboxyl;
a C5-C9-cycloalkylene radical, C1-C6alkylenephenylene radical or phenylene radical which are unsubstituted or substituted by C1-C4alkyl, C1-C4alkoxy, C2-C4alkanoylamino, sulfo, halogen or carboxyl;
or the radical of the formula
is a radical of the formulaD1 is a mono- or disazo radical of the formula (4) or (5)
D*—
N═
N—
(M—
N═
N)u—
K—
(4)or
2 Assignments
0 Petitions
Accused Products
Abstract
Reactive dyes of the formula (1)
in which
R1, R2, R3 and R4 independently of one another are hydrogen or substituted or unsubstituted C1-C4alkyl,
(R5)0-2 and (R6)0-2 independently of one another are 0 to 2 identical or different substituents from the group consisting of C1-C4alkyl, C1-C4alkoxy, C2-C4alkanoylamino, halogen, carboxyl, sulfo, carbamoyl, N-C1-C4alkylcarbamoyl, N,N-di-C1-C4alkylcarbamoyl, C1-C4alkylsulfonyl, sulfamoyl, N-C1-C4alkylsulfamoyl and N,N-di-C1-C4alkylsulfamoyl,
A is hydrogen or C1-C4alkyl which is unsubstituted or substituted by hydroxyl, sulfo, carboxyl or sulfato, phenyl or naphthyl which are unsubstituted or substituted by C1-C4alkyl, C1-C4alkoxy, C2-C4alkanoylamino, hydroxyl, carboxyl, carbamoyl, sulfo or halogen, phenyl-C1-C4alkylene which is unsubstituted or substituted in the phenyl ring by C1-C4alkyl, C1-C4alkoxy, C2-C4alkanoylamino, hydroxyl, carboxyl, sulfo, carbamoyl, ureido or halogen, or C5-C7cycloalkyl which is unsubstituted or substituted by C1-C4alkyl,
B1 is an aliphatic or aromatic bridge member, and the remaining substituents are described in the specification.
15 Citations
12 Claims
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1. A reactive dye of the formula (1)
in which R1, R2, R3 and R4 independently of one another are hydrogen or substituted or unsubstituted C1-C4alkyl, (R5)0-2 and (R6)0-2 independently of one another are 0 to 2 identical or different substituents selected from the group consisting of C1-C4alkyl, C1-C4alkoxy, C2-C4alkanoylamino, halogen, carboxyl, sulfo, carbamoyl, N-C1-C4alkylcarbamoyl, N,N-di-C1-C4alkylcarbamoyl, C1-C4alkylsulfonyl, sulfamoyl, N-C1-C4alkylsulfamoyl and N,N-di-C1-C4alkylsulfamoyl, A is hydrogen or C1-C4alkyl which is unsubstituted or substituted by hydroxyl, sulfo, carboxyl or sulfato; - phenyl or naphthyl which are unsubstituted or substituted by C1-C4alkyl, C1-C4alkoxy, C2-C4alkanoylamino, hydroxyl, carboxyl, carbamoyl, sulfo or halogen;
phenyl-C1-C4alkylene which is unsubstituted or substituted in the phenyl ring by C1-C4alkyl, C1-C4alkoxy, C2-C4alkanoylamino, hydroxyl, carboxyl, sulfo, carbamoyl, ureido or halogen;
or C5-C7cycloalkyl which is unsubstituted or substituted by C1-C4alkyl,B1 is a C2-C12alkylene radical, which can be interrupted by 1, 2 or 3 members selected from the group consisting of —
NH—
, —
N(CH3)—
or —
O— and
is unsubstituted or substituted by hydroxyl, sulfo, sulfato, cyano or carboxyl;
a C5-C9-cycloalkylene radical, C1-C6alkylenephenylene radical or phenylene radical which are unsubstituted or substituted by C1-C4alkyl, C1-C4alkoxy, C2-C4alkanoylamino, sulfo, halogen or carboxyl;
or the radical of the formula
is a radical of the formulaD1 is a mono- or disazo radical of the formula (4) or (5)
D*—
N═
N—
(M—
N═
N)u—
K—
(4)or - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12)
- phenyl or naphthyl which are unsubstituted or substituted by C1-C4alkyl, C1-C4alkoxy, C2-C4alkanoylamino, hydroxyl, carboxyl, carbamoyl, sulfo or halogen;
Specification
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- Resources
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Current AssigneeHuntsman International LLC (Huntsman Corporation)
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Original AssigneeCIBA Specialty Chemicals
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InventorsVerdugo, Thomas, Reichert, Hans
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Primary Examiner(s)EINSMANN, MARGARET V
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Application NumberUS09/521,711Time in Patent Office1,223 DaysField of Search544/76, 854/9, 891/8, 534/635, 534/642US Class Current8/549CPC Class CodesC09B 62/021 Specific dyes not provided ...C09B 62/043 containing two or more tria...C09B 62/205 Specific dyes not provided ...C09B 62/4403 the heterocyclic system bei...Y10S 8/918 Cellulose textile
