Sensors for detecting physical conditions

• US 6,593,588 B1
• Filed: 11/15/2001
• Issued: 07/15/2003
• Est. Priority Date: 05/28/1999
• Status: Expired due to Fees

• Current Assignee: Canpolar East Inc.
• Original Assignee: Canpolar East Inc.
• Inventors: Reimer, Ernest
• Primary Examiner(s): LE, QUE TAN
• Application Number:
  US09/979,037
• Time in Patent Office: 607 Days
• Field of Search: 250/573, 250/574, 250/559.4, 250/559.41, 250/221, 250/222.2, 250/238, 356/441, 356/442, 356/336-338, 356/73, 204/557-565, 204/455-461, 73/644.1, 73/644.3
• US Class Current: 250/573
• CPC Class Codes: G01D 5/268 using optical fibres G01D5/28 - G01D5/38 take precedence
• CPC Class Codes: G01K 11/12 using changes in colour, translucency or reflectance
• CPC Class Codes: G01L 1/24 by measuring variations of optical properties of material when it is stressed, e.g. by photoelastic stress analysis using infrared, visible light, ultraviolet
• CPC Class Codes: G01M 11/02 Testing optical properties

Abstract

A sensor for detecting changes in a variety of conditions is provided, including temperature, chemical conditions including pH and ion levels, biological antigens, radiation levels, electrical field and pressure applied to the sensor. The sensor body is formed from a material which incorporates an evenly dispersed matrix of light-scattering elements. A light source emits light into the body to form an effective optical cavity in which the light is scattered by the matrix. One or more receivers detects the intensity of scattered or integrated light inside and/or outside of the optical cavity. The matrix and/or the sensor body are composed of materials which reduce or increase the density of light-scattering elements, depending on the conditions applied to the matrix. An increase in the density of the light-scattering elements results in a corresponding increase in the integrated intensity of light received by the receiver, when the receiver is positioned within the optical cavity. At a more distant location, the integrated light intensity at the receiver decreases as the density of scattering elements increases. A processing unit translates the intensity level received by the receiver, into a measure of intensity of the condition detected by the sensor.

Claims

1. A sensor for detecting physical or chemical conditions, of the type comprising:

a volume of light-translucent material having light-scattering centers generally evenly dispersed therein;

a light emitter in operative communication with said material for emitting light into the interior of said material and thereby forming an integrating optical cavity within the interior of said material, said cavity defined by a region within which light from said source is generally fully scattered within one characteristic scattering length from said emitter;

a first light detector in operative communication with said material for detecting the intensity of scattered light within said optical cavity;

signal processing means in operative communication with said light detector, for converting said light intensity level into a corresponding electronic signal;

characterized by;

either of said light-translucent material or said scattering centers dispersed therein being responsive to changes in physical, chemical or biological conditions within the medium surrounding said material whereby the effective concentration of said scattering centers within said material changes in response to changes in said condition.

2. A sensor as defined in claim 1, comprising a temperature sensor, wherein said material comprises a light translucent material characterized by polycrystalline phase transition properties within a selected temperature range, wherein said material undergoes a reversible change in the concentration of crystalline structures within said temperature range, said crystalline structures comprising said scattering centers.

3. A temperature sensor as defined in claim 2, wherein said material comprises opal glass.

4. A temperature sensor as defined in claim 2, wherein said material comprises a transparent polymer with an embedded scattering agent generally evenly dispersed throughout.

5. A sensor as defined in claim 1 for detection of pH level, wherein said material comprises a hydrated polymer gel matrix having light scattering particles evenly dispersed throughout, and functional groups within said gel which react to the pH level within a surrounding medium by causing said gel to swell or shrink thereby changing the effective concentration of said light scattering particles.

6. A sensor as defined in claim 5, wherein said gel comprises a graft copolymer of PMMA and PEG.

7. A sensor as defined in claim 1 for detection of bio-organic molecules within a medium surrounding said sensor, wherein said scattering material comprises a hydrated polymer gel matrix having light scattering particles evenly dispersed throughout, and functional groups within said gel comprising an immune reagent having specificity for binding to a selected bio-organic substance in an antibody/antigen binding reaction, wherein said light scattering particles comprise said immune reagent, the light scattering properties of which are enhanced upon binding to said bio-organic substance.

8. A sensor as defined in claim 1 for detection of electromagnetic radiation, wherein said translucent material is encased within a housing transparent to radiation within a selected range of wavelengths, but substantially opaque within the range of light emitted by said light emitter, said scattering particles comprising radiation-sensitive particles which change their optical scattering properties in proportion to their exposure to radiation.

9. A sensor as defined in claim 8, wherein said particles are coated with thermochromic ink.

10. A sensor as defined in claim 1, for detection of electromagnetic radiation, wherein said light-scattering material is comprised of a material which fissures, forms dislocations or other defects upon exposure to ionizing radiation, said fissures, dislocations or defects forming said light scattering centers.

13. A sensor as defined in claim 1, further comprising a second light detector spaced apart from said first detector and positioned outside of said optical cavity, said medium having evenly dispersed therein scattering elements comprising particles coated with a thermo chromic substance adapted to change its optical absorption characteristics in response to temperature changes, said sensor being adapted to detect both pressure sufficient to compress said medium, and temperature changes.

11. A sensor for detection of an electric field, wherein a light translucent material comprises a hydrated gel matrix, having evenly dispersed therein particles comprising functional groups which react to the presence of an electric field by causing said gel to shrink or swell.

12. A sensor as defined in claim 11, wherein said gel matrix comprises elastic poly(dimethylsiloxane) combined with an electroheological fluid and a suspension of cross-linked poly(ethylene oxide) particles in oil.

14. A method for detecting physical, chemical or electromagnetic conditions, of the type comprising a sensor to a selected condition and transmitting an electronic signal in response thereto, characterized by the steps of:

providing a volume of light translucent material having dispersed therein light scattering centers;

said material or said scattering centers being responsive to changes in physical, chemical or biological conditions whereby the effective concentration of said scattering centers increases in response to said changes;

emitting a beam of light into the interior of said material, thereby forming within said material a virtual integrating optical cavity defined by a region within which light from said beam is fully scattered by said scattering centers;

detecting the intensity of said scattered light with a photodetector;

converting the detected level of scattered light within said optical cavity into information indicative of a selected physical, chemical or biological condition.

15. A method as defined in claim 14, comprising the step of measuring temperature, wherein said material comprises a light translucent material characterized by polycrystalline phase transition properties within a selected temperature range, wherein said material undergoes a reversible change in the concentration of crystalline structures within said temperature range, said crystalline structures comprising said scattering centers.

16. A method as defined in claim 15, wherein said material comprises opal glass.

17. A method as defined in claim 14, wherein said material comprises a transparent polymer with an embedded scattering agent generally evenly dispersed throughout.

18. A method as defined in claim 14 for detection of pH level, wherein said scattering material comprises a hydrated polymer gel matrix having light scattering particles evenly dispersed throughout, and functional groups within said gel which react to the pH level within a surrounding medium by causing said gel to swell or shrink thereby changing the concentration of said light scattering particles.

19. A method as defined in claim 18, wherein said gel comprises a graft copolymer of PMMA and PEG.

20. A method as defined in claim 14 for detection of bio-organic molecules within a medium surrounding said sensor, wherein said scattering material comprises a hydrated polymer gel matrix having light scattering particles evenly dispersed throughout, and functional groups within said gel comprising an immune reagent having specificity for binding to a selected bio-organic substance in an antibody/antigen binding reaction, wherein said light scattering particles comprise said immune reagent, the light scattering properties of which are enhanced upon binding to said bio-organic substance.

21. A method as defined in claim 14 for detection of electromagnetic radiation, wherein said translucent material is encased within a housing transparent to radiation within a selected range of wavelengths, but substantially opaque within the range of light emitted by said light emitter, said scattering particles comprising radiation-sensitive particles which change their optical scattering properties in proportion to their exposure to radiation.

22. A method as defined in claim 21, wherein said particles are coated with thermochromic ink.

23. A method as defined in claim 14, for detection of electromagnetic radiation, wherein said light-scattering material is comprised of a material which fissures, forms dislocations or other defects upon exposure to electromagnetic radiation within a selected wavelength, said fissures, dislocations or defects forming said light scattering centers.

26. A method as defined in claim 14, further comprising the step of positioning a second light detector spaced apart from said first detector and positioned outside of said optical cavity, said medium having evenly dispersed therein scattering elements comprising particles coated with a thermochromic substance adapted to change its optical absorption characteristics in response to temperature changes, said sensor being adapted to detect both pressure sufficient to compress said medium, and temperature changes.

24. A method for detection of an electric field, wherein a light translucent material comprises a hydrated gel matrix, having evenly dispersed therein particles comprising functional groups which react to the presence of an electric field by causing said gel to shrink or swell.

25. A method as defined in claim 24, wherein said gel matrix comprises elastic poly(dimethylsiloxane) combined with an electroheological fluid and a suspension of cross-linked poly(ethylene oxide) particles in oil.