Electrode design for electrochromic devices

• US 6,597,489 B1
• Filed: 06/30/1999
• Issued: 07/22/2003
• Est. Priority Date: 06/30/1999
• Status: Expired due to Term

• Current Assignee: Gentex Corporation
• Original Assignee: Gentex Corporation
• Inventors: Guarr, Thomas F., Theiste, David A.
• Primary Examiner(s): Lester, Evelyn A
• Application Number:
  US09/343,345
• Time in Patent Office: 1,483 Days
• Field of Search: 359/266, 359/275, 359/265, 359/267-274
• US Class Current: 359/266
• CPC Class Codes: G02F 1/155 Electrodes
• CPC Class Codes: G02F 1/157 Structural association of cells with optical devices, e.g. reflectors or illuminating devices
• CPC Class Codes: G02F 2001/15145 the electrochromic layer comprises a mixture of anodic and cathodic compounds
• CPC Class Codes: G02F 2001/1552 Inner electrode, e.g. the electrochromic layer being sandwiched between the inner electrode and the support substrate
• CPC Class Codes: G02F 2001/1557 Side by side arrangements of working and counter electrodes

Abstract

An electrochromic device, such as a window or mirror, is disclosed that includes a transparent first substrate having an inner surface, a second substrate having an inner surface spaced apart from the inner surface of the first substrate so as to define a chamber therebetween, first and second electrodes carried on the inner surface of the second substrate and disposed thereon so as to be electrically isolated from one another, and an electrochromic medium disposed in the chamber between the inner surfaces of the first and second substrates. The electrochromic medium may be in solution-phase. Also, the electrodes may be disposed on the inner surface of the second substrate in substantially co-planar relation. Alternatively, the electrodes may be arranged in a stacked relation, with a layer of dielectric material provided therebetween. In this alternative configuration, the dielectric layer and the second electrode would include a plurality of apertures through which the electrochromic medium may contact the first electrode, which underlies the dielectric and second electrode layers. Also disclosed is an electrochromic device including a positive electrode, a negative electrode having a surface area different from the surface area of the positive electrode, and an electrochromic medium including cathodic and anodic species, wherein the ratio of cathodic to anodic species within the electrochromic medium is a function of the ratio of the surface areas of the positive and negative electrodes.

Claims

1. An electrochromic device comprising:

a transparent first substrate having an outer surface and an inner surface;

a second substrate having an inner surface spaced apart from said inner surface of said first substrate, which, with a seal, defines a chamber therebetween;

a first electrode carried on said inner surface of said second substrate;

a second electrode also carried on said inner surface of said second substrate, said second electrode being substantially co-planar with, and electrically isolated from, said first electrode; and

an electrochromic medium disposed in said chamber between said inner surface of said first substrate and said inner surface of said second substrate, which carries said first and second electrodes.

2. The electrochromic device as defined in claim 1, wherein said electrochromic medium is a solution-phase electrochromic medium.

3. The electrochromic device as defined in claim 1, wherein said first and second electrodes both include a plurality of parallel, spaced-apart elongated strips of electrically conductive material, wherein the conductive strips of the first and second electrodes are interdigitatedly disposed on said inner surface of said second substrate.

4. The electrochromic device as defined in claim 3, wherein said conductive strips of said first electrode have different widths than said conductive strips of said second electrode.

5. The electrochromic device as defined in claim 3, wherein said electrochromic medium includes cathodic and anodic species, wherein the ratio of cathodic to anodic species within said electrochromic medium is a function of the ratio of the widths of said conductive strips of said first electrode to the widths of said conductive strips of said second electrode.

6. The electrochromic device as defined in claim 3, wherein the width of said conductive strips of said first electrode is at least five times greater than the width of said conductive strips of said second electrode.

7. The electrochromic device as defined in claim 1, wherein said electrochromic medium is in electrical contact with both said first and second electrodes.

8. The electrochromic device as defined in claim 7, wherein said electrochromic medium includes an anodic species in electrical contact with said first electrode and a cathodic species in electrical contact with said second electrode.

9. The electrochromic device as defined in claim 1, wherein said first and second electrodes are spaced apart from one another by a gap of substantially constant width.

10. The electrochromic device as defined in claim 1, wherein said electrochromic device is a mirror.

11. The electrochromic device as defined in claim 1, wherein said first and second electrodes are transparent.

12. The electrochromic device as defined in claim 1, wherein said second substrate is transparent.

13. The electrochromic device as defined in claim 1, wherein said electrochromic device is a window.

14. The electrochromic device as defined in claim 1 and further including a diffuser provided on an outer surface of one of said first and second substrates.

15. The electrochromic device as defined in claim 1, wherein said electrochromic medium includes anodic and cathodic species exhibiting substantially similar color transitions.

16. The electrochromic device as defined in claim 1, wherein said device is configured such that said electrochromic medium becomes colored when a current flows through said first and second electrodes.

17. The electrochromic device as defined in claim 1, wherein said electrochromic medium comprises a cathodic and anodic species.

19. The electrochromic device as defined in claim 16, wherein said second electrode is a continuous layer of electrically conductive material having said plurality of apertures provided through the thickness of the layer, said apertures in said second electrode layer being in communication with said apertures in said dielectric layer.

20. The electrochromic device as defined in claim 19, wherein said apertures in said second electrode are formed in substantial alignment with said apertures in said dielectric layer.

21. The electrochromic device as defined in claim 16, wherein said dielectric layer is a porous structure and said apertures are pores in the porous structure.

22. The electrochromic device as defined in claim 16, wherein said electrochromic device is a window.

23. The electrochromic device as defined in claim 16, wherein said electrochromic device is a mirror.

24. The electrochromic device as defined in claim 16 and further including a diffuser provided on an outer surface of one of said first and second substrates.

25. The electrochromic device as defined in claim 16, wherein said electrochromic medium includes anodic and cathodic species exhibiting substantially similar color transitions.

26. The electrochromic device as defined in claim 16, wherein said electrochromic medium is in electrical contact with both said first and second electrodes.

18. An electrochromic device comprising:

a transparent first substrate having an outer surface and an inner surface;

a second substrate having an inner surface spaced apart from said inner surface of said first substrate, which, with a seal, defines a chamber therebetween;

a first electrode including a layer of an electrically conductive material deposited on said inner surface of said second substrate;

a layer of dielectric material deposited over said first electrode layer;

a second electrode disposed on said dielectric layer; and

an electrochromic medium disposed in said chamber between said inner surface of said first substrate and said inner surface of said second substrate, which carries said first and second electrodes,

wherein said second electrode layer and dielectric layer include a plurality of apertures through which said electrochromic medium may contact said first electrode.

27. The electrochromic device as defined in claim 18, wherein said second electrode includes a layer of electrically conductive mesh applied to said dielectric layer.

28. The electrochromic device as defined in claim 18, wherein said electrochromic medium is a solution-phase electrochromic medium.

29. An electrochromic device comprising:

a transparent first substrate having an outer surface and an inner surface;

a second substrate having an inner surface spaced apart from said inner surface of said first substrate, which, with a seal, defines a chamber therebetween;

a first electrode carried on said inner surface of said second substrate, said first electrode includes a layer of an electrically conductive material deposited on said inner surface within said chamber;

a second electrode also carried on said inner surface of said second substrate, said second electrode being electrically isolated from said first electrode;

a single layer electrochromic medium disposed in said chamber between said inner surface of said first substrate and said inner surface of said second substrate, which carries said first and second electrodes; and

a layer of dielectric material deposited over said first electrode layer, wherein said second electrode includes a layer of electrically conductive material deposited on said dielectric layer, said second electrode layer and said dielectric layer include a plurality of apertures through which said electrochromic medium may contact said first electrode.

30. An electrochromic device comprising:

a transparent first substrate having an outer surface and an inner surface;

a second substrate having an inner surface spaced apart from said inner surface of said first substrate, which, with a seal, defines a chamber therebetween;

a first electrode carried on said inner surface of said second substrate, said first electrode includes a layer of an electrically conductive material deposited on said inner surface within said chamber;

a second electrode also carried on said inner surface of said second substrate, said second electrode being electrically isolated from said first electrode;

a single layer electrochromic medium disposed in said chamber between said inner surface of said first substrate and said inner surface of said second substrate, which carries said first and second electrodes; and

a layer of dielectric material deposited over said first electrode layer, wherein said second electrode includes a layer of electrically conductive mesh applied to said dielectric layer and said dielectric layer includes a plurality of apertures through which said electrochromic medium may contact said first electrode.

31. An electrochromic device comprising:

a transparent first substrate having an outer surface and an inner surface;

a second substrate having an inner surface spaced apart from said inner surface of said first substrate, which, with a seal, defines a chamber therebetween;

a first electrode carried on said inner surface of said second substrate;

a second electrode also carried on said inner surface of said second substrate, said second electrode being electrically isolated from said first electrode; and

a single layer electrochromic medium disposed in said chamber at least between said inner surface of said first substrate and said second electrode.

32. The electrochromic device as defined in claim 31, wherein said electrochromic device is a window.

33. The electrochromic device as defined in claim 31, wherein said first and second electrodes are both in direct contact with said inner surface of said second substrate in substantially co-planar relation.

34. The electrochromic device as defined in claim 31, wherein said first electrode includes a layer of an electrically conductive material deposited on said inner surface within said chamber.

35. The electrochromic device as defined in claim 31, wherein said device is configured such that said electrochromic medium becomes colored when a current flows through said first and second electrodes.

36. The electrochromic device as defined in claim 31, wherein said electrochromic medium comprises a cathodic and anodic species.

37. An electrochromic device comprising:

a cathode;

an anode having a surface area different from the surface area of said cathode; and

an electrochromic medium including cathodic and anodic species, wherein the ratio of cathodic to anodic species within said electrochromic medium is a function of the ratio of the surface areas of said cathode and said anode.

38. The electrochromic device as defined in claim 37, wherein the ratio of cathodic to anodic species within the electrochromic medium is substantially equal to the ratio of the surface area of said anode to the surface area of said cathode.

39. The electrochromic device as defined in claim 38, wherein the ratios of cathodic to anodic species and of the surface area of said anode to the surface area of said cathode are between about 20:

1 and 1;

20.

40. The electrochromic device as defined in claim 39, wherein the ratios of cathodic to anodic species and of the surface area of said anode to the surface area of said cathode are between about 10:

1 and 1;

10.

41. The electrochromic device as defined in claim 37 and further including:

a transparent first substrate having an outer surface and an inner surface; and

a second substrate having an inner surface spaced apart from said inner surface of said first substrate so as to define a chamber therebetween,

wherein said cathode and said anode are both carried on said inner surface of said second substrate and are disposed thereon so as to be electrically isolated from one another.

42. The electrochromic device as defined in claim 41, wherein said cathode and said anode are both in direct contact with said inner surface of said second substrate in co-planar relation.

43. The electrochromic device as defined in claim 37, wherein said electrochromic medium is a solution-phase electrochromic medium.

44. The electrochromic device as defined in claim 37, wherein said electrochromic device is a window.

45. A component for an electrochromic device comprising:

first and second electrodes carried on a single surface of a substrate, said first and second electrodes being electrically isolated from one another, each electrode having a first surface facing the substrate, and a second surface opposite said first surface; and

an electrochromic medium disposed over said second surfaces of said first and second electrodes and being in electrical contact therewith.

46. An electrochromic device comprising the component as defined in claim 45.

47. An insulated glass unit comprising:

a first glass pane;

a second glass pane sealably bonded to said first glass pane to define a chamber therebetween;

a low heat conducting gas provided in said chamber; and

the electrochromic device as defined in claim 46 carried on a surface of one of said first and second glass panes within said chamber.

48. The insulated glass unit as defined in claim 47, wherein said electrochromic device further includes a substrate on which said first and second electrodes are carried, said substrate being attached to a surface of one of said first and second glass panes within said chamber.

49. The insulated glass unit as defined in claim 47 and further including an ultraviolet blocking layer carried on a surface of one of said first class pane and said electrochromic device.

50. An electrochromic device comprising:

a transparent first substrate having an outer surface and an inner surface;

a second substrate having an inner surface spaced apart from said inner surface of said first substrate, which, with a seal, defines a chamber therebetween;

a first electrode carried on said inner surface of said second substrate;

a second electrode also carried on said inner surface of said second substrate, said second electrode being electrically isolated from, said first electrode; and

an electrochromic medium disposed in said chamber between said inner surface of said first substrate and said inner surface of said second substrate, which carries said first and second electrodes, said electrochromic medium including at least one anodic species and at least one cathodic species, wherein said anodic and cathodic species exhibit substantially similar color transitions.