Optical fiber and fibre-optic cable comprising at least one intermetallic element that absorbs hydrogen

• US 6,597,850 B2
• Filed: 06/17/2002
• Issued: 07/22/2003
• Est. Priority Date: 12/22/1999
• Status: Expired due to Term

• Current Assignee: Alcatel SA (Nokia Corporation)
• Original Assignee: Alcatel SA (Nokia Corporation)
• Inventors: Andrieu, Xavier, Knosp, Bernard, Decaumont, Anne
• Primary Examiner(s): Bruce, David V.
• Assistant Examiner(s): Song, Hoon K.
• Application Number:
  US10/168,105
• Publication Number:
  US 20030002828A1
• Time in Patent Office: 400 Days
• Field of Search: 385/123, 385/124, 385/125, 385/126, 385/127, 385/128, 385/141, 385/142, 385/144
• US Class Current: 385/128
• CPC Class Codes: G02B 6/44382 the means comprising hydrogen absorbing materials G02B6/4439, G02B6/4479 take precedence

Abstract

In a covering outside its light-guiding portion, an optical fiber includes at least one crystalline intermetallic compound made up of at least two metals, the compound having a plateau pressure during hydride formation that is less than equal to 5×10⁻² atm (where 1 atm=1.013×10⁵ Pa) as measured at 30° C. by a PCT method, the compound being of the form AB_xM_y where A is constituted by at least one element from columns IIa, IIIb, or IVb of the periodic classification of the elements (CAS version), B is constituted by at least one element from columns Vb, VIII, or IIIa of said classification, and M contains at least one element from columns VIb, VIIb, Ib, or IIb of said classification, where:

0≦x≦10,

0≦y≦3 if A contains elements from column IIa only, and

0.2≦y≦3 if A contains at least one element from columns IIIb or IVb.

The optical fiber cable is characterized in that it includes such a crystalline intermetallic compound.

Claims

1. An optical fiber comprising a light-guiding portion and a peripheral portion around its light-guiding portion, the peripheral portion being constituted by at least one protective covering, the optical fiber including, in a covering outside its light-guiding portion, at least one crystalline intermetallic compound made up of at least two metals, the compound having a plateau pressure during hydride formation that is less than equal to 5×

10<sup>−

2</sup> atm (where 1 atm=1.013×

10⁵ Pa) measured by a PCT (pressure composition temperature) method and of the form AB_xM_y where;

A is constituted by at least one element from columns IIa, IIIb, or IVb of the periodic classification of the elements (CAS version);

B is constituted by at least one element from columns Vb, VIII, or IIIa of the periodic classification of the elements (CAS version);

M contains at least one element from columns VIb, VIIb, Ib, or IIb of the periodic classification of the elements (CAS version);

with;

0≦

x≦

10;

0≦

y≦

3 if A contains elements from column IIa only; and

0.2≦

y≦

3 if A contains at least one element from columns IIIb or IVb.

2. A fiber according to claim 1, such that said crystalline intermetallic compound is an alloy of the AB₅ type, optionally substituted at least in part by M.

3. A fiber according to claim 1, such that said crystalline intermetallic compound is an alloy of the AB₂ type, optionally substituted at least in part by M.

4. A fiber according to claim 1, such that said crystalline intermetallic compound is an alloy of the A₂B type, optionally substituted at least in part by M.

5. A fiber according to claim 1, such that said crystalline intermetallic compound is an alloy of the AB type, optionally substituted at least in part by M.

6. A fiber according to claim 1, such that said crystalline intermetallic compound present in a covering outside the light-guiding portion of the fiber is incorporated in the optical fiber in at least one covering of said fiber.

7. A fiber according to claim 1, such that said crystalline intermetallic compound is coated at least in part by a metal deposit having effect of protecting said crystalline intermetallic compound from being polluted by a gas different from hydrogen, such as oxygen O₂, carbon monoxide CO, or carbon dioxide CO₂, for example, said deposit nevertheless enabling hydrogen to diffuse to said intermetallic compound.

8. A fiber according to claim 7, such that said crystalline intermetallic compound is coated by a deposit of nickel (Ni) or of copper (Cu).

9. An optical fiber cable having at least one optical fiber, the cable including at least one crystalline intermetallic compound formed by at least two metals, having a plateau pressure during hydride formation that is less than or equal to 5×

10<sup>−

2</sup> atm measured at 30°

C. by a PCT method, the compound being of the form AB_xM_y, where;

A is constituted by at least one element from columns IIa, IIIb, or IVb of the periodic classification of the elements (CAS version);

B is constituted by at least one element from columns Vb, VIII, or IIIa of the periodic classification of the elements (CAS version);

M contains at least one element from columns VIb, VIIb, Ib, or IIb of the periodic classification of the elements (CAS version);

with;

0≦

x≦

10;

0≦

y≦

3 if A contains elements from column IIa only; and

0.2≦

y≦

3 if A contains at least one element from columns IIIb or IVb.

10. A cable according to claim 9, such that crystalline intermetallic compound is an alloy of the AB₅ type, optionally at least partially substituted by M.

11. A cable according to claim 9, such that crystalline intermetallic compound is an alloy of the AB₂ type, optionally at least partially substituted by M.

12. A cable according to claim 9, such that crystalline intermetallic compound is an alloy of the A₂B type, optionally at least partially substituted by M.

13. A cable according to claim 9, such that crystalline intermetallic compound is an alloy of the AB type, optionally at least partially substituted by M.

14. A cable according to claim 9, such that said crystalline intermetallic compound is coated at least in part by a metal deposit having effect of protecting said intermetallic compound from being polluted by a gas different from hydrogen, such as oxygen O₂, carbon monoxide CO, or carbon dioxide CO₂, for example, said deposit nevertheless enabling hydrogen to diffuse to said intermetallic compound.

15. A cable according to claim 14, such that said crystalline intermetallic compound is coated by a deposit of nickel (Ni) or of copper (Cu).

16. A cable according to claim 9, such that said crystalline intermetallic compound is incorporated in the optical fiber cable by being incorporated in a matrix.

17. A cable according to claim 9, such that said crystalline intermetallic compound is incorporated in the optical fiber cable in the polymer compound of the housing tube when said tube is made of polymer material.

18. A cable according to claim 9, such that said crystalline intermetallic compound is incorporated in the optical fiber cable in a filler gel of the cable.