Recovery of adiponitrile from a mixture of adiponitrile, aminocapronitrile and hexamethylenediamine

• US 6,599,398 B1
• Filed: 07/17/2002
• Issued: 07/29/2003
• Est. Priority Date: 07/17/2002
• Status: Expired due to Term

• Current Assignee: Invista North America Sarl (Invista)
• Original Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Inventors: Ostermaier, John, Scott, Leon, Hastings, James
• Primary Examiner(s): Manoharan, Virginia
• Application Number:
  US10/197,882
• Time in Patent Office: 377 Days
• Field of Search: 203/73, 203/74, 203/75, 203/77, 203/78.2, 203/80, 203/100, 203/99, 203/DIG.19, 203/DIG.9, 564/492, 564/498, 564/497, 558/459, 558/456
• US Class Current: 203/74
• CPC Class Codes: B01D 3/143 by two or more of a fractionation, separation or rectification step
• CPC Class Codes: B01D 3/146 Multiple effect distillation
• CPC Class Codes: C07C 253/34 Separation; Purification
• CPC Class Codes: C07C 255/09 containing at least two cyano groups bound to the carbon skeleton
• CPC Class Codes: Y10S 203/09 Plural feed
• CPC Class Codes: Y10S 203/20 Power plant

Abstract

Process for the recovery of a purified adiponitrile (ADN) from a mixture of adiponitrile, aminocapronitrile and hexamethylenediamine, utilizing two sequential distillations: (1) a first distillation in which the mixture is distilled in a distillation column at a head pressure that causes at least 7% of the ADN to go into the distillate, along with bishexamethylenetriamine (BHMT) and 2-cyanocyclopentylideneimine (CPI), and (2) a second distillation in which the distillate from the first distillation is distilled in a second distillation column at a head pressure sufficient to cause minimum-temperature azeotropy between ADN and BHMT, thereby allowing the majority of the BHMT and CPI to be removed from the second distillation as distillate, and ADN, substantially free of both BHMT and CPI, to be removed as bottoms.

Claims

1. A process for recovering a purified adiponitrile (ADN) from a feed mixture comprising bishexamethylenetriamine (BHMT), ADN, 2-cyanocyclopentylideneimine (CPI), and high boiling tars, said process comprising the following sequential steps:

(1) distilling the mixture in an ADN Recovery Distillation Column having a head pressure in the range of 2 to 150 mm Hg to produce a substantially tar-free distillate comprising at least 70% of the ADN in the feed mixture, BHMT and CPI, and a bottoms product comprising substantially all of the tars and the remainder of the ADN in the feed mixture; and

then

(2) distilling the distillate from step (1) in an ADN Refining Distillation Column having a head pressure in the range of 20 to 150 mm Hg, which causes minimum-temperature azeotropy between ADN and BHMT, thereby allowing the removal from the ADN Refining Distillation Column of (i) a distillate containing the majority of the BHMT and CPI present in the distillate from step (1), and (ii) a bottoms product that comprises ADN that is substantially free of both BHMT and CPI.

2. The process of claim 1, wherein the feed mixture to the ADN Recovery Distillation Column is the bottoms of a Tails Concentrator Distillation Column whose feed material is the bottoms of a Step 1 Distillation Column whose feed material is an ADN hydrogenation product comprising ADN, HMD, ACN, BHMT, tetrahydroazepine (THA), polarographically reducible impurities (PRI), and tars.

3. The process of claim 2, wherein a side draw from the Step 1 Distillation Column is combined with the distillate of the Tails Concentrator Distillation Column and fed to a Step 2 Distillation Column whose bottoms comprises ACN.

4. The process of claims 1, 2 or 3, wherein the head pressure of the ADN Recovery Column is 13.5 mm Hg, and the head pressure of the ADN Refining Distillation Column is 80 mm Hg.