Low temperature cure coating composition and method therefore

• US 6,602,552 B1
• Filed: 11/14/2000
• Issued: 08/05/2003
• Est. Priority Date: 11/14/2000
• Status: Expired due to Fees

• Current Assignee: PPG Industries Ohio Incorporated (Nouryon BV)
• Original Assignee: BASF Corporation (BASF SE)
• Inventors: Lewarchik, Ronald J., Slawikowski, Mark P., Daraskevich, Edward J., McCann, Sebastian E.
• Primary Examiner(s): CAMERON, ERMA C
• Application Number:
  US09/712,496
• Time in Patent Office: 994 Days
• Field of Search: 427/388.1
• US Class Current: 427/388.1
• CPC Class Codes: C08G 18/222 metal compounds not provided for in groups C08G18/225 - C08G18/26
• CPC Class Codes: C08L 2666/08 Homopolymers or copolymers according to C08L7/00 - C08L21/00; Derivatives thereof
• CPC Class Codes: C09D 167/00 Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain based on polyester-amides C09D177/12; based on polyester-imides C09D179/08; Coating compositions based on derivatives of such polymers
• CPC Class Codes: C09D 175/04 Polyurethanes

Abstract

A method for a low temperature cure for a coating composition comprising: applying to a substrate a low temperature curing coating composition consisting essentially of a film forming component consisting essentially of a non-carbamate functional polymeric component selected from the group consisting of polyester, silicone modified polyester, polyurethane, acrylic, alkyd, epoxy, polyamide, phenolic and polysilane polymers and mixtures thereof; a crosslinking component to crosslink the non-carbamate functional polymeric component; a catalyst selected from the group consisting of Lewis acids, perflouracetic acid, methane sulfonic acid catalyst and mixtures thereof; and additives selected from the group consisting of solvents, flow control agents, pigments, flexibilizing resins, surfactants, waxes, wetting agents, plasticizers, anti-oxidants, UV light absorbers, and a mixture thereof, and subjecting the coated substrate to a cure temperature of between 280° F. and 450° F., for a time sufficient to cure the coating.

Claims

1. A method for a lowering the cure temperature of a coil coating composition comprising

A) applying to a metal coil substrate a low temperature curing coating composition consisting essentially of:

i) a film forming component consisting essentially of a non-carbamate functional polymeric component selected from the group consisting of polyester, silicone modified polyester, polyurethane, acrylic, epoxy, polyamide, phenolic and polysilane polymers and mixtures thereof;

ii) a crosslinking component to crosslink the component (i), selected from the group consisting of melamine, unblocked polyisocyanate and blocked polylsocyanate crosslinking components;

iii) a catalyst selected from the group consisting of (a) Lewis acids selected from the group consisting of aluminum nitrate, iron nitrate, zinc nitrate, zirconium perchlorate, barium nitrate, aluminum sulfate, and aluminum perchchorate and mixtures thereof, and (b) periluoroacetic acid, methane sulfonic acid catalysts and mixtures thereof, and mixtures of (a) and (b), and

iv) additives selected from the group consisting of solvents, flow control agents, pigments, flexibilizing resins, surfactants, waxes, wetting agents, plasticizers, anti-oxidants, UV light absorbers, and mixtures thereof,

B) subjecting the coated substrate to cure temperature between 300°

F. (148.9°

C.) and 450°

F.(232.2°

C.), for a time between 5 and 60 seconds, to cure the coating, whereby a cure temperature is reduced to a range of a high temperature of 525°

F. and a low temperature of 425°

F. to a range of a high temperature of 450°

F. and a low temperature of 300°

F., at equivalent times to achieve equivalent curing.

2. The method of claim 1, wherein the film forming non-carbamate functional polymeric component is selected from the group consisting of polyester, polyurethane and acrylic resins and mixtures thereof.

3. The method of claim 1, wherein the catalyst is present in an amount between 0.01% and 5.0% by weight based on total coating composition weight.

4. The method of claim 1, wherein the catalyst is utilized in an amount between 0.01% to 1.0% by weight, based on total coating composition weight.

5. The method of claim 1, wherein the coil coating composition is cured for a period of 7 to 35 seconds at a temperature of between 300°

F. and 450°

F.

6. The method of claim 1, wherein the coating passes a T-bend test.

7. A method for coil coating comprising:

A) Applying to a metal coil substrate a low temperature curing coating composition consisting essentially of;

i) a film forming component consisting essentially of a non-carbamate functional polymeric component selected from the group consisting of polyester, polyurethane, acrylic epoxy, polyamide, and polysliane polymers and mixtures thereof;

ii) a crosslinking component to crosslink the component (i), selected from the group consisting of melamine, unblocked polyisocyanate and blocked polyisocyanate crosslinking components;

iii) a catalyst selected from the group consisting of (a) Lewis acids selected from the group consisting of aluminum nitrate, iron nitrate, zinc nitrate, zirconium perchlorate, barium nitrate, aluminum sulfate, and aluminum perchchorate and mixtures thereof, and (b) perfluoroacetic acid, methane sulfonic acid catalysts, and mixtures thereof, and mixtures of (a) and (b), and

iv) additives selected from the group consisting of solvents, flow control agents, pigments, flexibilizing resins, surfactants, waxes, wetting agents, plasticizers, anti-oxidants, UV light absorbers, and mixtures thereof,

B) subjecting the coated substrate to a temperature between 300°

F.(148.9°

C.) 450°

F.(232.2°

C.), for a time between 7 seconds and 35 seconds to cure the coating on the substrate, whereby cure temperature is reduced to a range of a high temperature of 450°

F. (232.2°

C.) and a low temperature of 300°

F.(148.9°

F.) from a high temperature of 525°

F. (273.99°

C.) and a low temperature of 425°

F. (218.33°

C.) for the same coating without component (ii).

8. The method of claim 7, wherein the coating composition consists essentially of as component (i) compounds selected from the group consisting of polyester, acrylic and polyurethane resins and mixtures thereof.

9. The method of claim 7, wherein the catalyst is present in an amount between 0.01% and 2.0% by weight based on total coating composition weight.

10. The method of claim 7, wherein the coating passes a T-bend test.