Fuel cell separator plate having controlled fiber orientation and method of manufacture

• US 6,607,857 B2
• Filed: 05/31/2001
• Issued: 08/19/2003
• Est. Priority Date: 05/31/2001
• Status: Expired due to Term

• Current Assignee: Board of Trustees of The University of Illinois, GM Global Technology Operations LLC (General Motors Company)
• Original Assignee: General Motors Corporation (General Motors Company)
• Inventors: Yoo, Yeong-Eun, Tucker, Charles L., Blunk, Richard H., Lisi, Daniel J.
• Primary Examiner(s): Gulakowski, Randy
• Assistant Examiner(s): Scaltrito, Donald V.
• Application Number:
  US09/871,189
• Publication Number:
  US 20020182473A1
• Time in Patent Office: 810 Days
• Field of Search: 429/34, 429/35, 429/36, 429/38, 429/39, 428/357, 428/359, 428/361, 428/367
• US Class Current: 429/432
• CPC Class Codes: B29C 2793/0054 partially cutting through the material
• CPC Class Codes: B29C 2793/009 after shaping
• CPC Class Codes: B29C 43/003 characterised by the choice of material
• CPC Class Codes: B29C 43/021 characterised by the shape of the surface
• CPC Class Codes: B29C 45/0013 using fillers dispersed in the moulding material, e.g. metal particles
• CPC Class Codes: B29C 45/561 Injection-compression moulding
• CPC Class Codes: B29C 70/14 oriented
• CPC Class Codes: B29C 70/62 the filler being oriented during moulding for short fibres B29C70/14
• CPC Class Codes: B29K 2105/06 containing reinforcements, fillers or inserts
• CPC Class Codes: B29K 2995/0005 Conductive
• CPC Class Codes: B29L 2031/3468 Batteries, accumulators or fuel cells battery cases B29L2031/7146
• CPC Class Codes: H01M 8/0221 Organic resins; Organic polymers
• CPC Class Codes: H01M 8/0226 in the form of mixtures
• CPC Class Codes: H01M 8/0258 characterised by the configuration of channels, e.g. by the flow field of the reactant or coolant
• CPC Class Codes: H01M 8/0267 having heating or cooling means, e.g. heaters or coolant flow channels
• CPC Class Codes: Y02E 60/50 Fuel cells
• CPC Class Codes: Y02P 70/50 Manufacturing or production processes characterised by the final manufactured product
• CPC Class Codes: Y10T 428/29 Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
• CPC Class Codes: Y10T 428/2904 Staple length fiber
• CPC Class Codes: Y10T 428/2907 with coating or impregnation

Abstract

A composite separator plate for a fuel cell having a low-carbon loading and a high-polymer loading is disclosed. The separator plate composition includes a percentage of conductive fibrous filler having a relatively high aspect-ratio oriented through the thickness of the plate to achieve desired electrical and thermal conductivity requirements. A method of manufacturing the fuel separator plate having such fibers disposed in a through-plane orientation is also disclosed. The method includes forming a separator plate having a land height for orienting the fibers in a desired through-plane direction, then removing a portion of the land height to obtained the desired geometric configuration for the separator plate.

Claims

1. A composite separator plate for use in a fuel cell stack, of the type having a first surface with a plurality of flow channels formed therein and a second surface opposite said first surface the composite separator plate comprising a polymeric material of 50% to 98% by volume and a fibrous conductive material of 2% to 50% by volume disposed in a through-plane orientation such that the effective resistance of said composite separator plate is less than or equal to 50 milliohms·

cm².

2. The composite separator plate of claim 1 herein said through-plane orientation provides a voltage drop through said separator plate between said first surface and said second surface which is less than or equal to 50 mV at a current density of approximately 6.5 ampere per square inch and a fuel-cell stacking pressure of less than or equal to approximately 14 kilogram force per centimeters squared.

3. The composite separator plate of claim 1 wherein said composite separator plate comprises a polymeric material of 60% to 80% by volume and a fibrous conductive material of 20% to 40% by volume disposed in said through-plane orientation.

4. The composite separator plate of claim 1 wherein said polymeric material is a conductive polymeric material.

5. The composite separator plate of claim 3 further comprising a conductive non-fibrous material of less than 10% by volume.

6. The composite separator plate of claim 5 wherein said conductive non-fibrous material is selected from the group consisting of carbon black, graphite powder and metal powder.

7. The composite separator plate of claim 1 wherein said polymeric material is selected from the group consisting of thermoset and thermoplastic polymers.

8. The composite separator plate of claim 7 wherein said polymeric material is selected from the group consisting of silicone, poly-isobutylene, epoxy vinyl ester and phenolic.

9. The composite separator plate of claim 7 wherein said polymeric material is selected from the group consisting of polypropylene, ETFE, nylon and rubber-modified polypropylene.

10. The composite separator plate of claim 1 wherein said fibrous conductive filler is a conductive fiber material having an aspect ratio equal to or greater than 10:

1.

11. The composite separator plate of claim 10 wherein said conductive fiber material is a PAN MF 30 carbon fiber of approximately 40% by volume and having an aspect ratio of greater than 15:

1.

12. The composite separator plate of claim 10 wherein said conductive fiber material is selected from the group consisting of carbon fibers, graphite fibers, nickel-coated graphite fibers, and stainless steel fibers.

13. The composite separator plate of claim 1 further comprising a non-conductive fibrous material of less than 10% by volume.

14. The composite separator plate of claim 1 wherein said fibrous conductive material comprises a first conductive fiber material of 1% and 25% by volume and a second conductive fiber material of from 1% and 25% by volume said second conductive fiber material being different from said first conductive fiber material.

15. The composite separator plate of claim 14 wherein said first conductive fiber material is a graphite fiber of approximately 15% by volume and having an aspect ratio of greater than 100:

1, and said second conductive fiber material is a carbon fiber of approximately 5% by volume and having an aspect ratio of greater than 15;

1.

16. The composite separator plate of claim 15 further comprising a conductive non-fibrous material of approximately 5% by volume.

17. The composite separator plate of claim 16 wherein said conductive non-fibrous material is selected from the group consisting of carbon black, graphite powder and metal powder.

18. A method of manufacturing a composite separator plate comprising the steps of:

formulating a composite material having a polymeric material of 50% to 98% by volume and a fibrous conductive material of 2% to 50% by volume;

molding said composite material between a first molding surface defining a first land cavity and a second molding surface having a second land cavity to form a separator plate including a first land having a first land height extending from a first side of said separator plate and a second land having a second land height extending from a second side of said separator plate, said fibrous material being oriented such that a first portion of said fibrous conductive material is disposed in said first land and a second portion of said fibrous conductive material is disposed in said second land;

removing at least a portion of said first land, thereby reducing said first land height and forming a first exposed surface having an end of said first portion of fibrous conductive material terminating proximate said first exposed surface; and

removing at least a portion of said second land, thereby reducing said second land height and forming a second exposed surface having an end of said second portion of fibrous conductive material terminating proximate said second exposed surface.

19. The method of manufacturing a composite separator plate of claim 18 wherein the step of molding said composite material comprises forming a charge from said, composite material placing said charge in a die set having said first and second molding surfaces formed therein, and compression molding said separator plate.

20. The method of manufacturing a composite separator plate of claim 18 wherein the step of molding said composite material comprises injecting said composite material between a die set having said first and second molding surfaces formed therein, and compression molding said composite material into said separator plate.

21. The method of manufacturing a composite separator plate of claim 18 wherein the step of molding said composite material comprises injecting said composite material into a die cavity having said first and second molding surfaces such that said separator plate is molded in said die cavity.

22. The method of manufacturing a composite separator plate of claim 18 wherein the steps of removing at least a portion of said first and second land heights reduces said first and second lands height by 20% or more.

23. The method of manufacturing a composite separator plate of claim 18 wherein the steps of removing at least a portion of said first and second lands comprises a suitable machining operation.

24. The method of manufacturing a composite separator plate of claim 18 wherein said suitable machining operation is selected from a group of machining operation consisting of laser machining, water-jet machining, milling, fly-cutting and sanding.

25. A composite separator plate comprising:

a composite material molded to form a first land having a first land height extending from a first side of said separator plate and a second land having a second land height extending from a second side of said separator plate, said composite material including a polymeric material of 50% to 98% by volume and a fibrous conductive material of 2% to 50% by volume oriented such that a first portion of said fibrous material is disposed in said first land and a second portion of said fibrous material is disposed in said second land;

wherein a portion of said first land is removed from said separator plate to reduce said first land height and form a first exposed surface having an end of said first portion of said fibrous conductive material terminating proximate said first exposed surface; and

wherein a portion of said second land is removed from said separator plate to reduce said second land height and form a second exposed surface having an end of said second portion of said fibrous conductive material terminating proximate said second exposed surface.

26. The composite separator plate of claim 25 wherein said polymeric material is a conductive polymeric material.

27. The composite separator plate of claim 25 wherein composite material further comprises a conductive non-fibrous material of less than 10% by volume.

28. The composite separator plate of claim 27 wherein said conductive non-fibrous material is selected from the group consisting of carbon black, graphite powder and metal powder.

29. The composite separator plate of claim 25 wherein said polymeric material is selected from the group consisting of thermoset and thermoplastic polymers.

30. The composite separator plate of claim 29 wherein said polymeric material is selected from the group consisting of silicone, poly-isobutylene, epoxy vinyl ester and phenol.

31. The composite separator plate of claim 30 wherein said polymeric material is selected from the group consisting of polypropylene, ETFE, nylon, and rubber-modified polypropylene.

32. The composite separator plate of claim 25 wherein said fibrous conductive material is a conductive fiber material having an aspect ratio equal to or greater than 10:

1.

33. The composite separator plate of claim 32 wherein said conductive fiber material is selected from the group consisting of carbon fibers, graphite fibers, nickel-coated graphite fibers, and stainless steel fibers.

34. The composite separator plate of claim 33 wherein said conductive fiber material is a PAN MF 30 carbon fiber of approximately 40% by volume and having an aspect ratio of greater than 15:

1.

35. The composite separator plate of claim 25 wherein said composite material further comprises a non-conductive fibrous material of less than 10% by volume.

36. The composite separator plate of claim 25 wherein said fibrous conductive material comprises a first conductive fiber material of 1% and 25% by volume and a second conductive fiber material of from 1% and 25% by volume, said second conductive fiber material being different from said first conductive fiber material.

37. The composite separator plate of claim 36 wherein said first conductive fiber material is a graphite fiber of approximately 15% by volume and having an aspect ratio of greater than 100:

1, and said second conductive fiber material is a carbon fiber of approximately 5% by volume and having an aspect ratio of greater than 15;

1.

38. The composite separator plate of claim 36 wherein said composite material further comprises a conductive non-fibrous material of approximately 5% by volume.

39. The composite separator plate of claim 38 wherein said conductive non-fibrous material is selected from the group consisting of carbon black, graphite powder and metal powder.

40. A composite separator plate for use in a fuel cell stack, of the type having a first surface with a plurality of flow channels formed therein and a second surface opposite said first surface the composite separator plate comprising a polymeric material and a fibrous conductive material, said fibrous conductive material disposed in a through-plane orientation and present in an amount sufficient to provide a conductive path in said through-plane direction.

41. A composite separator plate comprising:

a composite material molded to form a first land having a first land height extending from a first side of said separator plate and a second land having a second land height extending from a second side of said separator plate, said composite material including a polymeric material and a fibrous conductive material said fibrous conductive material oriented such that a first portion of said fibrous material is disposed in said first land and a second portion of said fibrous material is disposed in said second land;

wherein has a portion of said first land is removed from said separator plate to reduce said first land height and form a first exposed surface having an end of said first portion of said fibrous conductive material terminating proximate said first exposed surface;

wherein a portion of said second land is removed from said separator plate to reduce said second land height and form a second exposed surface having an end of said second portion of said fibrous conductive material terminating proximate said second exposed surface; and

wherein said fibrous conductive material is present in an amount sufficient to provide a conductive path from said first land to said second land.

42. A method of manufacturing a composite separator plate comprising the steps of:

formulating a composite material having a polymeric material and a fibrous conductive material, said fibrous conductive material present in an amount of up to 50% by volume;

molding said composite material between a first molding surface defining a first land cavity and a second molding surface having a second land cavity to form a separator plate including a first land having a first land height extending from a first side of said separator plate and a second land having a second land height extending from a second side of said separator plate, said fibrous material being oriented such that a first portion of said fibrous conductive material is disposed in said first land and a second portion of said fibrous conductive material is disposed in said second land;

removing at least a portion of said first land, thereby reducing said first land height and forming a first exposed surface having an end of said first portion of fibrous conductive material terminating proximate said first exposed surface; and

removing at least a portion of said second land, thereby reducing said second land height and forming a second exposed surface having an end of said second portion of fibrous conductive material terminating proximate said second exposed surface; and

provided that said fibrous conductive material is present in an amount sufficient to provide a conductive path from said first land to said second land.