Method for preventing deposits in oil extraction

• US 6,613,899 B1
• Filed: 12/11/2000
• Issued: 09/02/2003
• Est. Priority Date: 06/09/1998
• Status: Expired due to Term

• Current Assignee: Cooperatie Cosun U.A.
• Original Assignee: Cooperatie Cosun U.A.
• Inventors: Kuzee, Hendrika Cornelia, Raaijmakers, Hendricus Wilhelmus Carolina
• Primary Examiner(s): Fonda, Kathleen K.
• Assistant Examiner(s): McIntosh, III, Traviss C.
• Application Number:
  US09/719,239
• Time in Patent Office: 995 Days
• Field of Search: 536/1.11, 536/4.1, 536/123, 536/124, 210/698, 252/180, 252/175, 252/102
• US Class Current: 536/124
• CPC Class Codes: C09K 8/528 inorganic depositions, e.g. sulfates or carbonates

Abstract

Carboxyl-containing fructans such as carboxymethylinulin can be successfully used to prevent deposition of scale composed of, for example, calcium, barium and strontium salts of sulphuric acid and carbonic acid in oil extraction. In the oil extraction method, 0.5-200 ppm of a carboxyl-containing fructan that contains 0.3-3 carboxyl groups per mono-saccharide unit is incorporated in the process water, in the process equipment or in the oil-containing formation.

Claims

1. A method of preventing deposition of scale on surfaces exposed to process sea water in an oil extraction process that uses sea water, the method comprising the steps of:

pumping process sea water into a rock formation from which oil is to be extracted; and

preventing deposition of scale that comprises calcium, barium and strontium salts on the surfaces exposed to the process sea water by adding a carboxyl-containing fructan that contains 0.3-3 carboxyl groups per monosaccharide unit to the process sea water so that a concentration of the carboxyl-containing fructan in the process sea water is 0.5-200 ppm.

2. The method according to claim 1, wherein the concentration is 2 to 50 ppm.

3. The method according to claim 1, wherein the carboxyl-containing fructan contains at least 0.8 carboxyl groups per monosaccharide unit.

4. The method according to claim 1, wherein the carboxyl-containing fructan contains 0.7-2.5 carboxymethyl groups per monosaccharide unit.

5. The method according to claim 1, wherein the carboxyl-containing fructan is a carboxymethylinulin having an average degree of polymerization of 6-60.

6. The method according to claim 1, wherein the method prevents deposition of scale that comprises carbonate and sulphate salts.

7. The method according to claim 1, wherein the method prevents deposition of scale that comprises iron salts.

8. The method according to claim 1, wherein the fructan is a purified carboxyalkylfructan.

9. A method of preventing deposition of scale on oil extraction equipment that extracts oil from an oil-containing rock formation using sea water, the method comprising the step of introducing a carboxyl-containing fructan that contains 0.3-3 carboxyl groups per monosaccharide unit onto locations on the oil extraction equipment exposed to sea water where calcium, barium and strontium salt scale forms to prevent formation of this scale.

10. The method according to claim 9, wherein the carboxyl-containing fructan contains at least 0.8 carboxyl groups per monosaccharide unit.

11. The method according to claim 9, wherein the carboxyl-containing fructan contains 0.7-2.5 carboxymethyl groups per monosaccharide unit.

12. The method according to claim 9, wherein the carboxyl-containing fructan is a carboxymethylinulin having an average degree of polymerization of 6-60.

13. The method according to claim 9, wherein the method prevents deposition of scale that comprises carbonate and sulphate salts.

14. The method according to claim 9, wherein the method prevents deposition of scale that comprises iron salts.

15. The method according to claim 9, wherein the fructan is a purified carboxyalkylfructan.

16. A method of preventing deposition of scale on an oil-containing rock formation in an oil extraction process that extracts oil from the oil-containing rock formation using sea water, the method comprising the steps of introducing a carboxyl-containing fructan that contains 0.3-3 carboxyl groups per monosaccharide unit into the rock formation that has been exposed to sea water so that the fructan is adsorbed by the rock formation, and then desorbing the fructan from the rock formation to prevent formation of this scale on the rock formation.

17. The method according to claim 16, wherein the carboxyl-containing fructan contains at least 0.8 carboxyl groups per monosaccharide unit.

18. The method according to claim 16, wherein the carboxyl-containing fructan contains 0.7-2.5 carboxymethyl groups per monosaccharide unit.

19. The method according to claim 16, wherein the carboxyl-containing fructan is a carboxymethylinulin having an average degree of polymerization of 6-60.

20. The method according to claim 16, wherein the method prevents deposition of scale that comprises carbonate and sulphate salts.

21. The method according to claim 16, wherein the method prevents deposition of scale that comprises iron salts.

22. The method according to claim 16, wherein the fructan is a purified carboxyalkylfructan.