Machinable positive image model material for shape deposition manufacturing

• US 6,616,885 B2
• Filed: 10/04/2001
• Issued: 09/09/2003
• Est. Priority Date: 12/08/1999
• Status: Expired due to Fees

• Current Assignee: Advanced Ceramics Research, Inc. (Rtx Corporation)
• Original Assignee: Advanced Ceramics Research, Inc. (Rtx Corporation)
• Inventors: Lombardi, John Lang, Artz, Gregory John
• Primary Examiner(s): Seidleck, James J.
• Assistant Examiner(s): McClendon, Sanza L.
• Application Number:
  US09/970,598
• Publication Number:
  US 20020053758A1
• Time in Patent Office: 705 Days
• Field of Search: 522/88, 522/116, 522/114, 522/120, 522/121, 522/71, 522/126, 527/314, 527/315, 525/242, 264/401, 264/138, 264/221, 264/317, 264/318, 264/219, 264/163, 264/241, 264/255, 264/313, 264/308, 264/297.1
• US Class Current: 264/401
• CPC Class Codes: B29C 2035/0827 using UV radiation
• CPC Class Codes: B29C 2793/009 after shaping
• CPC Class Codes: B29C 33/3842 Manufacturing moulds, e.g. shaping the mould surface by machining
• CPC Class Codes: B29C 64/124 using layers of liquid which are selectively solidified
• CPC Class Codes: B29K 2033/26 Polymers of acrylamide or methacrylamide
• CPC Class Codes: B29K 2039/06 Polymers of N-vinyl-pyrrolidones
• CPC Class Codes: B29K 2091/00 Use of waxes as moulding material
• CPC Class Codes: B29K 2995/0059 Degradable

Abstract

A manufacturing method comprising the steps of forming at first solidified wax layer of a desired shape, depositing onto the first solidified wax layer at least one layer of a liquid resin formulation, solidifying the layer of liquid resin formulation, depositing a second wax layer on to the combination of the first solidified wax layer and the layer of solidified resin formulation, solidifying the second wax layer, and separating the solidified resin formulation from first and second wax layers. Preferably, the resin formulation comprises at least one monofunctional water soluble vinyl or acrylic monomer in combination with a low molecular weight aliphatic polymer having acrylic or methacrylic acid functionality. The solidified wax and resin formulation layers can be machined as may be desired to form mold of a given shape comprising wax layers when the layer of formulation is separated from the wax layers.

Claims

1. In a manufacturing method comprising the steps of forming at first solidified wax layer of a desired shape;

depositing onto the first solidified wax layer at least one layer of a liquid resin formulation;

solidifying the layer of liquid resin formulation;

depositing a second wax layer onto the combination of the first solidified wax layer and the layer of solidified resin formulation;

solidifying the second wax layer; and

separating the solidified resin formulation from said first and second wax layers, the improvement comprising said step of depositing the liquid resin formulation including deposition of at least one monofunctional water soluble vinyl or acrylic monomer in combination with a low molecular weight aliphatic polymer having acrylic or methacrylic acid functionality.

3. The method of claim 1 wherein the monofunctional water soluble vinyl or acrylic monomer is N-Vinyl pyrrolidone or N,N′

-Dimethylacrylamide.

4. The method of claim 1 wherein the low molecular weight aliphatic polymer having acrylic or methacrylic acid functionality comprises polyethylene co-acrylic acid, polystyrene co-acrylic acid, or polyalkylacrylate co-acrylic acid.

5. The method of claim 1 wherein liquid resin formulation solidification is accomplished by UV photopolymerization.

7. The method of claim 1 wherein the step of separating the solidified resin formulation from the wax layers comprises dissolving the solidified resin formulation in a solvent comprising dilute ammonium hydroxide and its carbonate salts, and alkali and alkaline earth hydroxides.

9. The method of claim 1 wherein at least one sugar is added to the liquid resin formulation as a soluble filler prior to solidification of the resin formulation.

10. The method of claim 9 wherein the sugar comprises confectioner'"'"'s powdered sugar.

11. The method of claim 1 further including the step of adding a surfactant to enhance the wetting of the liquid resin formulation upon the wax layer prior to solidification of the resin formulation.

12. The method of claim 1 further including the step of adding a photoinitiator to the liquid resin formulation to increase the solidifying of the liquid resin formulation.

17. The method of claim 5 wherein the layer of liquid resin formulation is at least about 3 millimeters thick and is solidified by photopolymerization within about 2 minutes.

2. In a manufacturing method comprising the steps of forming at first solidified wax layer of a desired shape;

depositing onto the solidified first wax layer at least one layer of a liquid resin formulation;

solidifying the layer of liquid resin formulation;

depositing a second wax layer on to the combination of the solidified first wax layer and the layer of solidified resin formulation;

solidifying the second wax layer;

repeating any of the steps of depositing and solidifying layers of liquid resin and wax layers to form successive solidified wax and resin formulation layers; and

separating the solidified resin formulation layers from the solidified wax layers, the improvement comprising said step of depositing the layer of liquid resin formulation including deposition of at least one monofunctional water soluble vinyl or acrylic monomer in combination with a low molecular weight aliphatic polymer having acrylic or methacrylic acid functionality.

6. The method of claim 2 wherein liquid resin formulation solidification is accomplished by UV photopolymerization.

8. The method of claim 2 wherein the step of separating the solidified resin formulation from the wax layers comprises dissolving the solidified resin formulation in a solvent comprising dilute ammonium hydroxide and its carbonate salts, and alkali and alkaline earth hydroxides.

13. The method of claim 2 wherein at least one sugar is added to the liquid resin formulation as a soluble filler prior to solidification of the resin formulation.

14. The method of claim 13 wherein the sugar comprises confectioner'"'"'s powdered sugar.

15. The method of claim 2 further including the step of adding a surfactant to enhance the wetting of the liquid resin formulation upon the wax layer prior to solidification of the resin formulation.

16. The method of claim 2 further including the step of adding a photoinitiator to the liquid resin formulation to increase the solidifying of the liquid resin formulation.

18. The method of claim 6 wherein the layer of liquid resin formulation is about 3 millimeters thick and is solidified by photopolymerization within about 2 minutes.

19. A method for manufacturing a molded part comprising forming a dissolvable support core for a mold by solidifying a liquid resin formulation that includes at least one monofunctional water soluble vinyl or acrylic monomer in combination with a low molecular weight aliphatic polymer having acrylic or methacrylic acid functionality.

20. The method of claim 19 wherein the monofunctional water soluble vinyl or acrylic monomer is N-Vinyl pyrrolidone or N,N′

-Dimethylacrylamide.

21. The method of claim 19 wherein the low molecular weight aliphatic polymer having acrylic or methacrylic acid functionality includes polyethylene co-acrylic acid, polystyrene co-acrylic acid, or polyalkylacrylate co-acrylic acid.

22. The method of claim 19 wherein at least one sugar is added to the liquid resin formulation as a soluble filler prior to solidification of the resin formulation.

23. The method of claim 22 wherein the sugar comprises confectioner'"'"'s powdered sugar.

24. The method of claim 22 wherein addition of the at least one sugar reduces the shrinkage of the liquid resin formulation during solidification as compared to a liquid resin formulation without addition of the at least one sugar.

25. The method of claim 19 wherein the support core is formed by depositing one or more layers of the liquid resin formulation and solidifying the one or more layers by UV photopolymerization.

26. The method of claim 25 wherein the one or more layers each have a thickness of up to about 3 millimeters or more and are solidified by photopolymerization within about 2 minutes.