Protective layer transfer sheet

• US 6,616,993 B2
• Filed: 02/28/2001
• Issued: 09/09/2003
• Est. Priority Date: 03/03/2000
• Status: Active Grant

• Current Assignee: Dai Nippon Printing Company Limited
• Original Assignee: Dai Nippon Printing Company Limited
• Inventors: Saito, Hitoshi, Moriguchi, Satoshi, Usuki, Hideki, Obonai, Naohiro
• Primary Examiner(s): Hess, B. Hamilton
• Application Number:
  US09/794,235
• Publication Number:
  US 20020197453A1
• Time in Patent Office: 923 Days
• Field of Search: 847/1, 428/195, 428/913, 428/914, 428/32.79, 428/32.81, 503/227
• US Class Current: 428/32.79
• CPC Class Codes: B41M 7/0027 using protective coatings or layers by lamination or by fusion of the coatings or layers
• CPC Class Codes: Y10T 428/24802 Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]

Abstract

The present invention provides a protective layer transfer sheet which, when used to thermally transfer a protective layer onto an image-receiving sheet with an image formed thereon, provides a print that does not cause cracking of the protective layer and, even when housed and stored in a vinyl chloride case containing a plasticizer or the like, does not cause the migration of a dye constituting the image to the case, that is, has excellent fastness properties. In a protective layer transfer sheet 7 comprising a substrate sheet 1, a heat-resistant slip layer 3 provided on one side of the substrate sheet 1, and a thermally transferable protective layer 2 releasably provided on at least a part of the surface of the substrate sheet 1 remote from the heat-resistant slip layer 3, the thermally transferable protective layer 2 contains an epoxy resin and, in addition, contains at least one member selected from the group consisting of a butyral resin, an acrylic resin, and an ultraviolet absorber. By virtue of this construction, a protective layer 2 is strongly adhered onto an image-receiving sheet with an image formed thereon. Further, the protective layer 2 is strong and homogeneous, and, thus, even when the print is housed in a vinyl chloride case, the print does not cause the dye to migrate to the case, that is, has excellent plasticizer resistance.

Claims

1. A protective layer transfer sheet comprising:

a substrate sheet; and

a thermally transferable protective layer releasably provided on the substrate sheet, said thermally transferable protective layer comprising a combination of a main protective layer and an adhesive layer provided in that order from the substrate sheet side,

said adhesive layer containing an epoxy resin and, in addition, containing at least one member selected from the group consisting of a butyral resin, an acrylic resin, an ultraviolet absorber, and a mixture thereof.

2. The protective layer transfer sheet according to claim 1, which further comprises a heat-resistant slip layer provided on the surface of the substrate sheet on its side remote from the thermally transferable protective layer.

3. The protective layer transfer sheet according to claim 1, wherein the thermally transferable protective layer is a laminate comprising a release layer, a main protective layer, and an adhesive layer provided in that order from the substrate sheet side.

4. The protective layer transfer sheet according to claim 3, wherein the release layer contains at least an acrylic resin.

5. The protective layer transfer sheet according to claim 3, wherein the release layer is non-transferable, and, upon thermal transfer, the release layer stays on the substrate sheet while the protective layer is separable from the substrate sheet.

6. The protective layer transfer sheet according to claim 1, wherein, upon thermal transfer, the thermally transferable protective layer is separable directly from the substrate sheet.

7. The protective layer transfer sheet according to claim 1, wherein the epoxy resin has a molecular weight in the range of 800 to 6000 and a glass transition temperature of 60 to 150°

C.

8. The protective layer transfer sheet according to claim 1, wherein the ultraviolet absorber comprises a nonreactive ultraviolet absorber compound with a reactive group introduced thereinto.