Process for making visco-elastic foams, polyols blend and reaction system useful therefor

• US 6,617,369 B2
• Filed: 04/12/2002
• Issued: 09/09/2003
• Est. Priority Date: 11/02/1999
• Status: Expired due to Term

• Current Assignee: Huntsman International LLC (Huntsman Corporation)
• Original Assignee: Huntsman International LLC (Huntsman Corporation)
• Inventors: Yu, Jianming, Parfondry, Alain
• Primary Examiner(s): COONEY, JOHN M
• Application Number:
  US10/122,435
• Publication Number:
  US 20030105177A1
• Time in Patent Office: 515 Days
• Field of Search: 521/130, 521/133, 521/137, 521/160, 521/174, 521/904
• US Class Current: 521/174
• CPC Class Codes: C08G 18/4804 Two or more polyethers of different physical or chemical nature
• CPC Class Codes: C08G 18/4841 containing oxyethylene end groups
• CPC Class Codes: C08G 2110/0008 flexible
• CPC Class Codes: C08G 2110/005 < 50kg/m3
• CPC Class Codes: C08G 2110/0083 prepared using water as the sole blowing agent
• CPC Class Codes: Y10S 521/904 Polyurethane cellular product having high resiliency or cold cure property

Abstract

The invention relates to a one-shot or prepolymer process for preparing a visco-elastic polyurethane foam by reacting a polyisocyanate composition with a polyol composition comprising b1) an EO-rich polyol; b2) a polyol with an EO content between 20-50% and a primary hydroxy content of at least 50%; b3) a polyol with an EO content between 10-20% and a primary hydroxy content of at least 50%; and b4) a polyalkyleneglycol; according to the following proportions: b1: 30-85 wt %, b2: 5-65 wt %, b3: 5-40 wt %, b4: 0-50 wt %.

The invention also relates to reaction systems comprising the above components and to the polyol composition.

Claims

1. A process for preparing a visco-elastic polyurethane foam at an NCO index of 70-120, which process may be a one-shot or prepolymer process, comprising reacting:

a) a polyisocyanate composition;

b1) a polyoxyethylene-polyoxypropylene polyol, having an average nominal hydroxy functionality of 2-6, where the EO is present as tipped EO and/or random EO, the total EO content being at least 50% by weight;

b2) a polyoxyethylene-polyoxypropylene polyol, having an average nominal hydroxy functionality of 2-6, where the EO is present as tipped EO and/or random EO, the total EO content being between 20-50% by weight, having a primary hydroxy content of at least 50% calculated on the amount of primary and secondary hydroxyl groups;

b3) a polyoxyethylene-polyoxypropylene polyol, having an average nominal hydroxyl functionality of 2-6, having a primary hydroxy content of at least 50% calculated on the amount of primary and secondary hydroxyl groups, and having an EO content of from 10 to 20% by weight; and

optionally

b4) a polyalkyleneglycol having an average molecular weight from 100 to 1200;

these polyols b1, b2, b3 and b4 being reacted according to the following proportions, based on the combined weights of b1, b2, b3 and b4, b1;

30-85 wt %, b2;

5-65 wt %, b3;

5-40 wt %, b4;

0-50 wt %;

c) water; and

d) additives and auxiliaries known per se;

and where the polyisocyanate prepolymer has an NCO value above 20% in case the prepolymer process is used.

2. The process according to claim 1, wherein these polyols b1, b2, b3 and b4 are reacted according to the following proportions, based on the combined weights of b1, b2, b3 and b4:

b1;

40-70 wt %, b2;

10-30 wt %, b3;

5-25 wt %, b4;

0-40 wt %.

3. The process of claim 1, wherein the polyol b2) is of the -PO-PO/EO-EO type, the -PO/EO-EO type or the -PO-EO type.

4. The process of claim 1, wherein the functionality of the polyols b1, b2 and b3 is 2-4 and wherein the polyols b1 to b4 further comprise dispersed particles and wherein the EO content of the polyol based on the combined weights of b1, b2, b3 and b4 is at least 40% by weight and wherein the polyisocyanate is MDI or a modified variant thereof.

5. The process of claim 1, wherein the NCO value is at least 23% by weight and wherein the NCO index is 70-110.

6. A polyol composition comprising:

b1) a polyoxyethylene-polyoxypropylene polyol, having an average nominal hydroxy functionality of 2-6, where the EO is present as tipped EO and/or random EO, the total EO content being at least 50% by weight;

b2) a polyoxyethylene-polyoxypropylene polyol, having an average nominal hydroxy functionality of 2-6, where the EO is present as tipped EO and/or random EO, the total EO content being between 20-50% by weight, having a primary hydroxy content of at least 50% calculated on the amount of primary and secondary hydroxyl groups;

b3) a polyoxyethylene-polyoxypropylene polyol, having an average nominal hydroxyl functionality of 2-6, having a primary hydroxy content of at least 50% calculated on the amount of primary and secondary hydroxyl groups and having an EO content of from 10 to 20% by weight; and

optionally

b4) a polyalkyleneglycol having an average molecular weight from 100 to 1200;

these polyols b1, b2, b3 and b4 being present according to the following proportions, based on the combined weights of b1, b2, b3 and b4, b1;

30-85 wt %, b2;

5-65 wt %, b3;

5-40 wt %, b4;

0-50 wt %.

7. The polyol composition according to claim 6, wherein these polyols b1, b2, b3 and b4 are present according to the following proportions, based on the combined weights of b1, b2, b3 and b4:

b1;

40-70 wt %, b2;

10-30 wt %, b3;

5-25 w %, b4;

0-40 w %.

8. The polyol composition of claim 6, wherein the polyol b2) is of the -PO-PO/EO-EO type, the -PO/EO-EO type or the -PO-EO type.

9. The polyol composition of claim 6, wherein the EO content of the polyol based on the combined weights of b1, b2, b3 and b4 is at least 40 by weight.

10. A reaction system comprising:

A) a polyisocyanate prepolymer having an NCO value of at least 20% by weight, obtained by reacting a polyisocyanate with a polyol composition comprising;

b1) a polyoxyethylene-polyoxypropylene polyol, having an average nominal hydroxy functionality of 2-6, where the EO is present as tipped EO and/or random EO, the total EO content being at least 50% by weight;

b2) a polyoxyethylene-polyoxypropylene polyol, having an average nominal hydroxy functionality of 2-6, where the EO is present as tipped EO and/or random EO, the total EO content being between 20-50 % by weight, having a primary hydroxy content of at least 50% calculated on the amount of primary and secondary hydroxyl groups;

b3) a polyoxyethylene-polyoxypropylene polyol, having an average nominal hydroxyl functionality of 2-6, having a primary hydroxy content of at least 50% calculated on the amount of primary and secondary hydroxyl groups and having an EO content of from 10 to 20% by weight; and

optionally

b4) a polyalkyleneglycol having an average molecular weight from 100 to 1200;

wherein polyols b1, b2, b3 and b4 being present according to the following proportions, based on the combined weights of b1, b2, b3 and b4, b1;

30-85 wt %, b2;

5-65 wt %, b3;

5-40 wt %, b4;

0-50 wt %; and

B) an isocyanate-reactive component comprising the polyol composition and water.

11. The reaction system of claim 10, wherein polyols b1, b2, b3 and b4 are present according to the following proportions, based on the combined weights of b1, b2, b3 and b4:

b1;

40-70 wt %, b2;

10-30 wt %, b3;

5-25 w %, b4;

0-40 w %.

12. The reaction system of claim 10, wherein polyol b2 is of tho -PO-PO/EO-EO type, the -PO/EO-EO type or the -PO-EO type.

13. The reaction system of claim 10, wherein the EO content of the polyol based on the combined weights of b1, b2, b3 and b4 is at least 40 by weight.