Thick film conductor composition for use in biosensors

• US 6,627,058 B1
• Filed: 01/17/2001
• Issued: 09/30/2003
• Est. Priority Date: 01/17/2001
• Status: Expired due to Fees

• Current Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Original Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Inventors: Chan, Man-Sheung
• Primary Examiner(s): Nguyen, Nam
• Assistant Examiner(s): NOGUEROLA, ALEXANDER STEPHAN
• Application Number:
  US09/761,311
• Time in Patent Office: 986 Days
• Field of Search: 252/503, 252/514, 419/32, 204/292, 204/294, 204/403.01, 204/403.1, 204/403.11, 204/403.15, 204/416
• US Class Current: 204/403.15
• CPC Class Codes: C12Q 1/006 for glucose
• CPC Class Codes: G01N 27/308 at least partially made of carbon

Abstract

This invention is directed to a composition comprising: (a) platinum group metal powder, alloys, or mixtures thereof as a powder or deposited on graphite supports; (b) poly(glycol ether), derivatives, or mixtures thereof; (c) carbon-based electrically conductive filler; and (d) thermoplastic polymer or mixtures thereof. The invention is further directed to a process for dispersing platinum group metal powder, alloys, or mixtures thereof in poly(glycol ether), derivatives, or mixtures thereof. The invention is further directed to the above composition wherein the platinum group metal powder has been dispersed according to the above process.

Claims

1. A composition consisting essentially of:

(a) electrocatalyst selected from the group consisting of (1) platinum black and platinum group metal powders, alloys and mixtures thereof;

(2) platinum group metals, alloys or mixtures thereof deposited on graphite support particles;

or (3) mixtures of (1) and (2) wherein the surface area of said electrocatalyst is less than 150 m²/g;

(b) carbon-based electrically conductive filler selected from the group consisting of graphite and mixtures of graphite and conductive carbon black;

(c) a hydrophobic poly(glycol ether) material selected from the group consisting of a hydrophobic poly(glycol ethers)polymer, poly(tetramethylene glycol), poly(propylene glycol), hydrophobic copolymers of poly(gycol ether) with alkyl and carboxylated poly(glycol ether) and mixtures thereof; and

(d) a thermoplastic polymer material; and

;

(e) an aromatic hydrocarbon solvent.

2. The composition of claim 1 wherein the amount of electrocatalyst is in the range of 0.1-5% wt. based on solids in the composition.

3. The composition of claim 1 wherein the platinum group metal powder has a surface area >

5 m²/g.

4. The composition of claim 1 wherein the electrocatalyst is platinum black.

5. The composition of claim 4 wherein the platinum black has a surface area of 25-60 m²/g.

6. The composition of claim 1 wherein the carbon-based conductive filler consists of mixtures of graphite and conductive carbon black having a ratio of carbon black to graphite that is in the range of 5/95 to 0.5/99.5.

7. The composition of claim 6 wherein the carbon black has an average primary particle size <

100 nm.

8. The composition of claim 6 wherein the graphite is synthetic graphite, natural graphite or mixtures thereof having an average particle size >

1 micron.

9. The composition of claim 1 wherein the platinum group metals, alloys, or mixtures thereof deposited on graphite support particles comprise 0.5-10% metal based on the weight of the particle.

10. The composition of claim 1 wherein the carbon-based conductive filler is in the range of 62-85% wt. based on solids in the composition.

11. The composition of claim 1 wherein the amount of hydrophobic poly(glycol ether) material is in the range of 0.1-5% wt. based on solids in the composition.

12. The composition of claim 1 wherein the amount of thermoplastic polymer is in the range of 14-35% wt. based on solids in the composition.

13. The composition of claim 1 wherein the thermoplastic polymer a has T_g>

50°

C.

14. The composition of claim 1 wherein the thermoplastic polymer is selected from poly(styrene), styrene-containing acrylic copolymer, poly(acrylonitrile-butadiene styrene), poly(hydroxyether), polyester, poly(carbonate), polyimide, and mixtures thereof.

15. A disposable biosensor comprising the composition of claim 1.

16. A process for dispersing platinum group metal powders, alloys, or mixtures thereof, wherein the surface area of said platinum group metal powders, alloys or mixtures thereof is less than 65 m²/g, comprising the steps of first mixing an electrocatalyst selected from the group consisting of (1) platinum black and platinum group metal powders, alloys and mixtures thereof;

(2) platinum group metals, alloys or mixtures thereof deposited on graphite support particles;

or (3) mixtures of (1) and (2) wherein the surface area of said electrocatalyst is less than 150 m²/g with;

a hydrophobic poly(glycol ether) material dissolved in an aromatic hydrocarbon solvent wherein the hydrophobic poly(glycol ether) material selected from the group consisting of a hydrophobic poly(glycol ethers) polymer, poly(tetramethylene glycol), poly(propylene glycol), hydrophobic copolymers of poly(gycol ether) with alkyl and carboxylated poly(glycol ether) and mixtures thereof, and using a dispersing means to acheive a desired particle size.

17. The process of claim 16 wherein the dispersing means a three-roll-mill.