Polyurethane adhesive

• US 6,630,050 B1
• Filed: 05/24/2000
• Issued: 10/07/2003
• Est. Priority Date: 09/24/1997
• Status: Expired due to Fees

• Current Assignee: Henkel KGaA (Henkel AG & Co KGaA)
• Original Assignee: Henkel KGaA (Henkel AG & Co KGaA)
• Inventors: Plum, Hermann-Josef, Moeller, Thomas, Herlfterkamp, Bernhard, Fischer, Herbert, Gensch, Ingo, Huebner, Norbert
• Primary Examiner(s): YAO, SAMCHUAN CUA
• Application Number:
  US09/509,363
• Time in Patent Office: 1,231 Days
• Field of Search: 156/331.7, 524/591
• US Class Current: 156/331.7
• CPC Class Codes: B65C 9/22 by wetting, e.g. by applying liquid glue or a liquid to a dry glue coating
• CPC Class Codes: C08G 18/0823 containing carboxylate salt groups or groups forming them
• CPC Class Codes: C08G 18/4808 Mixtures of two or more polyetherdiols
• CPC Class Codes: C08G 18/6674 with compounds of group C08G18/3203
• CPC Class Codes: C08G 2170/80 Compositions for aqueous adhesives

Abstract

The invention relates to a contact adhesive based on a polyurethane of at least one diisocyanate and at least one low molecular weight polyethylene glycol, the polyethylene glycol having a molecular weight of up to 2,000 and the polyurethane having a degrees of crystallization of less than 20%. The contact adhesive can be applied from the melt or from an aqueous solution or dispersion. Surprisingly, it is suitable not only for polar plastic surface, but above all for PE and PP surfaces and of course for paper. Accordingly, the contact adhesive is preferably useful for applying paper labels to PE bottles.

Claims

1. An adhesive composition comprising:

a polyurethane comprising a reaction product of

a) at least one diisocyanate; and

b) at least one low molecular weight polyethylene glycol,

wherein, said polyethylene glycol has a molecular weight M_z up to 2,000, and;

wherein, said polyurethane has a degree of crystallization of less tan 20 percent, as measured by a DSC method, based on a degree of crystallization of polyethylene glycol 6000 as a standard, is permanently tacky and is water-soluble or dispersible in water, wherein, said low molecular weight polyethylene glycol is partly replaced by at least one polyol selected from the group consisting of;

a) up to 50 percent by weight of a block or statistical copolymer of ethylene oxide;

b) up to 20 percent by weight of a hydrophobic aliphatic or cycloaliphatic diol;

c) up to 10 percent by weight of hydrophobic homopolymeric polyalkylene glycols, wherein the alkylene group in said glycols contains more than 2 carbon atoms and said glycols have a molecular weight of from 150 to 10,000;

d) up to 40 percent by weight of polyethylene glycol with a molecular weight of from 2,000 to 40,000;

e) up to 5 percent by weight of triols; and

f) up to 5 percent by weight of ion-forming diols,

said percentages shown representing percent by weight, based on the total weight of said polyethylene glycol and polyols and;

wherein, the diisocyanate can contain up to 50% by weight of TMXDI based on the weight of the diisocyanate.

2. The adhesive of claim 1 wherein said polyurethane has an Epprecht melt viscosity of more than 5 Pas at 110°

C.

3. The adhesive of claim 2 wherein said polyurethane has an Epprecht melt viscosity of more than 30 Pas at 110°

C.

4. The adhesive of claim 1 wherein a 50 percent by weight aqueous solution has a viscosity of greater than 10,000 mPas, at 20°

C. as measured by a Brookfield method.

5. The adhesive of claim 3 wherein a 50 percent by weight aqueous solution has a viscosity of greater than 20,000 mPas, at 20°

C. as measured by a Brookfield method.

6. The adhesive of claim 1 wherein said diisocyanate comprises 50 percent by weight or greater of an aromatic diisocyanate, and up to 50 percent by weight of aliphatic or cycloaliphatic diisocyanates.

7. The adhesive of claim 6 wherein said aromatic diisocyanate comprises MDI.

8. The adhesive of claim 1 wherein said polyethylene glycol is partly replaced by a polyol selected from the group consisting of:

0.5-30 percent by weight of a block or statistical copolymer of ethylene oxide;

b) up to 10 percent by weight of a hydrophobic aliphatic or cycloalipbatic diol;

c) up to 10 percent by weight of hydrophobic homopolymeric polyalkylene glycols, wherein the alkylene group in said glycols contains more than 2 carbon atoms;

d) up to 40 percent by weight of polyethylene glycol with a molecular weight of from 2,000 to 40,000;

e) 0.2-2 percent by weight of triols;

f) up to 5 percent by weight of ion-forming diols; and

g) mixtures thereof.

9. The adhesive of claim 8 wherein said polyethylene glycol is partly replaced by at least one polyol selected from the group consisting of:

a) 0.7-20 percent by weight of a block or statistical copolymer of ethylene oxide;

b) up to 5 percent by weight of a hydrophobic aliphatic or cycloaliphatic diol;

c) 0.5-5 percent by weight of hydrophobic homopolymeric polyalkylene glycols, wherein the alkylene group in said glycols contains more than 2 carbon atoms;

d) up to 40 percent by weight of polyethylene glycol with a molecular weight of from 2,000 to 40,000;

e) 0.2-2 percent by weight of triols;

f) up to 5 percent by weight of ion-forming diols; and

g) mixtures thereof.

10. The adhesive of claim 9 wherein said polyethylene glycol is partly replaced by at least one polyol selected from the group consisting of;

a) 1-10 percent by weight of a block or statistical copolymer of ethylene oxide;

b) up to 5 percent by weight of a hydrophobic aliphatic or cycloaliphatic diol;

c) 0.5-5 percent by weight of hydrophobic homopolymeric polyalkylene glycols, wherein the alkylene group in said glycols contains more than 2 carbon atoms;

d) up to 40 percent by weight of polyethylene glycol with a molecular weight of from 2,000 to 40,000;

e) 0.2-2 percent by weight of triols;

f) up to 5 percent by weight of ion-forming diols; and

g) mixtures thereof.

11. The adhesive composition of claim 1 further comprising solubilizers, antioxidants, preservatives, and mixtures thereof.

12. An aqueous solution or dispersion comprising the composition of claim 1 and up to 98 percent by weight of water.

13. An aqueous solution or dispersion comprising the composition of claim 1 and 20-80 percent by weight of water.

14. An aqueous solution or dispersion comprising the composition of claim 1 and 30-70 percent by weight of water.

15. An aqueous adhesive system comprising:

a) 30 to 90 percent by weight of said polyurethane of claim 1;

b) 0 to 35 percent by weight of dispersion adhesives;

c) 0 to 10 percent by weight of solubilizers;

d) 0 to 10 percent by weight of viscosity controllers;

e) 0 to 5 percent by weight of filler; and

f) 0 to 0.5 percent by weight of preservative.

16. A hotmelt adhesive comprising:

a) 50 to 100 percent by weight of said polyurethane of claim 1;

b) 0 to 30 percent by weight of tackifiers; and

c) 0 to 30 percent by weight of waxes.

17. A process for the production of the adhesive of claim 1 comprising adding said polyisocyanate to the polyol in a melt at from 70 to 200°

C.

18. A process for labeling comprising applying a label to a surface using the adhesive composition of claim 1.

19. The process of claim 18 wherein said surface is a plastic surface.

20. A process for applying paper labels to bottles of polyolefins, comprising:

a) preparing an aqueous system comprising 50 percent by weight of the adhesive composition of claim 1;

b) applying said aqueous system to said paper label in a quantity of 100 g/ml;

c) pressing said moistened paper label onto the bottle while still moist (within 10 seconds) at temperatures of 10 to 40°

C.; and

d) drying said label at room temperature.

21. A process for bonding substrates comprising:

a) preparing a composition selected from the group consisting of an aqueous system, an organic solution or a melt comprising said adhesive of claim 1;

b) applying said composition to at least one of two substrates to be bonded;

c) drying or cooling said coated substrate; and

d) pressing said coated substrate together with the second substrate to be bonded.