Electrochemical gas sensor with gas communication means

• US 6,638,407 B1
• Filed: 09/13/2001
• Issued: 10/28/2003
• Est. Priority Date: 12/10/1998
• Status: Expired due to Fees

• Current Assignee: Kehoe Component Sales, Inc.
• Original Assignee: Senco Sensors Incorporated
• Inventors: Peng, Wenfeng
• Primary Examiner(s): TUNG, TA HSUNG
• Application Number:
  US09/952,227
• Time in Patent Office: 775 Days
• Field of Search: 204/412, 204/415, 204/431, 204/432
• US Class Current: 204/432
• CPC Class Codes: G01N 27/404 Cells with anode, cathode and cell electrolyte on the same side of a permeable membrane which separates them from the sample fluid , e.g. Clark-type oxygen sensors

Abstract

An electrochemical sensor having electrolyte, at least two electrodes and an electrolyte reservoir in a housing. The sensor has a hydrophobic gas communication means between said electrodes, electrolyte reservoir and ambient atmosphere. An electrochemical sensor having hydrophobic communication means mounted between electrodes and extending down to the electrolyte reservoir of the electrochemical sensor. Either embodiment of the sensor can provide oxygen for operation of the sensor and a balance of pressure, without interfering or poisonous gases.

Claims

1. An electrochemical gas sensor having an electrolyte matrix, a sensing electrode and a second electrode sandwiching the matrix, and an electrolyte reservoir, said electrolyte reservoir containing electrolyte, said electrodes and electrolyte being contained in a housing such that the sensing electrode is in gas communication with the atmosphere, said sensor having a hydrophobic gas communication channel connected to and extending continuously between the sensing electrode and inside the reservoir thereby facilitating equalization of pressure inside the reservoir with atmospheric pressure.

2. The electrochemical sensor of claim 1 in which the hydrophobic gas communication channel is in gas communication with the electrodes thereby providing for transmission of oxygen from the atmosphere to the electrodes.

3. The electrochemical sensor of claim 1 in which the matrix and the second electrode each comprise an orifice for flowthrough of electrolyte, and the gas communication channel extends through the matrix and second electrode orifices and is in gas communication with the reservoir, sensing electrode, electrolyte matrix and the second electrode.

4. An electrochemical gas sensor having hydrophobic gas communication means, said electrochemical sensor having a sensing electrode and a second electrode sandwiching an electrolyte matrix, and an electrolyte reservoir for containing electrolyte, said sensing electrode being in gas communication with the atmosphere, and said hydrophobic communication means being connected to and extending continuously between the sensing electrode and inside the reservoir thereby facilitating equalization of pressure inside the reservoir with atmospheric pressure.

5. The electrochemical sensor of claim 4 in which the hydrophobic gas communication means is in gas communication with the second electrode and thereby provides for oxygen to diffuse to the second electrode in the sensor and for balancing of air pressure between the inside and outside of the sensor.

6. The electrochemical sensor of claim 5 in which the reservoir is located beside the electrodes.

7. The electrochemical sensor of claim 5 in which the reservoir is physically separated from the electrodes.

8. The electrochemical sensor of claim 5 in which the gas communication means comprises a hydrophobic gas channel connected at one end to a hydrophobic portion of the sensing electrode and the other end to a hydrophobic portion of the second electrode, and a hydrophobic strip attached to the hydrophobic portion of the second electrode and extending into the reservoir.

9. The electrochemical sensor of claim 5 in which the gas communication means is dimensioned and configured so that gases that diffuse through the gas communication means come from the air that has passed the sensing electrode.

10. The electrochemical sensor of claim 5 further comprising a housing containing the electrodes, electrolyte matrix and gas communication means, the housing comprising a gas inlet that provides gas communication between the sensing electrode and the atmosphere and a gas filter mounted in the gas inlet.

11. The electrochemical sensor of claim 10 adapted so that diffusion of gas through the gas communication means is from air that has passed through the gas filter.

12. The sensor of claim 4 in which the second electrode is a counter electrode.

13. The sensor of claim 4 in which the second electrode is a reference electrode and the sensor further comprises a counter electrode and a second electrolyte matrix sandwiched between the reference electrode and the counter electrode.