Hardenable composition with a particular combination of characteristics

• US 6,638,567 B1
• Filed: 09/14/2001
• Issued: 10/28/2003
• Est. Priority Date: 03/16/1999
• Status: Expired due to Term

• Current Assignee: Huntsman Advanced Materials Americas, Inc.
• Original Assignee: Vantico Inc.
• Inventors: Beisele, Christian
• Primary Examiner(s): Dawson, Robert
• Assistant Examiner(s): AYLWARD, DAVID E
• Application Number:
  US09/936,706
• Time in Patent Office: 774 Days
• Field of Search: 523/457, 523/466, 528/409, 528/418, 427/116
• US Class Current: 427/116
• CPC Class Codes: C08G 59/04 of polyhydroxy compounds with epihalohydrins or precursors thereof
• CPC Class Codes: C08G 59/12 of polycarboxylic acids with epihalohydrins or precursors thereof
• CPC Class Codes: C08G 59/4215 cycloaliphatic
• CPC Class Codes: C08L 2666/04 Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
• CPC Class Codes: C08L 63/00 Compositions of epoxy resins; Compositions of derivatives of epoxy resins
• CPC Class Codes: H01B 3/40 epoxy resins

Abstract

A curable epoxy resin composition comprising

(a) a cycloaliphatic epoxy resin that is liquid at RT and, suspended therein, a core/shell polymer,

(b) a polycarboxylic anhydride and

(c) fillers,

wherein the composition is flame-retardant because two different fillers (c1) and (c2) are present, the nature of filler (c1) being such that, starting at RT, it is able to release water as the temperature rises, the total proportion of fillers (c1) and (c2) is from 58 to 73% by weight, based on the total amount of components (a), (b), (c1) and (c2), and the ratio by weight of the fillers (c1):(c2) is from 1:3 to 1:1, is suitable as a casting resin, especially in the impregnation of electrical coils and in the production of electrical components, such as air-cooled transformers, bushings, insulators, switches, sensors, converters and cable end seals.

Claims

1. A curable composition comprising:

(a) a cycloaliphatic epoxy resin that is liquid at room temperature and, suspended therein, a core/shell polymer;

(b) a polycarboxylic anhydride; and

(c) two different fillers, (c1) and (c2),

wherein (c1) is a filler that is able to release water as the temperature rises above room temperature;

(c2) is a reinforcing material;

the total proportion of fillers (c1) and (c2) is from 58 to 73% by weight based on the total amount of components (a), (b), (c1) and (c2) in the composition; and

the ratio by weight of the fillers (c1);

(c2) is in the range from 1;

3 to 1;

1.

2. A curable composition according to claim 1, wherein the total proportion of fillers (c1) and (c2) is from 62 to 68% by weight.

3. A curable composition according to claim 2, wherein the ratio by weight of the fillers (c1):

(c2) is in the range from 1;

2.3 to 1;

2.

4. A curable composition according to claim 2, wherein the ratio by weight of the fillers (c1):

(c2) is 1;

1.86.

5. A curable composition according to claim 2, wherein the ratio by weight of the fillers (c1):

(c2) is 1;

2.33.

6. A curable composition according to claim 1, wherein the cycloaliphatic epoxy resin is selected from the group consisting of

bis(4-hydroxycyclohexyl)methanediglycidyl ether, 2,2-bis(4-hydroxycyclehexyl)propanediglycidyl ether,

tetrahydrophthalic acid diglycidyl ester,

4-methyltetrahydrophthalic acid diglycidyl ester,

4-methylhexahydrophthalic acid diglycidyl ester, and

3,4-epoxycyclohexylmethyl 3′ ,4′

-epoxycyclohexanecarboxylate.

7. A curable composition according to claim 1, wherein the cycloaliphatic epoxy resin is hexahydrophthalic acid diglycidyl ester.

8. A curable composition according to claim 1, wherein the core/shell polymer is a solid core/shell polymer.

9. A curable composition according to claim 1, wherein the amount of core/shell polymer suspended in the epoxy resin is from 1 to 30% by weight based on the epoxy resin.

10. A curable composition according to claim 9, wherein the amount of core/shell polymer suspended in the epoxy resin is from 5 to 10% by weight based on the epoxy resin.

11. A curable composition according to claim 1, wherein the core/shell polymer is methylmethacrylate and polybutadiene latex in a 1:

1 ratio.

12. A curable composition according to claim 1, wherein filler (c2) is selected from the group consisting of quartz powder, silanised quartz powder, wollastonite, silanised wollastonite, and combinations thereof.

13. A curable composition according to claim 1, wherein filler (c1) is selected from the group consisting of untreated or thermally pretreated aluminum hydroxide, and silanised versions of the foregoing.

14. A crosslinked product obtained by curing a composition according to claim 1.

15. An improved method for the impregnation of electrical coils with a curable casting resin, wherein the improvement comprises the use of a curable composition according to claim 1 as the casting resin.

16. An improved method for the production of an electrical component utilizing a curable casting resin, wherein the improvement comprises the use of a curable composition according to claim 1 as the casting resin.

17. The improved method of claim 16, wherein the electrical component is selected from the group consisting of air-cooled transformers, bushings, insulators, switches, sensors, converters, and cable end seals.