Colored antimicrobial vulcanized rubber articles

• US 6,638,993 B2
• Filed: 12/12/2001
• Issued: 10/28/2003
• Est. Priority Date: 12/12/2001
• Status: Active Grant

• Current Assignee: Milliken & Company
• Original Assignee: Milliken & Company
• Inventors: Haas, Geoffrey, Patel, Bhawan, Morris, David L., Burke, William O. III
• Primary Examiner(s): MEDLEY, MARGARET B
• Application Number:
  US10/015,878
• Publication Number:
  US 20030119937A1
• Time in Patent Office: 685 Days
• Field of Search: 523/122, 523/86, 524/287, 524/403, 524/492, 524/297, 524/398, 524/450
• US Class Current: 523/122
• CPC Class Codes: C08K 3/015 Biocides macromolecular substances as carriers for biocide material A01N25/10
• CPC Class Codes: C08K 3/34 Silicon-containing compounds
• CPC Class Codes: C08K 5/0058 Biocides; macromolecular substances as carriers for biocide material A01N25/10
• CPC Class Codes: C08L 21/00 Compositions of unspecified rubbers
• CPC Class Codes: C08L 23/16 Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers

Abstract

Certain non-silicone vulcanized rubber articles made from at least a majority by weight of ethylene-propylene-diene modified (terpolymer) rubber (such as, without limitation, EPDM and/or NBR) that include silver-based compounds to provide highly desirable long-term antimicrobial characteristics within the cured rubber articles, at least a portion of which exhibits a color other than black, are provided. Such articles are in either solid or blown (foam or sponge) state (or combinations of both in multilayered forms, either all colored or individual layers colored) that can be utilized in a variety of different applications. As silver-based compounds are deleteriously affected by utilization of standard curing agents and curing accelerators, such as sulfur-based compounds and/or systems, the ability to provide such an effective antimicrobial vulcanized rubber article is rather difficult. However, this invention encompasses the presence of different non-sulfur-based curing systems and agents, such as peroxides, as one example, that permit vulcanization and do not irreversibly bind silver ions thereto, thereby resulting in long-term antimicrobial performance of the ultimate rubber article itself. The rubber articles must also comprise fillers and may also include plasticizers to provide desired characteristics of dimensional stability, stiffness, flexural modulus, tensile strength, abrasion resistance, elongation, and the like, for the ultimate rubber article, while simultaneously and surprisingly both enhancing the control of antimicrobial efficacy of the rubber article and not deleteriously binding to the available silver to permit coloring of the target rubber as well.

Claims

1. A dimensionally stable colored vulcanized rubber article comprising a majority of at least one non-silicone rubber constituent, and further comprising at least one silver-based antimicrobial agent, and at least one non-discoloring silver-ion control release additive selected from the group consisting of fillers, oils, and mixtures thereof, wherein no black coloring agents are present therein, and wherein said colored rubber article exhibits a minimum of 0.075 μ

g/dm² of surface available silver.

2. The rubber article of claim 1 wherein said silver-based antimicrobial compound is selected from the group consisting of elemental silver, silver oxides, silver salts, silver ion exchange compounds, silver zeolites, silver glasses, and any mixtures thereof.

6. The rubber article of claim 1 wherein said at east one silver ion control release additive is a hydrophilic filler selected from the group consisting of metal silicates, metal stearates, metal oxides, metal carbonates, clays, silica treated with silane oil, and any mixtures thereof.

9. The rubber article of claim 1 wherein said rubber constituent is selected from the group consisting of EPDM, NBR, and any mixtures thereof.

3. A dimensionally stable colored vulcanized rubber article comprising a majority of at least one non-silicone rubber constituent, and further comprising an effective surface availability of silver ions of at least one silver-based antimicrobial agent, and at least one non-discoloring silver-ion control release additive selected from the group consisting of fillers, oils, and mixtures thereof, wherein no black coloring agents are present therein.

4. The rubber article of claim 3 wherein said silver-based antimicrobial compound is selected from the group consisting of elemental silver, silver oxides, silver salts, silver ion exchange compounds, silver zeolites, silver glasses, and any mixtures thereof.

5. The rubber article of claim 3 wherein said at least one silver ion control release additive is a hydrophilic filler selected from the group consisting of metal silicates, metal stearates, metal oxides, metal carbonates, clays, silica treated with silane oil, and any mixtures thereof.

7. The rubber article of claim 3 wherein said rubber constituent is selected from the group consisting of EPDM, NBR, and any mixtures thereof.

8. A method of producing a colored rubber article exhibiting a minimum surface availability of silver ions of 0.075 μ

g/dm², comprising the steps of

a) compounding together an unvulcanized rubber formulation comprising at least one rubber constituent, the majority of which must be a non-silicone rubber, at least one silver-based antimicrobial compound, at least coloring agent, at least one filler component, and at least one curing compound, wherein no black coloring agents are present, and wherein said curing compound present within said formulation does not include an appreciable amount of sulfur-based compounds,

b) molding said rubber formulation into a preselected shape, and

c) vulcanizing said rubber formulation under high pressure and exposure to high temperature.

10. The method of claim 8 wherein said rubber constituent is selected from the group consisting of EPDM, NBR, and any mixtures thereof.

11. The method of claim 8 wherein said silver-based antimicrobial compound is selected from the group consisting of elemental silver, silver oxides, silver salts, silver ion exchange compounds, silver zeolites, silver glasses, and any mixtures thereof.

12. The method of claim 11 wherein said at least one filler component simultaneously functions as a silver ion control release additive.

13. The method of claim 12 wherein said at least one filler/silver ion control release additive is selected from the group consisting of fillers, oils, and mixtures thereof.

14. The method of claim 13 wherein said at least one filler/silver ion control release additive is a hydrophilic filler selected from the group consisting of metal silicates, metal stearates, metal oxides, metal carbonates, clays, silica treated with silane oil, and any mixtures thereof.