Manufacturing method for white light source

• US 6,641,448 B2
• Filed: 11/13/2001
• Issued: 11/04/2003
• Est. Priority Date: 11/09/2001
• Status: Expired due to Term

• Current Assignee: Lite-On Technology Corporation
• Original Assignee: Lite-On Technology Corporation
• Inventors: Su, Hung-Yuan, Wang, Chien-Yuan, Liu, Ru-Shi, Hsing Chen, Chen-Lun
• Primary Examiner(s): Dinkins, Anthony
• Assistant Examiner(s): Estrada, Angel R.
• Application Number:
  US09/986,846
• Publication Number:
  US 20030092345A1
• Time in Patent Office: 721 Days
• Field of Search: 445/23, 445/24, 445/25, 313/485, 313/486, 313/487, 252/301.4 R, 252/301.6 P, 252/301.4 P, 257/88, 257/89, 257/79
• US Class Current: 445/23
• CPC Class Codes: C09K 11/574 with zinc or cadmium
• CPC Class Codes: C09K 11/72 also containing halogen, e.g. halophosphates
• CPC Class Codes: C09K 11/7734 Aluminates
• CPC Class Codes: C09K 11/7774 Aluminates
• CPC Class Codes: H01L 33/502 Wavelength conversion materials
• CPC Class Codes: H01L 33/504 Elements with two or more wavelength conversion materials
• CPC Class Codes: H05B 33/14 characterised by the chemical or physical composition or the arrangement of the electroluminescent material , or by the simultaneous addition of the electroluminescent material in or onto the light source
• CPC Class Codes: Y02B 20/00 Energy efficient lighting technologies, e.g. halogen lamps or gas discharge lamps

Abstract

A manufacturing method for white light source utilizes an ultraviolet light source and suitable phosphors. One of the phosphors is directly excited by the ultraviolet light source and generates a radiation with longer wavelength. Other phosphors are excited by the radiation with longer wavelength and generate radiation with much longer wavelength. The lights generated by those phosphors are mixed to form a white light.

Claims

1. A method for manufacturing a white light source, the method comprising the steps of:

(a) synthesizing a first phosphor powder and a second phosphor powder;

(b) mixing the first phosphor powder and the second phosphor powder according to a mixing ratio into a phosphor mixture, the mixing ratio determined by the steps of;

(1) measuring at a first reference wavelength an emission response of the first phosphor powder to a plurality of excitation wavelengths within a first band of excitation wavelengths;

(2) selecting a first excitation wavelength from the first band of excitation wavelengths based upon the emission response measured in step (1);

(3) measuring a spectral response of the first phosphor powder to the first excitation wavelength over a first band of emission wavelengths, the first band of emission wavelengths including a first emission wavelength;

(4) indicating on a chromaticity chart a first color corresponding to the first emission wavelength;

(5) measuring at a second reference wavelength an emission response of the second phosphor powder to a plurality of excitation wavelengths within a second band of excitation wavelengths;

(6) selecting a second excitation wavelength from the second band of excitation wavelengths based upon the emission response measured in step (5);

(7) measuring a spectral response of the second phosphor powder to the second excitation wavelength over a second band of emission wavelengths, the second band of emission wavelengths including a second emission wavelength;

(8) indicating on a chromaticity chart a second color corresponding to the second emission wavelength;

(9) drawing a line on the chromaticity chart from the indication of the first color to the indication of the second color; and

(10) determining the mixing ratio of the first phosphor powder and the second phosphor powder such that an emitted color thereof lies on a line on the chromaticity chart in a region of white light;

(c) providing a light source of the first excitation wavelength; and

(d) applying the phosphor mixture to the light source.

2. The method of manufacturing a white light source as recited in claim 1, wherein the first excitation wavelength is ultraviolet.

3. The method of manufacturing a white light source as recited in claim 1, wherein the first emission wavelength of the first phosphor powder corresponds to the second excitation wavelength of the second phosphor powder.

4. The method of manufacturing a white light source as recited in claim 1, wherein the first reference wavelength corresponds to the first color and the second reference wavelength corresponds to the second color.

5. The method of manufacturing a white light source as recited in claim 1, wherein the mixing ratio determination of step (10) includes the steps of:

(i) mixing the first phosphor powder and the second phosphor powder into a plurality of phosphor test mixtures according to a corresponding plurality of predetermined mixing ratios;

(ii) indicating on the chromaticity chart a color temperature corresponding to light emitted by each of the phosphor test mixtures when excited by the first excitation wavelength; and

(iii) interpolating between indications of color temperature corresponding to the light emitted by each of the phosphor test mixtures on each side of the region of white light to establish the mixing ratio of the first phosphor powder and the second phosphor powder.

6. The method for manufacturing a white light source as recited in claim 1, wherein the light source is one of an LED, an electronic beam and plasma.

7. The method for manufacturing a white light source as recited in claim 1, wherein the first color is blue and the second color is yellow.

8. The method for manufacturing a white light source as recited in claim 7, wherein the first phosphor powder is selected from a group consisting of BaMgAl₁₀O₁₇:

Eu;

ZnS;

Ag; and

(Sr, Ca, Ba, Mg)₁₀(PO₄)₆Cl₂;

Eu; and

the second phosphor powder is selected from a group consisting of Y₃Al₅O₁₂;

Ce, Gd;

ZnS;

Mn; and

3Cd₃(PO₄)₂CdCl₂;

Mn.

9. The method for manufacturing a white light source as recited in claim 1, wherein the first phosphor powder and the second phosphor powder are made by one of a solid-state reaction and chemosynthesis method.

10. The method for manufacturing a white light source as recited in claim 1, wherein the light source applied with the phosphor mixture is packaged in one of the forms including lamp, surface mount device and chip on board.