System and method for removal of fluoride from wastewater using single fluoride sensing electrode

• US 6,645,385 B2
• Filed: 09/21/2001
• Issued: 11/11/2003
• Est. Priority Date: 09/26/2000
• Status: Expired due to Fees

• Current Assignee: Ionics Incorporated (Veolia Environnement SA)
• Original Assignee: Ionics Incorporated (Veolia Environnement SA)
• Inventors: Hannan, William, Krulik, Gerald A., Sverdlov, Gennadiy
• Primary Examiner(s): DRODGE, JOSEPH W
• Application Number:
  US09/960,614
• Publication Number:
  US 20020117456A1
• Time in Patent Office: 781 Days
• Field of Search: 210/85, 210/96.1, 210/103, 210/198.1, 210/199, 210/202, 210/205, 210/709, 210/719, 210/739, 210/743, 210/749, 210/754, 210/755, 210/752, 210/259, 210/806, 210/915, 422/62, 422/105, 422/108, 422/111, 436/124, 436/125, 204/416, 204/419, 204/420
• US Class Current: 210/709
• CPC Class Codes: C02F 1/001 Processes for the treatment of water whereby the filtration technique is of importance C02F1/44 takes precedence; construction of filters in general B01D24/00 - B01D41/00
• CPC Class Codes: C02F 1/5245 using basic salts, e.g. of aluminium and iron
• CPC Class Codes: C02F 1/66 by neutralisation; pH adjustment for degassing C02F1/20; using ion-exchange C02F1/42; for flocculation or precipitation of suspended impurities C02F1/52; for removing dissolved compounds C02F1/58
• CPC Class Codes: C02F 2101/14 Fluorine or fluorine-containing compounds
• CPC Class Codes: C02F 2209/001 Upstream control, i.e. monitoring for predictive control
• CPC Class Codes: C02F 2209/003 Downstream control, i.e. outlet monitoring, e.g. to check the treating agents, such as halogens or ozone, leaving the process
• CPC Class Codes: C02F 2209/06 pH
• CPC Class Codes: Y10S 210/915 Fluorine containing

Abstract

A system for removing fluoride from wastewater is provided. The system comprises a reaction tank for processing said wastewater by adding calcium salts, a filtration tank for removing the precipitated fluoride formed in the reaction tank, a single fluoride electrode disposed at the reaction tank for measuring a concentration of fluoride in the influent wastewater and providing an output signal, and a programmable controller for controlling addition of said calcium salts into said reaction tank. The programmable controller defines a setpoint of fluoride concentration in the reaction tank and automatically controls addition of calcium salts based on the setpoint and the output signal provided by the single fluoride electrode. A method of removing fluoride from wastewater is also provided.

Claims

1. A system for removing fluoride from a flouride bearing industrial wastewater, comprising:

a reaction tank for processing said wastewater, said reaction tank including a first input for feeding said wastewater into said reaction tank, and a second input for adding calcium salts to said reaction tank to form precipitated fluoride;

a filtration tank for removing said precipitated fluoride from said wastewater, said filtration tank including an output for discharging filtered wastewater;

a single fluoride electrode disposed at said first input of said reaction tank, said single fluoride electrode measuring a concentration of fluoride in said wastewater fed into said reaction tank and providing an output signal; and

a programmable controller for controlling addition of said calcium salts into said reaction tank responsive to said output signal provided by said single fluoride electrode so as to provide a treated output stream of desired quality.

2. The system of claim 1 wherein said programmable controller defines a setpoint of fluoride concentration in said reaction tank and automatically controls addition of calcium salts based on said setpoint defined by said controller and said output signal from said single fluoride electrode.

3. The system of claim 1 wherein said fluoride electrode is self-cleaning fluoride electrode.

4. The system of claim 1 wherein said reaction tank further comprises a pH sensor and a third input for adding an acid or a basic solution to said tank, said pH sensor measuring pH of said wastewater and providing an output signal to said controller.

5. The system of claim 4 wherein said pH sensor is selected from a group consisting of antimony electrodes and fluoride resistant glass pH electrodes.

6. The system of claim 4 wherein said programmable controller defines a pH setpoint in said reaction tank and automatically controls addition of said acid or basic solution based on said setpoint defined by said controller and said output signal provided by said pH sensor.

7. The system of claim 1 wherein said reaction tank comprises at least a first, second, and third tank in series, each tank being provided with a pH sensor for measuring pH in said each tank.

8. The system of claim 7 wherein said first tank is added from stoichiometric to 125% stoichiometric of calcium salts, and said second and third tanks are added from 5 to 25% of amount added to said first tank.

9. A method of removing fluoride from a fluoride bearing industrial wastewater, comprising:

defining a setpoint of concentration of fluoride using a programmable controller;

measuring a concentration of fluoride in said wastewater using a single fluoride electrode;

automatically adding calcium salts to said wastewater in an amount based on said setpoint defined by said controller and said concentration of fluoride measured by said single fluoride electrode so as to provide a treated output stream of desired quality.

10. The method of claim 9 wherein said calcium is added in an amount of from stoichiometric to 125 percent of stoichiometric.

11. The method of claim 9 further comprises defining a pH setpoint using a controller and measuring a pH of said wastewater using a pH sensor, and automatically adding an acid or a basic solution to said wastewater in an amount based on said setpoint defined by said controller and said pH measured by said pH sensor.

12. The method of claim 11 wherein said pH setpoint is defined at a value in a range from 6 to 9.

13. The method of claim 9 further comprises adding a coagulant and/or flocculant to said wastewater.

14. The method of claim 9 wherein said concentration of fluoride in said wastewater fed into said reaction tank is continuously varied.

15. The method of claim 14 wherein said concentration of fluoride in said wastewater fed into said reaction tank is in a range from 50 to 10,000 ppm.

16. The method of claim 9 further comprises monitoring a concentration of fluoride in discharging wastewater using a single fluoride electrode, and said concentration of fluoride monitored being in a range from 2 to 10 ppm.

17. A system for removing fluoride from a fluoride bearing industrial wastewater, comprising:

a reaction tank for processing said wastewater, said reaction tank including a first input for feeding said wastewater into said reaction tank, and a second input for adding calcium salts to said reaction tank to form precipitated fluoride;

a filtration tank for removing said precipitated fluoride from said wastewater, said filtration tank including an output for discharging filtered wastewater;

a first single fluoride electrode disposed at said first input of said reaction tank, said first single fluoride electrode measuring a concentration of fluoride in said wastewater fed into said reaction tank and providing an output signal;

a second single fluoride electrode disposed at said output of said filtration tank, said second single fluoride electrode monitoring a concentration of fluoride in said filtered wastewater and providing an output signal; and

a programmable controller for controlling addition of said calcium salts into said reaction tank responsive to said output signal provided by said first and second fluoride electrode so as to provide a treated output stream of desired quality.

18. The system of claim 17 wherein said programmable controller defines a setpoint of fluoride concentration in said reaction tank and automatically controls addition of calcium salts based on said setpoint defined by said controller and said output signal provided by said first and second fluoride electrode.

19. The system of claim 17 wherein said reaction tank further comprises a pH sensor and a third input for adding an acid or a basic solution to said tank, said pH sensor measuring pH of said wastewater fed into said reaction tank and providing an output signal to said controller, and said controller defining a pH setpoint in said reaction tank and automatically controlling addition of said acid or basic solution based on said setpoint and said output signal provided by said pH sensor.