Thin film solid oxide fuel cell and method for forming

• US 6,645,656 B1
• Filed: 03/24/2000
• Issued: 11/11/2003
• Est. Priority Date: 03/24/2000
• Status: Expired due to Term

• Current Assignee: University of Houston Law Center (University of Houston System)
• Original Assignee: University of Houston (University of Houston System)
• Inventors: Chen, Xin, Ignatiev, Alex, Wu, Naijuan
• Primary Examiner(s): Chaney, Carol
• Assistant Examiner(s): YUAN, DAH WEI D
• Application Number:
  US09/534,385
• Time in Patent Office: 1,327 Days
• Field of Search: 429/30, 429/32, 429/33
• US Class Current: 429/485
• CPC Class Codes: H01M 2008/1293 Fuel cells with solid oxide electrolytes
• CPC Class Codes: H01M 8/1253 the electrolyte containing zirconium oxide
• CPC Class Codes: H01M 8/1286 Fuel cells applied on a support, e.g. miniature fuel cells deposited on silica supports
• CPC Class Codes: Y02E 60/50 Fuel cells
• CPC Class Codes: Y02P 70/50 Manufacturing or production processes characterised by the final manufactured product

Abstract

A thin film solid oxide fuel cell (TFSOFC) having a porous metallic anode and a porous cathode is provided. The fuel cell is formed by using a continuous metal foil as a substrate to epitaxially deposit a thin film electrolyte on one surface of the foil. The metal foil may then be made porous by photolithographically patterning and etching the other surface of the foil to form holes extending through the foil to the electrolyte/foil interface. The cathode is then formed on the electrolyte by depositing a second thin film using known film deposition techniques. Further processing may be used to increase the porosity of the electrodes. The metal foil may be treated before film deposition to have an atomically ordered surface, which makes possible an atomically ordered thin film electrolyte.

Claims

1. A solid oxide fuel cell, comprising:

an anode film, the anode film being a metal foil having a first and second side, wherein the second side of the metal foil has an atomically ordered surface, the metal foil being made porous from a plurality of holes entering from the first side of the foil and extending to the second side;

an electrolyte film having a first and second side and plane, the first side of the electrolyte film being deposited on the second side of the metal foil; and

a cathode film, the cathode film being deposited on the second side of the electrolyte film.

2. The solid oxide fuel cell of claim 1 further comprising:

a mixed ionic and electron conductive film between be electrolyte film and the cathode film wherein the mixed ionic and electron conductive film is comprised of doped cerium oxide.

3. The fuel cell of claim 1 wherein the electrolyte film is comprised of a solid oxide selected from the group of solid oxides consisting of doped LaGaO₃ and doped CeO₂.

4. The fuel cell of claim 1 wherein the electrolyte film is atomically ordered.

5. The fuel cell of claim 1 wherein the second side of the metal foil has an atomically ordered surface and the electrolyte film is atomically ordered normal to the plane and in the plane of the electrolyte film.

6. The fuel cell of claim 1 wherein the electrolyte film is atomically ordered and the cathode film is atomically ordered.

7. The fuel cell of claim 1 wherein the porosity of the cathode film is at least partially made up of a columnar structure formed when the cathode film is deposited at a lower temperature and subsequently heated to a higher temperature.

8. A stack of fuel cells, comprised of at least two fuel cells of claim 1 interconnected by an electrically conducting material stable to oxidizing and reducing conditions between the fuel cells wherein the electrically conducting material is LaCrO₃.

9. A stack of fuel cells comprised of at least two fuel cells of claim 1 interconnected by an electrically conducting material stable to oxidizing and reducing conditions between the fuel cells wherein the fuel cells have a tubular shape.