Efficient cell stack for cells with double current collectors sandwich cathodes

• US 6,645,670 B2
• Filed: 04/30/2001
• Issued: 11/11/2003
• Est. Priority Date: 05/16/2000
• Status: Expired due to Term

• Current Assignee: Greatbatch Limited (Greatbatch Incorporated)
• Original Assignee: Wilson Greatbatch Technologies, Inc.
• Inventors: Gan, Hong
• Primary Examiner(s): WEINER, LAURA S
• Application Number:
  US09/845,875
• Publication Number:
  US 20010049032A1
• Time in Patent Office: 925 Days
• Field of Search: 429/209, 429/231.7, 429/219, 429/221, 429/220, 429/224, 429/231.5, 429/231.1, 429/233, 429/245, 429/330, 429/333, 429/335, 429/322, 429/323, 296/231
• US Class Current: 429/209
• CPC Class Codes: A61N 1/378 Electrical supply
• CPC Class Codes: H01M 10/0431 Cells with wound or folded electrodes H01M10/045 takes precedence
• CPC Class Codes: H01M 10/052 Li-accumulators
• CPC Class Codes: H01M 10/0563 Liquid materials, e.g. for Li-SOCl2 cells
• CPC Class Codes: H01M 10/0568 characterised by the solutes
• CPC Class Codes: H01M 10/0569 characterised by the solvents
• CPC Class Codes: H01M 10/0585 of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
• CPC Class Codes: H01M 10/286 Cells or batteries with wound or folded electrodes
• CPC Class Codes: H01M 4/0404 by coating on electrode collectors
• CPC Class Codes: H01M 4/0435 Rolling or calendering
• CPC Class Codes: H01M 4/24 Electrodes for alkaline accumulators
• CPC Class Codes: H01M 4/30 Pressing
• CPC Class Codes: H01M 4/366 as layered products
• CPC Class Codes: H01M 4/5825 Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
• CPC Class Codes: H01M 4/583 Carbonaceous material, e.g. graphite-intercalation compounds or CFx
• CPC Class Codes: H01M 4/5835 Comprising fluorine or fluoride salts
• CPC Class Codes: H01M 4/667 in the form of layers, e.g. coatings
• CPC Class Codes: H01M 6/10 with wound or folded electrodes
• CPC Class Codes: Y10T 29/49108 Electric battery cell making

Abstract

The present invention improves the performance of lithium electrochemical cells by providing a new electrode assembly based on a sandwich cathode design, but termed a double screen sandwich cathode electrode design. In particular, the present invention uses sandwich cathode electrodes which are, in turn, sandwiched between two half double screen sandwich cathode electrodes, either in a prismatic plate or serpentine-like electrode assembly. In a jellyroll electrode assembly, the cell is provided in a case-positive design and the outside round of the electrode assembly is a half double screen sandwich cathode electrode.

Claims

1. An electrochemical cell, which comprises:

a) a first cathode structure of a first cathode active material of a first energy density and a first rate capability sandwiched between first and second cathode current collectors, and a second cathode active material of a second energy density and a second rate capability contacted to the first and second cathode current collectors opposite the first cathode active material, wherein the first energy density of the first cathode active material is greater than the second energy density while the first rate capability is less than the second rate capability of the second cathode active material;

b) a first anode structure of an alkali metal contacted to opposite sides of a first anode current collector, wherein the first anode structure is in electrical association with the second cathode active material contacting the first cathode current collector;

c) a second cathode structure having a third cathode active material of a third energy density and a third rate capability contacted to one side of a third cathode current collector, and a fourth cathode active material of a fourth energy density and a fourth rate capability contacted to the other side of the third cathode current collector, wherein the third energy density of the third cathode active material is greater than the fourth energy density while the third rate capability is less than the fourth rate capability of the fourth cathode active material and wherein the fourth cathode active material is in electrical association with the first anode structure opposite the second cathode active material contacting the first cathode current collector; and

d) a nonaqueous electrolyte activating the first anode structure and the first and second cathode structures.

2. The electrochemical cell of claim 1 wherein the first and third cathode active materials are selected from the group consisting of CF_x, Ag₂O, Ag₂O₂, CuF, Ag₂CrO₄, MnO₂, silver vanadium oxide, and mixtures thereof, and wherein MnO₂ and silver vanadium oxide are only one of the first and third cathode active materials when the second and fourth cathode active materials are not MnO₂ or silver vanadium oxide and are of a lesser energy density and a greater rate capability than MnO₂ or silver vanadium oxide.

3. The electrochemical cell of claim 1 wherein the second and fourth cathode active materials are selected from the group consisting of silver vanadium oxide, copper silver vanadium oxide, V₂O₅, MnO₂, LiCoO₂, LiNiO₂, LiMnO₂, CuO, TiS, CuS, FeS, FeS₂, copper oxide, copper vanadium oxide, and mixtures thereof.

4. The electrochemical cell of claim 1 wherein the first and third cathode active materials are CF_x and the second and fourth cathode active materials are silver vanadium oxide.

5. The electrochemical cell of claim 1 wherein the first cathode structure has the configuration:

silver vanadium oxide/first cathode current collector/CF_x/second cathode current collector/silver vanadium oxide.

6. The electrochemical cell of claim 1 wherein the second cathode structure has the configuration:

CF_x/third cathode current collector/silver vanadium oxide.

7. The electrochemical cell of claim 1 further including a second anode structure of the alkali metal contacted to opposite sides of a second anode current collector, wherein the second anode structure is in electrical association with the second cathode active material contacting the second cathode current collector.

8. The electrochemical cell of claim 7 further including a third cathode structure of a fifth cathode active material of a fifth energy density and a fifth rate capability contacted to one side of a fourth cathode current collector, and a sixth cathode active material of a sixth energy density and a sixth rate capability contacted to the other side of the fourth cathode current collector, wherein the fifth energy density of the fifth cathode active material is greater than the sixth energy density while the fifth rate capability is less than the sixth rate capability of the sixth cathode active material and wherein the sixth cathode active material is in electrical association with the second anode structure opposite the second cathode active material contacting the second cathode current collector.

9. The electrochemical cell of claim 8 wherein the first, third and fifth cathode active materials are selected from the group consisting of CF_x, Ag₂O, Ag₂O₂, CuF, Ag₂CrO₄, MnO₂, silver vanadium oxide, and mixtures thereof, and wherein MnO₂ and silver vanadium oxide are only one of the first and third cathode active materials when the second and fourth cathode active materials are not MnO₂ or silver vanadium oxide and are of are of a lesser energy density and a greater rate capability than MnO₂ or silver vanadium oxide.

10. The electrochemical cell of claim 8 wherein the second, fourth and sixth cathode active materials are selected from the group consisting of silver vanadium oxide, copper silver vanadium oxide, V₂O₅, MnO₂, LiCoO₂, LiNiO₂, LiMnO₂, CuO, TiS, CuS, FeS, FeS₂, copper oxide, copper vanadium oxide, and mixtures thereof.

11. The electrochemical cell of claim 8 wherein the first, third and fifth cathode active materials are CF_x and the second, fourth and sixth cathode active materials are silver vanadium oxide.

12. The electrochemical cell of claim 8 wherein the second and third cathode structures have the configuration:

CF_x/cathode current collector/silver vanadium oxide.

13. The electrochemical cell of claim 1 wherein the first cathode structure has the configuration:

silver vanadium oxide/first cathode current collector/silver vanadium oxide/CF_x/silver vanadium oxide/second cathode current collector/silver vanadium oxide.

14. The electrochemical cell of claim 1 wherein the first, second and third cathode current collectors are selected from the group consisting of stainless steel, titanium, tantalum, platinum, gold, aluminum, cobalt nickel alloys, nickel-containing alloys, highly alloyed ferritic stainless steel containing molybdenum and chromium, and nickel-, chromium-, and molybdenum-containing alloys.

15. The electrochemical cell of claim 1 wherein the first, second and third cathode current collectors are titanium having a coating selected from the group consisting of graphite/carbon material, iridium, iridium oxide and platinum provided thereon.

16. The electrochemical cell of claim 1 wherein the first anode structure is of lithium, the first and third cathode active materials are CF_x, the second and fourth cathode active materials are silver vanadium oxide and the first, second and third cathode current collectors are titanium.

17. The electrochemical cell of claim 1 wherein the electrolyte has a first solvent selected from an ester, a linear ether, a cyclic ether, a dialkyl carbonate, and mixtures thereof, and a second solvent selected from a cyclic carbonate, a cyclic ester, a cyclic amide, and mixtures thereof.

18. The electrochemical cell of claim 17 wherein the first solvent is selected from the group consisting of tetrahydrofuran, methyl acetate, diglyme, trigylme, tetragylme, dimethyl carbonate, 1,2-dimethoxyethane, 1,2-diethoxyethane, 1-ethoxy, 2-methoxyethane, ethyl methyl carbonate, methyl propyl carbonate, ethyl propyl carbonate, diethyl carbonate, dipropyl carbonate, and mixtures thereof, and the second solvent is selected from the group consisting of propylene carbonate, ethylene carbonate, butylene carbonate, acetonitrile, dimethyl sulfoxide, dimethyl formamide, dimethyl acetamide, γ

-valerolactone, γ

-butyrolactone, N-methyl-pyrrolidinone, and mixtures thereof.

19. The electrochemical cell of claim 1 wherein the electrolyte includes a lithium salt selected from the group consisting of LiPF₆, LiBF₄, LiAsF₆, LiSbF₆, LiClO₄, LiO₂, LiAlCl₄, LiGaCl₄, LiC(SO₂CF₃)₃, LiN(SO₂CF₃)₂, LiSCN, LiO₃SCF₃, LiC₆F₅SO₃, LiO₂CCF₃, LiSO₆F, LiB(C₆H₅)₄, LiCF₃SO₃, and mixtures thereof.

20. The electrochemical cell of claim 17 wherein the electrolyte is 0.8M to 1.5M LiAsF₆ or LiPF₆ dissolved in a 50:

50 mixture, by volume, of propylene carbonate as the first solvent and 1,2-dimethoxyethane as the second solvent.

21. The electrochemical cell of claim 1 wherein the first anode structure is of lithium and the second cathode structure has the configuration:

silver vanadium oxide/third cathode current collector/Ag₂O, with the silver vanadium oxide facing the anode.

22. An electrochemical cell, which comprises:

a) a first cathode structure of a first cathode active material of a first energy density and a first rate capability sandwiched between first and second cathode current collectors, and a second cathode active material of a second energy density and a second rate capability contacted to the first and second cathode current collectors opposite the first cathode active material, wherein the first energy density of the first cathode active material is greater than the second energy density while the first rate capability is less than the second rate capability of the second cathode active material;

b) a first anode structure of an alkali metal contacted to opposite sides of a first anode current collector, wherein the first anode structure is in electrical association with the second cathode active material contacting the first cathode current collector;

c) a second cathode structure of a third cathode active material of a third energy density and a third rate capability contacted to one side of a third cathode current collector, and a fourth cathode active material of a fourth energy density and a fourth rate capability contacted to the other side of the third cathode current collector, wherein the third energy density of the third cathode active material is greater than the fourth energy density while the third rate capability is less than the fourth rate capability of the fourth cathode active material and wherein the fourth cathode active material is in electrical association with the first anode structure opposite the second cathode active material contacting the first cathode current collector;

d) a second anode structure of the alkali metal contacted to opposite sides of a second anode current collector, wherein the second anode structure is in electrical association with the second cathode active material contacting the second cathode current collector;

e) a third cathode structure having a fifth cathode active material of a fifth energy density and a fifth rate capability contacted to one side of a fourth cathode current collector, and a sixth cathode active material of a sixth energy density and a sixth rate capability contacted to the other side of the fourth cathode current collector, wherein the fifth energy density of the fifth cathode active material is greater than the sixth energy density while the fifth rate capability is less than the sixth rate capability of the sixth cathode active material and wherein the sixth cathode active material is in electrical association with the second anode structure opposite the second cathode active material contacting the second cathode current collector; and

f) a nonaqueous electrolyte activating the first and second anode structures and the first, second and third cathode structures.

23. The electrochernical cell of claim 22 wherein the first, third and fifth cathode active materials are selected from the group consisting of CF_x, Ag₂O, Ag₂O₂, CuF, Ag₂CrO₄, MnO₂, silver vanadium oxide, and mixtures thereof, wherein MnO₂ and silver vanadium oxide are only one of the first, third and fifth cathode active materials when the second and fourth cathode active materials are not MnO₂ or silver vanadium oxide and are of a lesser energy density and a greater rate capability than MnO₂ or silver vanadium oxide.

24. The electrochemical cell of claim 22 wherein the second, fourth and sixth cathode active materials are selected from the group consisting of silver vanadium oxide, copper silver vanadium oxide, V₂O₅, MnO₂, LiCoO₂, LiNiO₂, LiMnO₂, CuO, TiS, CuS, FeS, FeS₂, copper oxide, copper vanadium oxide, and mixtures thereof.

25. A method for powering an implantable medical device, comprising the steps of:

a) providing the medical device;

b) providing an electrochemical cell, comprising the steps of;

i) providing a first cathode structure of a first cathode active material of a first energy density and a first rate capability sandwiched between first and second cathode current collectors, and a second cathode active material of a second energy density and a second rate capability contacted to the first and second cathode current collectors opposite the first cathode active material, wherein the first energy density of the first cathode active material is greater than the second energy density while the first rate capability is less than the second rate capability of the second cathode active material;

ii) providing a first anode structure of an alkali metal contacted to opposite sides of a first anode current collector, wherein the first anode structure is in electrical association with the second cathode active material contacting the first cathode current collector;

iii) providing a second cathode structure of a third cathode active material of a third energy density and a third rate capability contacted to one side of a third cathode current collector, and providing a fourth cathode active material of a fourth energy density and a fourth rate capability contacted to the other side of the third cathode current collector, wherein the third energy density of the third cathode active material is greater than the fourth energy density while the third rate capability is less than the fourth rate capability of the fourth cathode active material and wherein the fourth cathode active material is in electrical association with the first anode structure opposite the second cathode active material contacting the first cathode current collector; and

iv) activating the first anode structure and the first and second cathode structures with a nonaqueous electrolyte; and

c) electrically connecting the electrochemical cell to the medical device.

26. The method of claim 25 including selecting the first and third cathode active materials from the group consisting of CF_x, Ag₂O, Ag₂O₂, CuF, Ag₂CrO₄, MnO₂, silver vanadium oxide, and mixtures thereof, wherein MnO₂ and silver vanadium oxide are only one of the first and third cathode active materials when the second and fourth cathode active materials are not MnO₂ or silver vanadium oxide and are of are of a lesser energy density and a greater rate capability than MnO₂ or silver vanadium oxide.

27. The method of claim 25 including selecting the second and fourth cathode active materials from the group consisting of silver vanadium oxide, copper silver vanadium oxide, V₂O₅, MnO₂, LiCoO₂, LiNiO₂, LiMnO₂, CuO, TiS, CuS, FeS, FeS₂, copper oxide, copper vanadium oxide, and mixtures thereof.

28. The method of claim 25 wherein the first anode structure is of lithium, the first and third cathode active materials are CF_x, and the second and fourth cathode active materials are silver vanadium oxide.

29. The method of claim 25 including providing the first cathode structure having the configuration:

silver vanadium oxide/first cathode current collector/CF_x/second cathode current collector/silver vanadium oxide.

30. The method of claim 25 including providing the second cathode structure having the configuration:

CF_x/third cathode current collector/silver vanadium oxide.