Corrosion resistant coated fuel cell bipolar plate with filled-in fine scale porosities and method of making the same

• US 6,649,031 B1
• Filed: 10/08/1999
• Issued: 11/18/2003
• Est. Priority Date: 10/08/1999
• Status: Expired due to Term

• Current Assignee: Hybrid Power Generation Systems, LLC
• Original Assignee: Hybrid Power Generation Systems, LLC
• Inventors: Rehg, Timothy, Narasimhan, Dave, Iqbal, Zafar, Guiheen, James V.
• Primary Examiner(s): McDonald, Rodney G.
• Application Number:
  US09/415,466
• Time in Patent Office: 1,502 Days
• Field of Search: 204/192.15, 204/192.16, 204/192.17, 427/123, 427/126.1, 427/249.1, 427/249.7, 427/250, 427/255.11, 427/530, 427/528
• US Class Current: 204/192.15
• CPC Class Codes: H01M 8/0204 Non-porous and characterised by the material
• CPC Class Codes: H01M 8/0206 Metals or alloys
• CPC Class Codes: H01M 8/0213 Gas-impermeable carbon-containing materials
• CPC Class Codes: H01M 8/0215 Glass; Ceramic materials
• CPC Class Codes: H01M 8/0228 in the form of layered or coated products
• CPC Class Codes: Y02E 60/50 Fuel cells
• CPC Class Codes: Y02P 70/50 Manufacturing or production processes characterised by the final manufactured product

Abstract

A corrosion resistant coated fuel cell plate and method of making the same are embodied in a metal plate provided with a multilayered conductive coating and then with an overcoating which fills in fine scale porosities in the coating. In one preferred embodiment, the overcoating is amorphous graphite applied through a deposition process. In another preferred embodiment, the overcoating is a thin layer of oxide created by a chemical anodization process.

Claims

1. A method of corrosion passivation of a bipolar plate for a fuel cell, the method comprising the steps of:

providing a metal fuel cell bipolar plate;

providing an electrically conductive corrosion resistant coating over the metal fuel cell bipolar plate, the electrically conductive corrosion resistant coating including a top surface and porosities; and

providing an overcoating over the electrically conductive corrosion resistant coating, the overcoating sealing some or all of the porosities at the top surface of the electrically conductive corrosion resistant coating.

2. A method as claimed in claim 1, wherein the step of providing the electrically conductive corrosion resistant coating includes employing a near-zero bias magnetron sputtering process.

3. A method as claimed in claim 1, wherein the step of providing the electrically conductive corrosion resistant coating includes employing a physical vapor deposition (PVD) process.

4. A method as claimed in claim 1, wherein the electrically conductive corrosion resistant coating includes a portion adjacent to the metal fuel cell bipolar plate which promotes adhesion to other portions of the electrically conductive corrosion resistant coating.

5. A method as claimed in claim 1, wherein the metal fuel cell bipolar plate is held at room temperature during the step of providing the overcoating.

6. A method as claimed in claim 1, wherein the step of providing the overcoating includes employing a physical vapor deposition (PVD) process.

7. A method as claimed in claim 1, wherein the overcoating comprises an electrically conductive overcoating.

8. A method as claimed in claim 1, wherein the overcoating comprises an electrically conductive overcoating that entirely coats the metal fuel cell bipolar plate.

9. A method as claimed in claim 1, wherein the overcoating comprises an electrically insulating overcoating.

10. A method as claimed in claim 1, wherein the overcoating comprises an electrically insulating overcoating that does not entirely coat the metal fuel cell bipolar plate.

11. A method as claimed in claim 1, wherein the overcoating comprises a hydrophobic overcoating.

12. A method as claimed in claim 1, wherein the overcoating comprises a crystalline overcoating.

13. A method as claimed in claim 12, wherein the crystalline overcoating comprises an aluminum oxide.

14. A method as claimed in claim 12, wherein the crystalline overcoating comprises a titanium oxide.

15. A method as claimed in claim 12, wherein the crystalline overcoating comprises a titanium sub-oxide.

16. A method as claimed in claim 1, wherein the overcoating comprises an amorphous overcoating.

17. A method as claimed in claim 16, wherein the amorphous overcoating comprises an amorphous carbon powder.

18. A method as claimed in claim 1, wherein the metal fuel cell bipolar plate comprises aluminum, an aluminum alloy, or a stainless steel.

19. A method as claimed in claim 1, further comprising providing a transition metal sublayer onto the metal fuel cell bipolar plate before providing the electrically conductive corrosion resistant coating over the metal fuel cell bipolar plate, such that the transition metal sublayer is disposed between the metal fuel cell bipolar plate and the electrically conductive corrosion resistant coating.

20. A method of corrosion passivation of a bipolar plate for a fuel cell, the method comprising the steps of:

providing a metal fuel cell bipolar plate;

providing an electrically conductive corrosion resistant coating over the metal fuel cell bipolar plate, the electrically conductive corrosion resistant coating including a top surface and porosities; and

employing a chemical anodization process to provide an overcoating over the electrically conductive corrosion resistant coating, the overcoating sealing some or all of the porosities at the top surface of the electrically conductive corrosion resistant coating.

21. A method as claimed in claim 20, wherein the chemical anodization process includes the steps of:

after the electrically conductive corrosion resistant coating is applied to the metal fuel cell bipolar plate, dipping the metal fuel cell bipolar plate into an acid bath; and

washing the metal fuel cell bipolar plate with deionized water.

22. A method of manufacturing a bipolar plate for a fuel cell, the method comprising the steps of:

providing a metal plate;

providing an electrically conductive corrosion resistant coating over the metal plate, the electrically conductive corrosion resistant coating including a top surface and porosities; and

providing an overcoating sealing some or all of the porosities at the top surface of the electrically conductive corrosion resistant coating, the overcoating being at least partially formed as a structure that is free of grain boundaries.

23. A method of manufacturing a fuel cell plate, a fuel cell conductor element, or a fuel cell current collector element, the method comprising:

applying a transition metal sublayer onto a metal structure which comprises aluminum;

applying an electrically conductive corrosion resistant coating over the sublayer, wherein the electrically conductive corrosion resistant coating comprises titanium aluminum nitride and includes a top surface and porosities; and

applying an overcoating onto the electrically conductive corrosion resistant coating, sealing porosities at the top surface of the electrically conductive corrosion resistant coating, wherein the overcoating comprises amorphous graphite.

24. The method of claim 23, wherein the step of applying the sublayer, the step of applying the electrically conductive corrosion resistant coating, the step of applying the overcoating, or a combination thereof, is conducted using a physical vapor deposition process.

25. The method of claim 23, further comprising stamping or machining flow field patterns into a surface of the metal structure before application of the sublayer.